• 공업화학
• /
• 제17권3호
• /
• pp.296-302
• /
• 2006

산소농도에 따른 폐폴리우레탄의 열적 산화분해에 관한 속도론적 연구를 $10{\sim}50^{\circ}C/min$ 사이의 여러 가열속도에서 비등온 질량감소 기술을 이용하여 수행하였다. 폐폴리우레탄의 열적 산화분해를 묘사하기 위하여 Arrhenius식에 근거한 미분법과 적분법을 이용하여 산소농도에 대한 영향을 고려할 수 있는 속도론 모델을 제시하였으며 활성화 에너지 및 반응차수 그리고 pre-exponential 인자와 같은 속도 상수들에 대한 정보를 얻기 위하여 본 연구에서 제시한 속도론 해석 방법을 이용하여 질량감소 곡선 및 그 미분값을 해석하였다. 본 연구로부터 산소농도에 대한 반응차수는 모두 음의 값을 나타내었으며 활성화 에너지는 산소농도가 증가함에 따라 감소함을 확인할 수 있었다. 또한 단일 가열속도에서의 실험값을 이용하는 적분법의 경우 가열속도에 따라 반응속도 상수의 값이 변화함을 알 수 있었다. 따라서 여러 가열속도에서의 실험값을 이용하는 미분법이 폐폴리우레탄의 열적 산화분해 반응을 보다 효율적으로 나타내고 있는 것으로 판단된다.

• 한국가시화정보학회지
• /
• 제9권4호
• /
• pp.16-21
• /
• 2011

The effects of stroke change on turbulent kinetic energy for the in-cylinder flow of a four-valve SI engine were studied. For this study, the same intake manifold, head, cylinder, and the piston were used to examine turbulence characteristics in two different strokes. In-cylinder flow measurements were conducted using three dimensional LDV system. The measurement method, which simultaneously collects 3-D velocity data, allowed a evaluation of turbulent kinetic energy inside a cylinder. High levels of turbulent kinetic energy were found in regions of high shear flow, attributed to the collisions of intake flows. These specific results support the more general conclusion that the inlet conditions play the dominant role in the generation of the turbulence fields during the intake stroke. However, in the absence of two counter rotating vortices, this intake generated turbulent kinetic energy continues to decrease but at a much faster rate.

• Environmental Engineering Research
• /
• 제11권5호
• /
• pp.250-256
• /
• 2006

The combustion kinetics of poly(ethylene terephthalate) (PET) was studied by the dynamic model which accounts for the thermal decomposition of polymer at any time. The kinetic analysis was performed by a conventional nonisothermal thermogravimetric (TG) technique at several heating rates between 10 and 40 K/min in air atmosphere. The thermal decomposition of PET in air atmosphere was found to be a complex process composed of at least two stages for which kinetic values can be calculated. The combustion kinetic analysis of PET gave apparent activation energy for the first stage of $257.3{\sim}269.9\;kJ/mol$, with a value of $140.5{\sim}213.8\;kJ/mol$ for the second stage. To verify the effectiveness of the kinetic analysis method used in this work, the kinetic analysis results were compared with those of various analytical methods. The kinetic parameters were also compared with values of the pyrolysis of PET in nitrogen atmosphere.

• International Journal of Contents
• /
• 제12권3호
• /
• pp.42-46
• /
• 2016

Kinetic typography is technology such as color, scale, position of the letter changes dynamically with time and it communicates information with aesthetics and originality. The purpose of this study is to identify the design factors in the formativeness of Hangul and present and implement the interaction design method of unique Hangul kinetic typography based on the scientific structure of Hangul. We implemented the Hangul kinetic typography system, which varies in sizes and motion directions according to a viewer's movement and exhibited in a media art event. To do this, we used a viewer's skeleton information on typography synchronization. The results indicated that Hangul kinetic typography has potential not only as a means to communicate with viewers but also as a medium to show the artistic value of Hangul.

