• 제목/요약/키워드: KRICT

Search Result 419, Processing Time 0.027 seconds

Effect of PFO/Coal-tar Blending Ratio on Yield and Physical Properties of Pitch-based Activated Carbon (열분해유/콜타르 혼합비가 피치계 활성탄의 수율 및 물성에 미치는 영향)

  • Tae Ung Yoo;Sang Wan Seo;Ji Sun Im;Soo Hong Lee;Woo Jin Song;Seok Chang Kang
    • Applied Chemistry for Engineering
    • /
    • v.35 no.2
    • /
    • pp.107-114
    • /
    • 2024
  • In order to produce high-yield pitch-based activated carbon, pitch was synthesized by blending pyrolysis fuel oil (PFO) and coal-tar. Pitch was synthesized by varying the amount of coal-tar from 0~20% compared to PFO and reacting at 380~420 ℃ for 3 h. The synthesized pitch had a softening point between 80 and 260 ℃, and yields ranged from 10 to 40%. At all synthesis temperatures, as the coal-tar blending ratio increased, the yield increased and the softening point decreased. After considering the selected pitches (softening points: 230~260 ℃), pitches containing coal-tar were more volatile at a low boiling point and had a higher residual carbon content. This is a difference in the composition of coal-tar and PFO, and it was con- firmed that coal-tar has a lot of aromatics and PFO has a lot of aliphatics. The selected pitch was heated to 950 ℃ in a tubular reactor and physically activated with steam for 1 hour. Activated carbon containing coal-tar showed higher yield and microporosity compared to only PFO. In this study, the effect of increasing activated carbon yield by blending pitch raw materials was confirmed, and the physical activation characteristics according to the coal-tar mixing ratio were examined.

Primary Skin and Eye Irritation Study of Combined Vaccine (KGCC-95VI) Against Japanese Encephalitis and Hantaan Virus Infection

  • Shin, Kwang-Soon;Kim, Chul-Joong;Yun, Hyo-In;Park, Jong-Il;Cha, Shin-Woo;Shin, Hyeong-Soon
    • Toxicological Research
    • /
    • v.13 no.1_2
    • /
    • pp.157-160
    • /
    • 1997
  • The primary skin and eye irritancy of the combined vaccine (KGCC-95VI) for the prophylaxis against Japanese encephalitis and Hantaan virus infection recently developed by Korea Green Cross Corporation was investigated. The KGCC-95VI was applied to the back skins of the New Zealand White rabbits. The rabbits were observed for 72 hours and did not exhibit erythema, eschar and edema. The eyes of the rabbits were exposed to the KGCC-95VI. The rabbits were observed for 7 days and did not exhibit any ocular findings on cornea, iris and conjuntivae. The KGCC-95VI is considered not to have the primary skin and eye toxicity in rabbits.

  • PDF

Synthesis of Poly(glycerol-succinic acid)-dithiocarbamate and Poly(glycerol-succinic acid)-1,3,4-thiadiazole Dendrimers and Their Use as Anti-Wear Oil Additives

  • Kim, Yeong-Joon;Hoang, Quoc-Viet;Kim, Sung-Ki;Cho, Chang-Yong;Kim, Jeongkwon;Chung, Keun-Woo;Kim, Young-Wun
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.7
    • /
    • pp.2044-2050
    • /
    • 2013
  • A series of poly(glycerol-succinic acid) dithiocarbamate and 1,3,4-thiadiazole dendrimers, which have potential as anti-wear oil additives, were synthesized. Their anti-wear properties in three different oils (100N, DB-51, and soybean) were evaluated using a four-ball wear tester. The results indicated that thiocarbamate dendrimers have moderate anti-wear properties in DB-51 oil, and 1,3,4-thiadiazole dendrimers exhibited good anti-wear properties in 100N and DB-51 oils. However, dithiocarbamate and 1,3,4-thiadiazole dendrimers were not effective anti-wear additives in soybean oil.

