• Title/Summary/Keyword: Kinetic stability

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Oxidation Stability of PAO Oils Determined by Differential Scanning Calorimetry

  • Shim, Joosup;Cho, Wonoh;Chung, Keunwo
    • Tribology and Lubricants
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    • v.12 no.1
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    • pp.36-41
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    • 1996
  • The suitability of a pressure differential scanning calorimetry (PDSC) in monitoring the quality of synthetic base fluids has been investigated using polyalphaolefin (PAO) oils as an example. Induction period meassured at 170, 180 and 19$0^{\circ}C$, and 3.53 MPa oxygen pressure was applied to characterize their oxidation stability. The PDSC method has proven to be simple and repeatable and requires only small sample size for testing. More importantly, it can be applied in differentiating the oxidation performance quality of PAO oils and is versatile enough for use in studying kinetic aspects of PAO oil oxidation which include the effect of temperature and antioxidant concentration. Additionally, the method appears to correlate well with a rotary bomb oxidation test (RBOT).

INSTABILITY IN A PREDATOR-PREY MODEL WITH DIFFUSION

  • Aly, Shaban
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.13 no.1
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    • pp.21-29
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    • 2009
  • This paper treats the conditions for the existence and stability properties of stationary solutions of a predator-prey interaction with self and cross-diffusion. We show that at a certain critical value a diffusion driven instability occurs, i.e. the stationary solution stays stable with respect to the kinetic system (the system without diffusion) but becomes unstable with respect to the system with diffusion and that Turing instability takes place. We note that the cross-diffusion increase or decrease a Turing space (the space which the emergence of spatial patterns is holding) compared to the Turing space with self-diffusion, i.e. the cross-diffusion response is an important factor that should not be ignored when pattern emerges.

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Effects of the Colloid/Interface Variables on Densification and Pore Elimination of Zirconia (콜로이드/계면변수가 Zirconia의 치밀화와 기공제거에 미치는 영향)

  • 장현명;한규호;이기강;정한남
    • Journal of the Korean Ceramic Society
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    • v.27 no.2
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    • pp.169-178
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    • 1990
  • The sintering characteristics of ZrO2 were analyzed in terms of pore microstructure and kinetics of pore elimination. The pore structue of the ZrO2 sample prepared from colloid suspension was characterized by three distinct types of pores ; intradomain, interdomain, and intergglomerate pores. Sintering data at 1600$^{\circ}C$ showed that pores larger than a certain critical size(∼3$\mu\textrm{m}$) were difficult to remove, and this was analyzed in terms of the interagglomerate pore formed from the suspension under the condition of low kinetic stability, that is, the stability ratio smaller than its critical value. A theoretical equation for densification rate was derived and was applied to the densification rate of the ZrO2 polycrystalline body containging both the matrix(the 1st-generation) pores and the interagglomerate (the 2nd-generation) pores under the condition of slow grain growth.

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Optimization Application for Assessment of Total Transfer Capability Using Transient Energy Function in Interconnection Systems (과도에너지 함수를 이용하여 연계계통의 총송전용량 평가를 위한 최적화기법 응용)

  • Kim, Kyu-Ho;Kim, Soo-Nam;Rhee, Sang-Bong;Lee, Sang-Keun;Song, Kyung-Bin
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.12
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    • pp.2311-2315
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    • 2009
  • This paper presents a method to apply energy margin for assesment of total transfer capability (TTC). In order to calculate energy margin, two values of the transient energy function have to be computed. The first value is transient energy that is the sum of kinetic and potential energy at the end of fault. The second is critical energy that is potential energy at controlling UEP(Unstable Equilibrium Point). It is seen that TTC level is determined by not only bus voltage magnitudes and line thermal limits but also transient stability. TTC assessment is compared by the repeated power flow(RPF) method and optimization method.

Rehabilization after ACL Reconstruction (전방십자인대 재건술후 재활치료)

  • Shin, Dong-Min
    • Journal of the Korean Arthroscopy Society
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    • v.1 no.1
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    • pp.86-90
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    • 1997
  • Good stability and complete range of motion should be the ultimate goal of a rehabilitation program after ACL reconstruction. In previous years. the rehabilitation of the ACL reconstructed knee focused on protecting the new ligament by blocking terminal knee extension, hut, despite good stability, this approach led to numerous postoperative complications. Nowadays, most of surgeons agree the accelerated rehabilitation program based on the concept of ligamentization and clinical experience. Accelerated rehabilitation program consists of maintain of full extension of the knee, early weight bearing and prompt recovery of ROM, and closed kinetic chain exercise. Meeting this goal requires effective communication between-members of the health care team-the physician, physical therapist, atheletic trainer, and the patient. We have to know the importance of rehabilitation, knowlege about the physical therapy, and to introduce for special physical therapist and equipment.

