• 대한환경공학회지
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• 제33권11호
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• pp.804-811
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• 2011

본 연구는 흡착제의 흡착특성을 이해하는데 이용되는 각종 흡착모델의 적용성을 평가하는데 목적이 있다. 이를 위해 상용의 음이온교환수지(PA-308)를 이용하여 질산성질소에 대한 흡착특성을 회분식 실험을 통해 조사하였다. 음이온교환수지에 의한 질산성질소의 속도실험 결과는 초기의 빠른 흡착과정과 후기의 느린 흡착 과정의 두 가지 단계의 과정으로 이원화되는 경향을 나타내었다. 1차 속도식과 2차 속도식 모두 전체 반응시간에서의 질산성질소에 대한 음이온교환수지의 흡착속도를 수식화 할 수 없었다. 초기의 빠른 흡착반응($t\leq$ 20분)은 1차 속도식에 따르고 외부확산에 의해 거의 지배되는 거동을 보이는 반면, 후기 느린 흡착반응(t > 20분)은 2차 속도 화학반응과 내부확산, 즉 세공 내 확산에 의해서 일어남을 알 수 있었다.

• Advances in environmental research
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• 제4권2호
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• pp.119-133
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• 2015

Water pollution means that the physical, chemical and biological properties of water are changing. In this study, adsorption was chosen as the treatment method because it is an eco-friendly and low cost approach. Magnetite is a magnetic material that can synthesize chemical precipitation. Magnetite was used for the removal of copper in artificial water samples. For this purpose, metal removal from water dependent on the pH, initial concentration of metal, amount of adsorbent and effect of sorption time were investigated. Magnetite was characterized using XRD, SEM and particle size distribution. The copper ions were determined by atomic absorption spectrometry. The adsorption of copper on the magnetite was studied in a batch process, with different aqueous solutions of Cu (II) at concentrations ranging from 10 to $50mg\;l^{-1}$. Optimum conditions for using magnetite were found to be concentration of $10mg\;L^{-1}$, pH: 4.5, contact time: 40 min. Optimum adsorbent was found to be 0.3 gr. Furthermore, adsorption isotherm data were analyzed using the Langmuir and Freundlich equations. The adsorption data fitted well with the Freundlich ($r^2=0.9701$) and Langmuir isotherm ($r^2=0.9711$) equations. Kinetic and equilibrium aspects of the adsorption process were studied. The time-dependent Cu (II) adsorption data were described well by a pseudo-second-order kinetic model.

• 한국미생물·생명공학회지
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• 제17권6호
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• pp.552-555
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• 1989

Corynebacterium glutamicum의 NADPH-specific glutamate dehydrogenase를 이용하여 NADPH, NH$_4$Cl, $\alpha$-ketoglutarate의 기질에 대한 kinetics를 고찰하였다. 이들의 kinetic constants를 측정함으로서 정반응에로의 효소반응 기작은 첫번째 효소와 반응하는 기질이 NADPH 임을 확인할 수 있었다. Glutamate dehydrogenase 활성의 조절을 위한 metabolites의 효과를 고찰하여 본 결과 malate와 citrate 만이 효소에 억제 효과를 나타내었으며, potassium chloride는 효소활성에 가장 많은 영향을 주었다.

• Journal of Welding and Joining
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• 제32권5호
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• pp.72-79
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• 2014

Shaped charge(SC) ammunition is a weapon that penetrates directly the target by made jet from metal liner on impacting at a target. In SC, the liner occupies significantly important role causing an explosion and penetration of the target. The Al-Ni composite coating was deposited on copper liner in a solid state via kinetic spraying to improve the explosive force. The mechanical properties, reactivity and microstructure were investigated to confirm the possibility of kinetic sprayed Al/Ni composite coating as a reactive liner material. Reactive liner using Al/Ni composite exhibited much enhanced reactivity than pure copper liner due to Self-propagating High-temperature Synthesis (SHS) reaction with significantly improved adhesive bond strength. Especially, among the Al/Ni composite coatings, AN11 (the Al versus Ni atomic percent ratio is 1:1) showed the greatest reactivity due to its widest reaction area between deposited Al and Ni.

• BMB Reports
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• 제38권3호
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• pp.343-349
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• 2005

Gamma-glutamyltransferase (GGT, EC 2.3.2.2) which hydrolyzes glutathione (GSH), is required for the maintenance of normal intracellular GSH concentration. GGT is a membrane enzyme present in leukocytes and platelets. Its activity has also been observed in human neutrophils. In this study, GGT was purified from Triton X-100 solubilized neutrophils and its kinetic parameters were determined. For kinetic analyses of transpeptidation reaction, $\gamma$-glutamyl p-nitroanilide was used as the substrate and glycylglycine as the acceptor. Apparent $K_m$ values were determined as 1.8 mM for $\gamma$-glutamyl p-nitroanilide and 16.9 mM for glycylglycine. The optimum pH of GGT activity was 8.2 and the optimum temperature was $37^{\circ}C$. It had thermal stability with 58% relative activity at $56^{\circ}C$ for 30 min incubation. L-serine, in the presence of borate, was detected as the competetive inhibitor. Bromcresol green inhibited neutrophil GGT activity as a noncompetetive inhibitor. The neutrophils seem to contain only the isoenzyme that is present in platelets. We characterized the kinetic properties and compared the type of the isoenzyme of neutrophil GGT with platelet GGT via polyacrylamide gel electrophoresis (PAGE) under a standart set of conditions.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.425-428
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• 2006

