• Title/Summary/Keyword: Kinetic 모델

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Development of User-Friendly Modeling Software and Its Application in Processed Meat Products

  • Lee, Heeyoung;Lee, Panho;Lee, Soomin;Kim, Sejeong;Lee, Jeeyeon;Ha, Jimyeong;Choi, Yukyung;Oh, Hyemin;Yoon, Yohan
    • Journal of Food Hygiene and Safety
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    • v.33 no.3
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    • pp.157-161
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    • 2018
  • The objective of this study was to develop software to predict the kinetic behavior and the probability of foodborne bacterial growth on processed meat products. It is designed for rapid application by non-specialists in predictive microbiology. The software, named Foodborne bacteria Animal product Modeling Equipment (FAME), was developed using Javascript and HTML. FAME consists of a kinetic model and a probabilistic model, and it can be used to predict bacterial growth pattern and probability. In addition, validation and editing of model equation are available in FAME. The data used by the software were constructed with 5,400 frankfurter samples for the kinetic model and 345,600 samples for the probabilistic model using a variety of combinations including atmospheric conditions, temperature, NaCl concentrations and $NaNO_2$ concentrations. Using FAME, users can select the concentrations of NaCl and $NaNO_2$ meat products as well as storage conditions (atmosphere and temperature). The software displays bacterial growth patterns and growth probabilities, which facilitate the determination of optimal safety conditions for meat products. FAME is useful in predicting bacterial kinetic behavior and growth probability, especially for quick application, and is designed for use by non-specialists in predictive microbiology.

Sorption Characteristics of Arsenic on Furnace Slag by Adsorption Isotherm and Kinetic Sorption Experiments (등온 및 동적 흡착 실험을 통한 제강 슬래그의 비소 흡착 특성)

  • Oh, Cham-Teut;Rhee, Sung-Su;Igarashi, Toshifumi;Kon, Ho-Jin;Lee, Won-Taek;Park, Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.26 no.9
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    • pp.37-45
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    • 2010
  • Sorption characteristics of arsenic on furnace slag were investigated to remove arsenic from groundwater using furnace slag, which is industrial waste generated from steel company. Adsorption isotherm experiments and kinetic sorption experiments were performed and the chemical characteristics of supernatants from these experiments were analyzed. Results showed that all supernatants were alkaline (above pH 9) and the highest ion concentration in the solution was found with calcium (30~50 mg/L). Results of adsorption isotherms were more adequately described by the Freundlich model than Langmuir model. From adsorption isotherms experiments, it was noted that the adsorption amount of As(V) was 87% higher than that of As(III). Results of kinetic sorption experiments were more properly fitted by pseudo second order (PSO) model than pseudo first order model. Equilibrium adsorption amount ($q_e$) and relaxation time ($t_r$) calculated from PSO model increased with initial concentration of arsenic. Equilibrium adsorption amount of As(V) was higher than that of As(III) and relaxation time of As(V) was shorter than that of As(III). Adsorption isotherm results could be predicted by kinetic adsorption results, since equilibrium adsorption amount calculated through PSO model generally agreed with equilibrium adsorption amount measured from adsorption isotherm.

Applicability of Theoretical Adsorption Models for Studies on Adsorption Properties of Adsorbents(II) (흡착제의 흡착특성 규명을 위한 흡착모델의 적용성 평가(II)-흡착속도론을 중심으로)

  • Na, Choon-Ki;Park, Hyun-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.804-811
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    • 2011
  • The aim of this study is to evaluate the applicability of adsorption models for understanding adsorption properties of adsorbents. For this study, the adsorption charateristics of $NO_3^-$ by commercial anion exchange resin, PA-308, were investigated in bach process. The adsorption kinetic data for $NO_3^-$ by anion exchange resin showed two stage process comprising a fast initial adsorption process and a slower second adsorption process. Both the pseudo-first-order kinetic model and the pseudo-second-order kinetic model could not be used to predict the adsorption kinetics of $NO_3^-$ onto anion exchange resin for the entire sorption period. Only the fast initial portion ($t{\leq}20min$) of adsorption kinetics was found to follow pseudo-first-order kinetic model and controlled mainly by external diffusion that is very fast and high, whereas, the slower second portion (t > 20 min) of adsorption kinetics seems to be controlled by a second-order chemical reaction and by intraparticle diffusion.

On the Proper Use of Char Reaction Kinetic Model in CFD Code for Oxy-PC Combustion (순산소 미분탄 연소 CFD 연구에 사용되는 촤 반응속도 모델의 적절한 사용에 대한 연구)

  • Kim, Daehee;Choi, Sangmin
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.67-70
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    • 2012
  • Many computational fluid dynamic (CFD) simulations have treated the coal kinetics poorly due to large physical domain sizes and high computational complexity, particularly for the recent oxy-coal boilers. Furthermore, some modelers' lack of understanding of the kinetic rate model seems to worsen the simulation accuracy. This study is to suggest the importance of proper use of single-film global kinetic model generally used in CFD code to describe the oxy-fuel combustion of coal char through simple char burnout calculation.