• 한국진공학회지
• /
• 제9권4호
• /
• pp.419-427
• /
• 2000

본 연구는 원자의 주변 환경에 따른 각각의 확산 속도를 구할 수 있는 기구를 제시하였다. STM 또는 HRLEED 등의 실험과 kinetic Monte Carlo(KMC) 시뮬레이션 계산과의 비교를 통하여 테라스 위 흡착 원자의 확산장벽, step 끝 부착 원자의 탈착 확산 장벽, 잘 알려진 Schwoebel 장벽을 포함한 각각의 확산 장벽을 구할 수 있었다. 팔-넓이, 군집 밀도, 거칠기 등이 시뮬레이션 계산과 실험 결과를 비교하는 데에 가장 적절한 원자단위의 구조변수들임을 확인하였고, 특히 아직 잘 사용되지 않은 구조 계수인 가지폭이 확산 장벽을 구별하여 구하는 데에 중요한 역할을 하는 것을 확인하였다.

• Bulletin of the Korean Chemical Society
• /
• 제15권3호
• /
• pp.241-245
• /
• 1994

A method has been developed to estimate the kinetic energy release originating from the reverse critical energy in unimolecular ion dissociation. Contribution from the excess energy was estimated by RRKM theory, the statistical adiabatic model and the modified phase space calculation. This was subtracted from the experimental kinetic energy release distribution (KERD) via deconvolution. The present method has been applied to the KERDs in $H_2$, loss from $C_6H_6^+$ and HF loss from ${CH_2CF_2}^+$. In the present formalism, not only the energy in the reaction coordinate but also the energy in some transitional vibrational degrees of freedom at the transition state is thought to contribute to the experimental kinetic energy release. Details of the methods for treating the transitional modes are found not to be critical to the final outcome. For a reaction with small excess energy and large reverse critical energy. KERD is shown to be mainly governed by the reverse critical energy.

• Nuclear Engineering and Technology
• /
• 제54권3호
• /
• pp.811-816
• /
• 2022

This work presents the methodology used to expand the capabilities of the Monte Carlo code OpenMC for the calculation of reactor kinetic parameters: effective delayed neutron fraction β_eff and neutron generation time L. The modified code, OpenMC(Time-Dependent) or OpenMC(TD), was then used to calculate the effective delayed neutron fraction by using the prompt method, while the neutron generation time was estimated using the pulsed method, fitting Λ to the decay of the neutron population. OpenMC(TD) is intended to serve as an alternative for the estimation of kinetic parameters when licensed codes are not available. The results obtained are compared to experimental data and MCNP calculated values for 18 benchmark configurations.

• 한국연초학회지
• /
• 제4권2호
• /
• pp.57-61
• /
• 1982

For evaluating kinetic parameters of various reactions and materials a straight- forward method has been studied by the variable heating rate method in DSC analysis. Based on the linear relationship between the logarithm of the heating rate and reciprocal Peak temperature, this method allows calculation of activation energy and the Arrhenius frequency factor by only one observation of the peak temperature versus the heating rate. According to tile D function, D=-In P(x)/dx, to x(=$\frac{E}{RT}$) we can calculate reasonably accurate activation energy, tile Arrhenius factor and the rate constant, and predict half-life times of various materials from the kinetic calculation.

• Advances in Computational Design
• /
• 제2권1호
• /
• pp.71-87
• /
• 2017

This study focuses on the efficiency and applicability of dynamic relaxation methods in form-finding of membrane structures. Membrane structures have large deformations that require complex nonlinear analysis. The first step of analysis of these structures is the form-finding process including a geometrically nonlinear analysis. Several numerical methods for form-finding have been introduced such as the dynamic relaxation, force density method, particle spring systems and the updated reference strategy. In the present study, dynamic relaxation method (DRM) is investigated. The dynamic relaxation method is an iterative process that is used for the static equilibrium analysis of geometrically nonlinear problems. Five different examples are used in this paper. To achieve the grading of the different dynamic relaxation methods in form-finding of membrane structures, a performance index is introduced. The results indicate that viscous damping methods show better performance than kinetic damping in finding the shapes of membrane structures.

• 대한기계학회논문집
• /
• 제11권1호
• /
• pp.1-18
• /
• 1987

본 연구에서는 입자가 부상된 이상난류제트유동에 Einstein의 확산모형, Pes- kin모형, 3-방정식 모형, 4-방정식 모형, 대수응력모형 등을 적용하여 해석하고 각 모 형들의 결과를 비교 분석하였다. 이상난류유동의 수치해석에서 공기는 제1유체유동 으로 하고 첨가되는 고체분말의 흐름은 밀도(.rho.$_{p}$), 층류동점성계수(.nu.$_{p}$), 과점성계수(.nu.$_{pt}$ )를 갖는 제2유체유동의 흐름으로 간주하였다.