Fungicidal activity of synthetic piericidin analogs as inhibitors of NADH-ubiquinone oxidoreductase on the respiratory chain (호습쇄의 NADH-ubiquinone oxidoreductase 저해제인 합성 piericidin유사체드르이 살균활성)

  • Chung, Kun-Hoe;Cho, Kwang-Yun;Takahashi, Nobutaka;Yoshida, Shigeo
    • Applied Biological Chemistry
    • /
    • v.33 no.3
    • /
    • pp.264-267
    • /
    • 1990
  • Representative synthetic piericidin-like compounds, such as hydroxypyridine and hydroxyquinoline derivatives, which showed high inhibition activity against NADH-ubiquinone oxidoreductase on the respiratory chain revealed good fungicide activity. Especially, hydrolrypyridine ones showed high activity against rice blast (Pyricularia oryzae) and barley powdery mildew (Erysiphe graminis).

  • PDF

Radiation Effects on Polypropylene for Biomedical Application (Polypropylene의 방사선멸균에있어 제 첨가제들에 의한 영향)

  • Khang, Gil-Son;Lee, Hai-Bang
    • Proceedings of the KOSOMBE Conference
    • /
    • v.1995 no.11
    • /
    • pp.134-137
    • /
    • 1995
  • Studies on the formulations of the additives such as antioxidants, crosslinking agent, and trans-stilbeneoxide (StO) with polypropylene (PP) have been carried out to improve the resistance of gamma radiation sterilization. The irradiated PP and ethylene-propylene copolymers samples with control and additives were characterized by mechanical tester, colorimetry, and Fourier transform infrared spectroscopy with total attenuated reflectance mode (FTIR-ATR). Crosslinking agent and StO formulated PP showed remarkable radiation resistance and minimum discoloration. Also, radiation resistance of ethylene propylene copolymers with 3% of ethylene contents was better than that of PP homopolymers in the case of no additives. The proposed mechanisms of radiation stabilization with additives are also discussed.

  • PDF

Polymeric and Oligomeric OTFT Materials Containing Fused Aromatics

  • Kim, Hyeong-Sun;Kim, Yun-Hi;Jung, Sung-Wook;Yi, Mi-Hye;Pyo, Seung-Moon;No, Yong-Young;Kim, Dong-Yu;Kwon, Soon-Ki
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.161-161
    • /
    • 2006
  • New polymeric and oligomeric OTFT materials containing fused aromatics such as anthracene and naphthalene have been designed, synthesized and characterized. The new OTFT materials were prepared by palladium-catalyzed Suzuki cross-coupling reaction. The obtained materials were characterized by various spectroscopic methods such as UV-vis, PL, cyclovoltametry, and XRD. The obtained OTFT materials containing fused aromatics showed high thermal stability above $350^{\circ}C$ In OTFT devices using new materials, high charge carrier mobility and on/off ratio were observed.

  • PDF

Study on Simultaneous Removal of Nitrogen and Phosphorus Using Zeocarbon

  • Hong, Ji-Sook;Suh, Jeong-Kwon
    • Carbon letters
    • /
    • v.11 no.2
    • /
    • pp.112-116
    • /
    • 2010
  • The objective of this study was to evaluate the possibility of simultaneous removal of ammonium, nitrate and phosphorus in water using the zeocarbon. In this study, the surface of zeocarbon was modified by acid because of difficulty in application of water treatment. After surface modification, the strength was enhanced about 62% higher than that of original one. The removal efficiency of ammonium and nitrate using the modified zeocarbon was about 47% and 32%, respectively and were higher than that of zeocarbon. In batch type experiment on the simultaneous removal of ammonium, nitrate and phosphorus, the presence of phosphorus did not have influence on nitrogen removal efficiency. Concomitantly, removal efficiency of phosphorus was obtained was about 35%. This indicates that the surface modified zeocarbon can be applied for simultaneous removal of nitrogen and phosphorus. Consequently, our results could be used as basic data to design of one-stage nitrogen/phosphorus simultaneous removal system.