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Rural areas, Vibration Stability Analysis of Wall and Retaining Wall of Low-rise Masonry Buildings (농촌지역 저층 조적조 건축물의 벽체 및 옹벽의 진동 안정 해석 - 전북 정읍시 ◯◯면 농촌지역 사례를 중심으로 -)

  • Lee, Deog-Yong;Kim, Il-Jung
    • Journal of the Korean Institute of Rural Architecture
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    • v.16 no.4
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    • pp.59-66
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    • 2014
  • This paper deals with vibration of plates with concentrated mass on elastic foundation. The object of investigating natural frequencies of tapered thick plate on pasternak foundation by means of finite element method and providing kinetic design data for mat of building structures. Free vibration analysis that tapered thick plate in this paper. Finite element analysis of rectangular plate is done by use of rectangular finite element with 8-nodes. In order to analysis plate which is supported on pasternak foundation. The Winkler parameter is varied with 10, $10^2$, $10^3$ and the shear foundation parameter is 5, 10. This paper is analyzed varying thickness by taper ratio. The taper ratio is applied as 0.0, 0.25, 0.5, 0.75, 1.0. And the Concentrated Mass is applied as P1, Pc, P2 respectively.

Power Transmission Mechanism of Electrorheological Clutch (Part II: Estimation of Performance Variation due to Temperature Rise of Eiectrorheological Fluid) (전기유변성 클러치의 동력전달 메커니즘 제2보:전기유변성 유체의 온도상승에 의한 성능변화 예측)

  • 이규한;심현해;김창호;임윤철
    • Tribology and Lubricants
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    • v.13 no.3
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    • pp.73-84
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    • 1997
  • ER clutch is a device using ER fluid, so called "intelligent material" and is a controlled system with electric field strength. Currently, the temperature of ER fluid increases and affects the performance of ER clutch when ER clutch is operating. This study was undertaken to estimate this performance variation due to temperature rise of ER fluid. An analytic heat transfer model of concentric cylinder type ER clutch was developed and with this model, effects of changing geometric, kinetic parameters of ER clutch and ER fluid properties were described. In conclusion, compared with neglecting thermal effects, a performance of ER clutch was very differential and for uniform performance of ER clutch, we have to improve thermal stability of ER fluid. ER fluid.

Genetic analysis of P22 tail spike protein folding

  • ;King, Janathan
    • The Microorganisms and Industry
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    • v.12 no.1
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    • pp.9-14
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    • 1986
  • We have adopted a genetic approach to identifying those residues and local sequences in a polypeptide chain which play an important role on the folding pathway. Our approach has been to isolate and characterize mutants which specifically alter the folding and subunit association pathway of a polypeptide chain, without altering the native protein. Such mutants distinguish residues involved in the kinetic control of conformation from residues involved in the stability and activity of the native protein. This approach is complementary to the efforts to characterize mutations which alter the stability of the mature protein(6,7,8). It is likely that many residues will have roles in both aspects of the functioning of the polypeptide chain. We thought it likely, however, that at least with large proteins, these aspects might be segregated in different local sequences.

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Physical properties of mungbean starch/PVA bionanocomposites added nano-ZnS particles and its photocatalytic activity

  • Yun, Yeon-Hum;Kim, Eun-Sik;Shim, Wang-Geun;Yoon, Soon-Do
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.57-68
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    • 2018
  • The main objective of this study is to prepare the bionanocomposite films using mungbean starch (MBS), PVA, ZnS, and plasticizers, and to evaluate the physical properties, thermal stability, and photocatalytic activity. The bionanocomposite films were cross-linked by heat-curing process. The ZnS and bionanocomposite films were characterized by FT-IR, XRD, and SEM. The results indicated that the mechanical properties and water resistance enhanced up to 1.2-1.5 times by the addition of nano-ZnS particles, and the thermal stability was improved by the addition of nano-ZnS particles. The photocatalytic activity of the bionanocomposite films added nano-ZnS particles was examined using bisphenol A (BPA) and methyl orange (MO). In addition, the photodegradation efficiency of BPA and MO was evaluated using the pseudo-first order kinetic model (PFOK).

Enzymatic synthesis of cephalexin

  • Rhee, D.K.;Rhee, J.S.;Ryu, D.Y.
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 1978.10a
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    • pp.206.4-206
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    • 1978
  • By utilizillg whole cell enzyme of the Xantho-monas citri IFO 3835, cephalexin is synthesized directly from 7-amino-deacetoxy cephalosporanic acid (7-ADCA) and phenyl glycine methyl ester (PGM). To date, cephalexin has been manufactu-red by chemical process involving fairly large number of steps to protect the amino group of phenly glycine and carboxyl group of 7-ADCA. However, the enzymatic process involves only a single step with 85% conversion in 90 minutes. The fermentation variables studied indicate that oxygen transfer is limiting step in the enzyme production. Optimum conditions for enzymatic reaction were 37 C, pH 6.0, and the optimum substrate molar ratio of PGM to 7-ADCA was 2. Other variables that are related to the biochemical properties of whole cell enzyme temperature stability, pH stability, kinetic constants, reusing effect, enzyme loading effect were also evaluated.

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