• 제목/요약/키워드: Kajiyama

검색결과 36건 처리시간 0.024초

광학활성 이소로이신을 출발물질로 한 강유전성 액정물질의 합성 (Synthesis of Ferroelectric Liquid Crystals Obtained from Optically Active l-isoleusine)

  • 정노희;기쿠치;카지야마
    • 한국응용과학기술학회지
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    • 제13권3호
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    • pp.51-60
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    • 1996
  • A new one series of chiral schiff's base containing benzylidene aniline moieties was synthesized and characterized by IR, $^1H$ NMR. elementary analysis, and polarized optical microscopy(POM). The yield of these synthetic compounds was in the range of $62{\sim}67^{\circ}C$. The results showed that most of the synthetic compounds were monotropic liquid crystal and exhibited chiral smectic C($Sc^{\ast}$) liquid crystal phases, and the range of phase transition temperature was to $71.4^{\circ}C$ from $45.0^{\circ}C$.

Five new records of ostracods (Crustacea) from Korea

  • Yoo, Hyunsu;Huyen, Pham Thi Minh;Karanovic, Ivana
    • Journal of Species Research
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    • 제6권spc호
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    • pp.220-226
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    • 2017
  • We briefly report the observation of five ostracod species: Scottia birigida Smith, Matzke-Karasz, Kamiya and Ikeda, 2002; Codonocera mortenseni Poulsen, 1962; Pyrocypris noctiluca Kajiyama, 1912; Euconchoecia cf. chierchiae Muller, 1890; and E. pacifica Chavtur, 1976. All five species are new records of Korean ostracod fauna. Specimens were collected during the 2014-2016 Korean Indigenous Species project. For three species we also include mtCO1 sequences. Currently, there are 65 published reports of indigenous Korean ostracod species.

Activated Physical Properties at Air-Polymer Interface

  • Kajiyama, Tisato;Tanaka, Keiji
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.5-6
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    • 2006
  • Molecular motion at the surface of monodisperse polystyrene (PS) films with various chain end groups was studied by scanning probe microscopy. Surface glass transition temperature ($T_{g^s}$) of the PS films was much lower than the corresponding bulk value. And, the magnitude of $T_{g^s}$ was strongly dependent on chain end chemistry. This result can be explained in terms of the chain end concentration at the surface. Time-temperature superposition principle was applied to rheological analysis at the surface. The apparent activation energy of the surface ${\alpha}_{a}$-relaxation process was approximately a half of that for the bulk sample. This result clearly indicates that the cooperativity for the surface segmental motion was reduced in comparison with that in the bulk region.

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PDP Researches at Hiroshima University

  • Kajiyama, Hiroshi;Uchida, Giichiro;Shinoda, Tsutae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1613-1616
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    • 2008
  • Hiroshima University opened the advanced display laboratory (ADL) in 2006 to specifically focus on the PDP researches. The mission of ADL is to lay the bases for the innovative PDP technologies. Our research efforts have been concentrated on the fundamental study of protective materials and phosphors, and also of the effect of protective materials with high $\gamma$ emission in the high luminous efficacy. This paper briefly introduces the present status of our research activities.

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Small Watershed Peak Flow Prediction

  • Jun, Byong-Ho;Oh, Kyoung-Doo;Park, Young-Ha
    • Korean Journal of Hydrosciences
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    • 제2권
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    • pp.1-12
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    • 1991
  • To estimate the peak discharge from the small rural watersheds, 53 storm events of seven small watersheds from 1972 to 1989 were selected and were analyzed by the multiple regression technique. The peak values by the new prediction method developed in this study were also compared to the real data of Banwol Basins and the estimated peaks of the several watersheds which were analyzed by the Korean engineering companies. These values were also compared to the results from the other method, i.e. the Rational Method, the Kajiyama Method, the Nakayasu Unit Hydrograph companies. Through Method, the Area Routing Method, etc., which are favored by the Korean engineering companies. Through these comparisons, it is proved that the proposed method may be used for day-to-day use without any problem. However, there should be some modifications and improvements as more data are available in the future.