Natural gas hydrate has been a major problem for its plugging nature in the pipeline. With the demand of deep-water production, the importance of flow assurance technology, preventing hydrate, asphaltene and wax in the pipeline becomes bigger Kinetic models combined with the flow simulator are being developed to explain the nature of hydrate plug formation in the pipeline. To simulate the hydrate plug formation, each stage including the nucleation, growth and agglomeration should be considered. The hydrate nucleation is known to be stochastic and is believed hard to be predicted. Recent publications showed hydrate growth and agglomeration can be observed rigorously using a particle size analyzer. However properties of the hydrate should be investigated to model the growth and agglomeration. The attractive force between hydrate particles, supposed to be the capillary force, was revealed to be stochastic. Alternative way to model the hydrate agglomeration is to simulate by the discrete element method. Those parameters, particle size distribution, attractive force, and growth rate are embedded into the kinetic model which is combined Into the flow simulator. When compared with the flowloop experimental data, hydrate kinetic model combined into a flow simulator showed good results. With the early results, the hydrate kinetic model is promising but needs more efforts to improve it.

• 한국멀티미디어학회논문지
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• 제24권8호
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• pp.1184-1191
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• 2021

In a pop song, the creator's intention is communicated to the user through music and lyrics. Lyric meaning is as important as music, but in most cases lyrics are delivered to users in a static form without non-verbal cues. Providing lyrics in a static text format is inefficient in conveying the emotions of a music. Recently, lyrics video with kinetic typography are increasingly provided, but producing them requires expertise and a lot of time. Therefore, in this system, the emotions of the lyrics are found through the analysis of the text of the lyrics, and the deep learning model is trained with the data obtained by converting the melody into a Mel-spectrogram format to find the appropriate emotions for the music. It sets properties such as motion, font, and color using the emotions found in the music, and automatically creates a kinetic typography video. In this study, we tried to enhance the effect of conveying the meaning of music through this system.

• 한국재료학회지
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• 제31권8호
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• pp.465-470
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• 2021

Deuterium is a crucial clean energy source required for nuclear fusion and is a future resource needed in various industries and scientific fields. However, it is not easy to enrich deuterium because the proportion of deuterium in the hydrogen mixture is scarce, at approximately 0.016 %. Furthermore, the physical and chemical properties of the hydrogen mixture and deuterium are very similar. Therefore, the efficient separation of deuterium from hydrogen mixtures is often a significant challenge when using modern separation technologies. Recently, to effectively separate deuterium, studies utilizing the 'Kinetic Quantum Sieving Effect (KQS)' of porous materials are increasing. Therefore, in this review, two different strategies have been discussed for improving KQS efficiency for hydrogen isotope separation performance using nanoporous materials. One is the gating effect, which precisely controls the aperture locally by adjusting the temperature and pressure. The second is the breathing phenomenon, utilizing the volume change of the structure from closed system to open system. It has been reported that efficient hydrogen isotope separation is possible using these two methods, and each of these effects is described in detail in this review. In addition, a specific-isotope responsive system (e.g., 2nd breathing effect in MIL-53) has recently been discovered and is described here as well.

• 대한화학회지
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• 제65권2호
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• pp.83-87
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• 2021

• 대한기계학회논문집B
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• 제41권5호
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• pp.341-346
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• 2017

본 연구는 해석적 접근이 용이한 실리콘 내 포논 평균자유행로(mean free path, MFP) 스펙트럼(spectrum) 열전도 특성 예측 모델을 제시했다. 해석이 용이한 포논 기체 운동론(kinetic theory)을 적용하기 위해, 나노구조물의 현상학적 접근으로 열전도에 관여하는 포논 모드(mode)들만 추출하고, 300 K의 실리콘에 대한 포논의 분산관계(dispersion relations) 및 분극(polarization) 효과가 고려된 포논의 주파수 변화에 따른 비열(specific heat)과 군속도(group velocity) 및 MFP 정보를 사용했다. 300 K의 실리콘 내 포논의 MFP 스펙트럼 열전도율 기여를 계산하고, 기존 실험결과 및 제1원리 기법 결과와 비교하여, 본 방법의 타당함을 보였다. 본 연구를 통해, 나노구조물 열전달 해석모델 개발 및 나노재료 열전달 특성 조정(tailoring) 전략 설계에 필요한 포논 MFP 스펙트럼 열전도 특성 정보를 해석이 용이한 방법으로 구할 수 있는 방법을 제공했다.