• 대한정형도수물리치료학회지
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• 제15권1호
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• pp.22-31
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• 2009

Purpose The purpose of this study was to compare the effects of closed kinetic chain exercise and open kinetic chain exercise in improving the balance of patients with hemiplegia. Methods Ten patients with stroke were randomly allocated to either a closed kinetic chain exercise (CKC) group(n=5) or an open kinetic chain exercise(OKC) group(n=5). The subjects of each group followed the exercise regimen of their respective groups, and each exercise was performed for 50 mins per day, 3 days per week, for 4 weeks. Assessment was made using Berg Balance Scale (BBS), One Leg Standing(OLS) test, and Timed up and go(TUG) test. The 2 groups were assessed twice: before and after the intervention. Results The TUG test score was significantly different in the CKC group between before and after intervention (p<.05); however, there was no such deference in the OKC group (p>.05). Further, the scores of the BBS and OLS tests were not significantly different for the 2 groups between before and after intervention (p>.05). The hanges in these BBS and OLS score were not significantly different(p>.05); however, there was a significant difference in the change in the TUG scores (p<.05). Conclusion On the basis of the results of this study, we found that the closed kinetic chain exercise is more effective in improving the walking ability and dynamic balance in patients with stroke. Future studies are warranted in this regard.

• Bulletin of the Korean Chemical Society
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• 제32권spc8호
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• pp.3003-3008
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• 2011

Reactions of benzyl alcohol and its derivatives by [Ru$^{IV}$(tpy)(dcbpy)(O)]$^{2+}$ (tpy = 2,2':6',2"-terpyridine; dcbpy = 4,4'-dicarboxy-2,2'-bipyridine) leading to the corresponding benzaldehydes in acetonitrile and water have been studied. Kinetic studies show that the reaction is first-order in both alcohol and oxidant, with k = 1.65 (${\pm}$ 0.1) $M^{-1}s^{-1}$ at $20^{\circ}C$, ${\Delta}H^{\ddag}$ = 4.3 (${\pm}$ 0.1) kcal/mol, ${\Delta}S^{\ddag}$ = -22 (${\pm}$ 1) eu, and $E_a$ = 4.9 (${\pm}$ 0.1) kcal/mol. High ${\alpha}$ C-H kinetic isotope effects are observed, but O-H solvent isotope effects are negligible. Spectral evidences with the isotope effects suggest that oxidation of benzyl alcohols occurs by a two-electron, hydride transfer. The catalytic cycles of aerobic benzyl alcohol oxidation are employed.

• Journal of Microbiology and Biotechnology
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• 제13권3호
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• pp.332-337
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• 2003

Enzyme kinetics data play a vital role in the design of reactors and control of processes. In the present study, kinetic studies on pectinases were carried out. Partially purified polymethylgalacturonase (PMG) and polygalacturonase (PG) were the two pectinases studied. The plot of initial rate vs. initial substrate concentration did not follow the conventional Michaelis-Menten kinetics, but substrate inhibition was observed. For PMG, maximum rate was attained at an initial pectin concentration of 3 g/l, whereas maximum rate was attained when the initial substrate concentration of 2.5 g/l of polygalacturonic acid for PG I and PG II. The kinetic data were fitted to five different kinetic models to explain the substrate inhibition effect. Among the five models tested, the combined mechanism of protective diffusion limitation of both high and inhibitory substrate concentrations (semi-empirical model) explained the inhibition data with 96-99% confidence interval.

• Advances in environmental research
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• 제6권1호
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• pp.1-14
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• 2017

New technologies or improvement of the existing technologies are required to enhance the efficiency of removal of pollutants from wastewater. In this study we attempted to produce and test the activated carbon produced from the refused tea waste for the removal of dyes from wastewater. The objectives of this investigation were to produce activated carbon from refused tea waste by chemical activation, evaluate its performance for the removal of color produced from Acid Yellow 36, and the modeling of its dye removal with the kinetic study. The activation was performed in two steps namely carbonization at $375{\pm}25^{\circ}C$ and chemical activation with HCl at $800^{\circ}C$ under the absence of Oxygen. Adsorption isotherms and kinetic studies were performed with a textile dye, Acid Yellow 36, at different concentrations (20-80 mg/L). The maximum dye removal (~90%) observed at 80 mg/L dye concentration and it reduced at low dye concentrations. Maximum adsorption (71.97 mg/g) was recorded at 96 h at $29{\pm}1^{\circ}C$. Low pH increased the dye adsorption (pH=2; 78.27 mg/g) while adsorption reduced at high pH levels indicating that the competition occurs in between OH- ions and AY36 molecules for the adsorption sites in RTAC. The Langmuir isotherm model clearly explained the dye adsorption, favorably, by RTAC. Moreover, kinetic studied performed showed that the pseudo second order kinetic model clearly describes the dye adsorption. Based on the results obtained in this study, it can be concluded that RTAC can be used for the removal of textile dyes.