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Activated Physical Properties at Air-Polymer Interface

  • Kajiyama, Tisato
    • Macromolecular Research
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    • 제15권2호
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    • pp.109-113
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    • 2007
  • The surface molecular motion of monodisperse polystyrene (PS) films was examined using scanning vis-coelasticity microscopy (SVM) in conjunction with lateral force microscopy (LFM). The dynamic storage modulus, E', and loss tangent, $tan\delta$, at a PS film surface with number-average molecular weights, $M_n$, smaller than 30 k were found to be smaller and larger than those for the bulk sample, even at room temperature, meaning that the PS surface is in a glass-rubber transition or fully rubbery sate at this temperature when the $M_n$ is small. In order to quantitatively elucidate the dynamics of the molecular motion at the PS surface, SVM and LFM measurements were performed at various temperatures. The glass transition temperature, $T_g$, at the surface was found to be markedly lower than the bulk $T_g$, and this discrepancy between the surface and bulk became larger with decreasing $M_n$. Such an intensive activation of the thermal molecular motion at the PS surfaces can be explained in terms of an excess free volume in the vicinity of the film surface induced by the preferential segregation of the chain end groups.

Discharge analysis of SrO- and SrCaO-PDP operated at lower voltage

  • Uchida, G.;Uchida, S.;Yano, T.;Awaji, N.;Kajiyama, H.;Shinoda, T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.177-180
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    • 2009
  • Here is presented the measurement on SrO- and SrCaO-PDP operated at lower voltage. SrO- and SrCaO-PDP attain high luminous efficacy at low voltage, where the breakdown voltage is 30 % lower than that of the ordinary MgO-PDP. A one-dimensional fluid model is applied for the simulation of PDP discharge. High VUV radiation efficiency is confirmed at high ${\gamma}_i$ and both low and high $V_s$ as in the experiment. Discharge analysis in simulation also shows that the high ${\gamma}_i$ protective layer leads to high plasma density especially near the cathode electrode, being responsible for high efficiency.

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Discharge characteristics of MgO-PDP manufactured by using "all-in-vacuum" process

  • Yano, T.;Uchida, G.;Uchida, K.;Awaji, N.;Shinoda, T.;Kajiyama, H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.28-30
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    • 2009
  • PDP panels with MgO protective layer are manufactured by using the "all-in-vacuum" process we have established [1]. This is the process aiming to keep the MgO surface as clean as possible after the evaporation. The panels are evaluated in term of discharge voltage, aging time, luminance, luminous efficacy, discharge time-lag. It is confirmed that the "all-in-vacuum" process particularly improves the aging time, discharge voltage and the discharge time-lag.

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Surface Structure of Blend Films of Styrene/Acrylonitrile Copolymer and Poly(methyl methacrylate)(PMMA) or Hydrolyzed PMMA

  • 이원기;K. Tanaka;A. Takahara;T. Kajiyama;하창식
    • Bulletin of the Korean Chemical Society
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    • 제18권9호
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    • pp.958-961
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    • 1997
  • The compatibility and the surface structure of blends of poly(styrene-co-acrylonitrile) (SAN) with either poly(methyl methacrylate) (PMMA) or hydrolyzed PMMA (H-PMMA) were studied in terms of film thickness, interaction, and surface free energy difference on the basis of X-ray photoelectron spectroscopy (XPS), attenuated total reflection Fourier transform IR spectroscopy and atomic force microscopy. The XPS measurement showed that the surface enrichment of (PMMA/SAN) blends with different AN contents of SAN and with different carboxyl acid contents of PMMA was dependent on the molecular interaction, the surface free energy difference between components and the sample preparation history. It was found that the compatibility of H-PMMA and SAN was reduced with increasing carboxyl acid content of PMMA.

Effect of fines on the compression behaviour of poorly graded silica sand

  • Hyodo, Masayuki;Wu, Yang;Kajiyama, Shintaro;Nakata, Yukio;Yoshimoto, Norimasa
    • Geomechanics and Engineering
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    • 제12권1호
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    • pp.127-138
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    • 2017
  • A series of high-pressure isotropic compression tests were performed on four types of poorly graded silica sand that were artificially prepared based on representative grading curves and similar mineralogy composition of seabed sediment containing different fines contents existing in the Nankai Trough. The addition of fines steepens the initial compression path and increases the decrement of the void ratio after loading. The transitional behaviour of the poorly graded sand with a larger amount of fines content was identified. The slope of the normal compression line shows a slight decreasing tendency with the level of fines content. The bulk modulus of silica sand with fines was lower when compared with the published results of silica sand without fines. A small amount of particle crushing of the four types of poorly graded sand with variable fines content levels was noticed, and the results indicated that the degree of particle crushing tended to decrease as the fines content increased.