• Title/Summary/Keyword: Kinetic Analysis

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A Study on Kinetic Gait Analysis of the Normal Adult (정상 성인의 운동역학적 보행분석)

  • Kim, Geon;Yoon, Na-Mi
    • The Journal of Korean Physical Therapy
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    • v.21 no.2
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    • pp.87-95
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    • 2009
  • Purpose: This study reports the basic reference data of the specific gait parameters for Korean normal adults. Methods: The basic gait parameters were extracted from 73 Adults (35 men and 38 women), 18 to 33 years of age, using a Vicon MX motion analysis system. The segment kinetics, such as joint moment and power, was analyzed at the hip, knee and ankle. Results: The motion patterns are typically associated with a specific phase of the gait cycle. The temporal-spatial gait parameters of Korean normal adults, such as cadence, walking speed, stride length, single support and double support, were similar to the other western reference data. The kinetic parameters of Korean normal adults, such as joint moments of force, joint mechanical power generation or absorption and ground reaction forces, were also similar to other western reference datasets. Conclusion: This study demonstrates that objective gait analysis can be used to document the gait patterns of normal healthy adults. The techniques of 3-dimensional temporal-spatial gait parameters and kinematic parameters analysis can provide a detailed biomechanical description of a normal and pathological gait.

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Kinetic Analysis for the Catalytic Pyrolysis of Polyethylene Terephthalate Over Cost Effective Natural Catalysts

  • Pyo, Sumin;Hakimian, Hanie;Kim, Young-Min;Yoo, Kyung-Seun;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.706-710
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    • 2021
  • In the current research, thermal and catalytic thermogravimetric (TG) analysis of polyethylene terephthalate (PET) over natural zeolite (NZ), olivine, bentonite, HZSM-5, and HAl-MCM-41 were investigated using a TG analyzer and model-free kinetic analysis. Catalytic TG analysis of PET was carried out at multi-heating rates, 10, 20, 30, and 40 ℃/min, under nitrogen atmosphere. Apparent activation energy (Ea) values for the thermal and catalytic pyrolysis of PET were calculated using Flynn-Wall-Ozawa method. Although natural catalysts, NZ, olivine, and bentonite, could not lead the higher PET decomposition efficiency than synthetic zeolites, HZSM-5 and HAl-MCM-41, maximum decomposition temperatures on the differential TG (DTG) curves for the catalytic pyrolysis of PET, 436 ℃ over olivine, 435 ℃ over bentonite, and 434 ℃ over NZ, at 10 ℃/min, were definitely lower than non-catalytic pyrolysis. Calculated Ea values for the catalytic pyrolysis of PET over natural catalysts, 177 kJ/mol over olivine, 168 kJ/mol over bentonite, and 171 kJ/mol over NZ, were also not lower than those over synthetic zeolites, however, those were also much lower than the thermal decomposition, suggesting their feasibility as the proper and cost-effective catalysts on the pyrolysis of PET.

Identification of Essential Amino acid Residues in Valine Dehydrogenase from Streptomyces albus

  • Hyun Chang-Gu;Kim Sang-Suk;Suh Joo-Won
    • Journal of Microbiology
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    • v.44 no.1
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    • pp.50-53
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    • 2006
  • Cys-29 and Cys-251 of Streptomyces albus valine dehydrogenase(ValDH) were highly conserved in the corresponding region of $NAD(P)^+$-dependent amino acid dehydroganase sequences. To ascertain the functional role of these cysteine residues in S. albus ValDH, site-directed mutagenesis was performed to change each of the two residues to serine. Kinetic analyses of the enzymes mutated at Cys-29 and Cys-251 revealed that these residues are involved in catalysis. We also constructed mutant ValDH by substituting valine for leucine at 305 by site-directed mutagenesis. This residue was chosen, because it has been proposed to be important for substrate discrimination by phenylalanine dehydrogenase (PheDH) and leucine dehydrogenase (LeuDH). Kinetic analysis of the V305L mutant enzyme revealed that it is involved in the substrate binding site. However it displayed less activity than the wild type enzyme toward all aliphatic and aromatic amino acids tested.