• 조형예술학연구
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• 제8권
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• pp.267-296
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• 2005

Typography, as the median for communication, has expanded its roles according the attributes of the media where it Is used, and the change of media follwing the change of times is presenting new directions to the field of typography. The attempts of 20C experimental typography prioritize visual formativeness, free typography and language started to appear on printed matters and different kinds of prints put pep in magazines. Thus, experiments in the aspects of effective delivery of inpormation that letters have and aesthetic side of shapes of letter are continuing. Today with the appearance of multimedia, development of visual colture and rapid development of digital technology, the range of experimental typography has expanded even wider and therefore, different kinds of expressions became possible. As seen above, unlike the existing static printed media that carries linguistic information only, letters in the multimedia environment is shown in the movie titles, TV or web not only as a basic visual media such as type and image, but as a dynamic and complex factor that contains additional information of motion and sound factor. This study will attempt to find the historic context of focus of moment from the kinetic art and define the moving letters as kinetic typography. Therefore, this paper will have an understanding on kinetic typography's background, concept and characteristics following the change of communication environment in the multimedia era and tried to study the basic theories of kinetic typography and the information delivery and imagery function of letters. Also, this paper attempted to carry out a study on whether kinetic typography is delivering information smoothly from the aspect of communication through the image role as delivering information by studying major works of artists who have influenced kinetic typography. Based on this study, I would like to suggest new direction for effective delivery of information and value of use.

• Journal of Welding and Joining
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• 제25권4호
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• pp.35-41
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• 2007

In kinetic spraying process, the critical velocity is an important criterion which determines the deposition of a feedstock particle onto the substrate. In other studies, it was experimentally and numerically proven that the critical velocity is determined by the physical and mechanical properties and the state of materials such as initial temperature, size and the extent of oxidation. Compared to un-oxidized feedstock, oxidized feedstock required a greater kinetic energy of in-flight particle to break away oxide film during impact. The oxide film formed on the surface of particle and substrate is of a relatively higher brittleness and hardness than those of general metals. Because of its physical characteristics, the oxide significantly affected the deposition behavior and critical velocity. In this study, in order to investigate the effects of oxidation on the deposition behavior and critical velocity of feedstock, oxygen contents of Al feedstock were artificially controlled, individual particle impact tests were carried out and the velocities of in-flight Al feedstock was measured for a wide range of process gas conditions. As a result, as the oxygen contents of Al feedstock increased, the critical velocity increased.

• 한국지반환경공학회 논문집
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• 제19권12호
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• pp.15-23
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• 2018

우리나라에서 발생하는 대부분의 토양침식은 물에 의한 토양침식이며 강우와 밀접한 관계를 가진다. 강우로부터 발생하는 토양침식은 토지자원의 손실을 발생시키고 이후 하천에 유입되고 퇴적되어 하천수자원의 관리 및 이용에 많은 어려움을 주고 있다. 최근 기후변화의 영향으로 우리나라에서는 30mm/hr 이상의 집중호우의 발생횟수가 증가하고 있어 단기간에 토양침식이 발생할 가능성이 높아지고 있다. 본 연구에서는 강우의 물리적인 특성을 고려하기 위하여 누적분포함수를 이용하여 강우강도별 강우입자의 분포를 추정하고 단일 호우사상이 가지는 강우에너지를 계산하는 방법을 제안하고자 하였다. 강우에너지 산정공식을 개발하기 위하여 강우강도 0.254~152.4mm/hr에서 측정된 강우입자 자료를 이용하였다. 누적분포함수를 적용하여 산정된 강우에너지는 강우강도의 관계에서 멱함수형태로 증가하는 경향으로 나타났으며, 이 관계로 얻어진 식을 바탕으로 1~80mm/hr 강우강도의 강우 운동에너지를 산정한 결과 $0.03{\sim}48.26Jm^{-2}mm^{-1}$로 나타났다. 강우강도와 강우에너지의 관계를 바탕으로 강우에너지 식을 멱함수로 제시하였다. 본 연구에서 제안된 공식은 한시적으로 설치하는 침사지와 같은 시설물의 규모를 결정하는 계획의 토양침식량을 예측에 활용될 수 있을 것으로 판단된다.

• 대한화학회지
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• 제61권3호
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• pp.89-96
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• 2017

This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.

• 한국지반환경공학회 논문집
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• 제11권1호
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• pp.45-51
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• 2010

본 연구는 hydroxyapatite(HAP) 첨가 활성탄(HAP sorbent)의 카드뮴에 대한 흡착특성을 조사하였다. HAP 첨가량의 변화에 따른 카드뮴의 제거특성은 HAP 첨가량이 증가 할수록 카드뮴의 제거량은 흡착에 의한 영향으로 증가하는 것으로 나타났다. 이러한 결과는 HAP에 의한 이온교환능력의 증가에 의한 것으로 사료된다. 동역학적 흡착과 흡착평형에 관한 연구는 연속적인 회분식 실험을 통하여 조사하였다. 조사된 흡착평형 데이터는 Langmuir와 Freundlich isotherm mode을 사용하여 살펴보았으며, 초기 흡착질의 농도 변화에 따른 HAP 첨가 활성탄의 카드뮴의 흡착은 Freundlich isotherm model에 적합한 것으로 나타났다. Cd의 흡착반응의 동역학적 연구를 위하여 유사 1차 반응속도와 유사 2차 반응속도 모델을 사용하 Cd 흡착반응의 흡착 메커니즘을 조사하였다. 유사 2차 반응속도를 따르며, 유사 2차 반응속도 상수는 활성탄에 HAP의 첨가량이 증가할수록 증가하는 것을 확인할 수 있었다. 또한, intraparticle diffusion model을 사용하여 수용액상의 흡착질과 흡착매질과의 흡착 메커니즘을 조사하였다. 수용액상 카드뮴의 흡착 메커니즘은 흡착질과 흡착매질에서 표면흡착반응과 입자내 확산이 동시에 일어나는 것으로 확인되었다.

• 한국디자인학회:학술대회논문집
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• 한국디자인학회 2002년도 가을학술발표대회 디자인학 연구
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• pp.38-39
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• 2002