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Kinetics analysis of energetic material using isothermal DSC (등온 DSC를 이용한 고에너지 물질의 정밀 반응 모델 기법 개발)

  • Kim, Yoocheon;Park, Jungsu;Kwon, Kuktae;Yoh, Jai-ick
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.219-222
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The frequency factor and activation energy are extracted as a function of product mass fraction. The extracted kinetic scheme does not assume multiple chemical steps to describe the response of energetic materials; instead, multiple set of Arrhenius factors are used in describing a single global step. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

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A Kinetic Model of the Nonphotochemical Hole Burning : 3-Level System (비광화학적인 홀의 생성에 대한 속도론적 모델 : 유사 3-준위계)

  • Lee, In-Ja
    • Journal of the Korean Chemical Society
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    • v.39 no.10
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    • pp.763-768
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    • 1995
  • The theory previously proposed to simulate hole depth in the weak burn intensity limit is extended to examine the hole depth at arbitrary burn intensity using 3-level system model. The hole spectrum simulated using constant fluence gives different hole depth for strong burn intensity while it gives same hole depth for weak burn intensity region. The calculated hole growth curves are compared with published experimental data for oxazine720 in glycerol and tetracene in MTHF glass.

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Prediction of Spectral Phonon Mean Free Path Contribution to Thermal Conduction in Silicon Using Phonon Kinetic Theory (포논 기체 운동론을 이용한 실리콘 내 포논 평균자유행로 스펙트럼 열전도율 기여도 예측)

  • Jin, Jae Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.5
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    • pp.341-346
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    • 2017
  • Knowing the mean free paths (MFPs) of thermal phonons is an essential step in performing heat transfer analysis for nanomaterials, and in determining the optimum design for tailoring the heat transfer characteristics of nanomaterials. In this study, we present a method that can be used to calculate accurately the phonon MFP spectra of nanostructures based on simple phonon kinetic theory. Here, the kinetic theory may be employed by extracting only the diffusive-transport part of the phonon spectrum (i.e., the MFPs are less than a thermal length). By considering phonon dispersion and polarization effects, the phonon MFP distributions of silicon at room temperature are calculated from phonon transport properties and the spectral MFP. Our results are validated by comparison with those of the first principle and MFP spectroscopy data.

Ion Exchange Modeling with Mass Action Law and Surface Complexation Models (질량작용법칙과 표면착화모델을 이용한 이온교환 모델링)

  • 안현경;김상대;이인형
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.3
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    • pp.296-300
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    • 2003
  • A large equilibrium and kinetic data set for multi-component cation exchanges was obtained and tested with mass action law and surface complexation model. The systematic batch equilibrium and column experiments of cation adsorption were conducted for binary, ternary, quaternary, and quinary cation exchanges involving $ H^{+}, Li^ {+}, Na^{+}, NH$_4$^{+}, Mg^{2+} $ on a strongly acidic cation exchange resin IRN 77. The mass action law and surface complexation model were tested against both data set to investigate the consistency of ion selectivity and their predictability for competitive cation exchanges. Surface complexation model provided more accurate predictions for both equilibrium and kinetic experimental data than mass action model.

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Kinetic Measurement of the Step Size of DNA Unwinding by Bacteriophage T7 DNA Helicase gp4 (T7 박테리오파지 gp4 DNA helicase에 의한 DNA unwinding에서 step size의 반응속도론적 측정)

  • Kim, Dong-Eun
    • Journal of Life Science
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    • v.14 no.1
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    • pp.131-140
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    • 2004
  • T7 bacteriophage gp4 is the replicative DNA helicase that unwinds double-stranded DNA by utilizing dTTP hydrolysis energy. The quaternary structure of the active form of T7 helicase is a hexameric ring with a central channel. Single-stranded DNA passes through the central channel of the hexameric ring as the helicase translocates $5'\rightarrow3'$ along the single-stranded DNA. The DNA unwinding was measured by rapid kinetic methods and showed a lag before the single-stranded DNA started to accumulate exponentially. This behavior was analyzed by a kinetic stepping model for the unwinding process. The observed lag phase increased as predicted by the model with increasing double-stranded DNA length. Trap DNA added in the reaction had no effect on the amplitudes of double-stranded DNA unwound, indicating that the $\tau7$ helicase is a highly processive helicase. Global fitting of the kinetic data to the stepping model provided a kinetic step size of 10-11 bp/step with a rate of $3.7 s^{-1}$ per step. Both the mechanism of DNA unwinding and dTTP hydrolysis and the coupling between the two are unaffected by temperature from $4∼37^{\circ}C$. Thus, the kinetic stepping for dsDNA unwinding is an inherent property of tile replicative DNA helicase.

A Study on Kinetic Art applied Hair Shaping (키네틱 아트를 응용한 헤어 조형에 관한 연구)

  • Park, Hyun-Hwa;Lee, Hyun-Sook
    • Journal of the Korean Society of Fashion and Beauty
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    • v.3 no.1 s.4
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    • pp.29-38
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    • 2005
  • Nowadays, fashion is high evaluated as a mean of self expression as well as a formative art itself, The moderns' elevated beauty sense and strong desire for individuality expression have not only advanced various and refined fashion presentation but also led to expansion of fashion to a total coordination covering hair and makeup. Of them, hair styling does play an important role in rounding out the various image of fashion. It is not only far from omittable part but also, out of simplicity in the past, taking formative characteristics in form and structure day by day. Especially, artistic elements of modern arts are being introduced as motives, and of which representative is e introduction of kinetic art which is thought the artistic approval on mechanization trend in the 20th century. Thus, the study was intended to investigate how and in what forms the various features of kinetic arts is reflected in the modern hair shaping, and to suggest a new prospect of kinetic art-applied hair shaping.

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