Kinetic modeling analysis for the decolorization of dyes using a mixed adsorbent

  • Ravikumar, K.;Son, Young-A
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.42-47
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    • 2006
  • A mixed adsorbent prepared by pyrolysing a mixture of carbon and flyash in 1:1 ratio was tested for its deceleration ability for three different classes of dyes namely, Astrazone Blue FRR(Basic Blue 69), Teflon flue ANL(Acid Blue 125) and Verofix Red(Reactive Red 3GL). Kinetic analyses were carried out at the optimum conditions obtained by the author in the previous studies. The data was fitted with three kinetic model equations. The results showed that the dye uptake mechanism followed the second-order rate expression.

Kinetic Study of Milk Gellation by the Electrical Resistance Measurement

  • LEE Keun Tai
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.22 no.6
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    • pp.391-396
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    • 1990
  • Changes in electric resistance was measured to carry out the kinetic analysis of milk gellation upon addition of rennet. Using pasteurized milk and commercial rennin, kinetic properties were investigated during milk gellation in terms of initial hydrolysis and coagulation steps. Specially designed reactor with two platinum electrodes was used throughout the experiments. As a function of either milk concentrations or reaction temperatures, gel time exhibited directly proportional relations: on the contrary, gel time was inversely pro-portional to enzyme concentration. Activation energies for enzymatic degradation and cogulation were 16.3, 4.6 and 34, 8.6 Kcal/mol, repectively. This simple analytical method proved to be very effective to characterize the mechanism of milk gellation. Moreover, unlike other methods, this method reguired simple apparatus and short time of analysis.

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Kinetic Approaches to Measuring Peroxiredoxin Reactivity

  • Winterbourn, Christine C.;Peskin, Alexander V.
    • Molecules and Cells
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    • v.39 no.1
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    • pp.26-30
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    • 2016
  • Peroxiredoxins are ubiquitous thiol proteins that catalyse the breakdown of peroxides and regulate redox activity in the cell. Kinetic analysis of their reactions is required in order to identify substrate preferences, to understand how molecular structure affects activity and to establish their physiological functions. Various approaches can be taken, including the measurement of rates of individual steps in the reaction pathway by stopped flow or competitive kinetics, classical enzymatic analysis and measurement of peroxidase activity. Each methodology has its strengths and they can often give complementary information. However, it is important to understand the experimental conditions of the assay so as to interpret correctly what parameter is being measured. This brief review discusses different kinetic approaches and the information that can be obtained from them.

Comparison of EMG Activity of the Posterior Oblique Sling Muscles and Pelvic Rotation During Prone Hip Extension With and Without Lower Trapezius Pre-Activation

  • Jeon, In-cheol;Ha, Sung-min;Hwang, Ui-jae;Jung, Sung-hoon;Kim, Hyun-sook;Kwon, Oh-yun
    • Physical Therapy Korea
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    • v.23 no.1
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    • pp.80-86
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    • 2016
  • Background: Prone hip extension (PHE) can be performed to measure the lumbopelvic motor patterns and motions. Imbalances in lumbopelvic muscle activity and muscle weakness can result in instability including pain in lumbopelvic region. The posterior oblique sling (POS) muscles contribute to dynamic lumbopelvic stability. In addition, POS are anatomically aligned with the trapezius muscle group according to shoulder positions. Objects: This study compared the electromyography (EMG) activity of POS and pelvic compensations during PHE with and without pre-activation of lower trapezius muscle (lowT). Methods: Sixteen healthy males were recruited. PHE was performed in randomized order: PHE with and without lowT pre-activation. Surface EMG signals were recorded for biceps femoris (BF), gluteus maximus (GM) (ipsilateral), lumbar multifidus (MF) (bilateral), and the lowT (contralateral). An electromagnetic tracking motion analysis was used to measure the angle of pelvic rotation and anterior tilting. Results: The ipsilateral GM and bilateral MF EMG amplitudes were greater during PHE with lowT pre-activation compared to PHE without lowT pre-activation (p<.05). The BF amplitude during PHE without lowT pre-activation was significantly greater than that during PHE with lowT pre-activation (p<.05). The angles of pelvic rotation and anterior tilting during PHE with lowT pre-activation were significantly smaller compared to PHE without lowT pre-activation (p<.05). Conclusion: PHE with lowT pre-activation, which is aligned with the POS, showed more increased MF and GM muscular activity with smaller lumbopelvic compensations in rotation and anterior tilting compared to PHE without lowT pre-activation.

A study of life predictions on very high temperture thermal stress (고온분위기에서 열응력을 받는 부재의 수명예측에 관한 연구)

  • 김성청
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.7 no.6
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    • pp.117-125
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    • 1998
  • The paper attempts to estimate the incubation time of a cavity in the interface between a power law creep particle and an elastic matrix subjected to a uniaxial stress. Since the power law creep particle is time dependent, the stresses in the interface relax. The volume free energy associated with Helmholtz free energy includes strain energies caused by applied stress and dislocations piled up in interface(DPI). The energy due to DPI is found by modifying the result of Dundurs and Mura[4]. The volume free energies caused by both applied stress and DPI are a function of the cavity size(r) and elapsed time(t) and arise from stress relaxation in the interface. Critical radius $r^*$ and incubation time $t^*$ to maximise Helmholtz free energy is found in present analysis. Also, kinetics of cavity formation are investigated using the results obtained by Riede [7]. The incubation time is defined in the analysis as the time required to satisfy both the thermodynamic and kinetic conditions. Through the analysis it is found that 1) strain energy caused by the applied stress does not contribute significantly to the thermodynamic and kinetic conditions of a cavity formation, 2) in order to satisfy both thermodynamic and kinetic conditions, critical radius $r^*$ decreases or holds constant with increase of the time until the kinetic condition(eq. 2.3) is satisfied. there for the cavity may not grow right after it is formed, as postulated by Harris [15], and Ishida and Mclean [16], 3) the effects of strain rate exponent (m), material constant $\sigma$0, volume fraction of the particle to matrix(f)and particle size on the incubation time are estimated using material constants of the copper as matrix.

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The Effect of Open and Close Kinetic Chain Exercise on the Muscle Activity of Pectoralis Major and Triceps (열린사슬운동과 닫힌사슬운동이 큰가슴근과 위팔세갈래근의 근활성도에 미치는 영향)

  • Kim, Ju-O;Jang, Sang-Hun
    • Journal of Korean Physical Therapy Science
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    • v.25 no.1
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    • pp.52-61
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    • 2018
  • Background: The purpose of this study was to investigate the effect of open and close kinetic chain exercise on the muscle activity of pectoralis major and triceps. Method: Twenty healthy male college students were assessed three times over two weeks. The participants were randomly assigned to OKCE(Open Kinetic Chain Exercise) and CKCE(Close Kinetic Chain Exercise). On the first day, the 7th day and the last day, The MP(mean power) and PT(peak torque) of the PM(pectoralis major) and TR(triceps) during the exercise were measured with an electromyography device and the study was compared. Result: In the present study, it was found that Statistical analysis of the measured values at the end of experimental period revealed statistically significant differences in the MP and PT values of TR and PM. Conclusion: These findings suggest that CKCE and OKCE may be an effective physical therapy intervention for strengthening muscular activity in patients with low activity in the upper limb, including normal subjects, although it is not suitable for effective exercise by selecting either CKCE or OKCE.

Adsorption of Pb(II) Ions from Aqueous Solution Using Activated Carbon Prepared from Areca Catechu Shell: Kinetic, Isotherm and Thermodynamic Studies

  • Muslim, A.;Aprilia, S.;Suha, T.A.;Fitri, Z.
    • Journal of the Korean Chemical Society
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    • v.61 no.3
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    • pp.89-96
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    • 2017
  • This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.