• Title/Summary/Keyword: KOH solution

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A basic study on the defiberation of waste newspaper (폐지의 해섬에 관한 연구)

  • 윤태환;김형석;조동성
    • Resources Recycling
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    • v.4 no.1
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    • pp.31-37
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    • 1995
  • This study was to investigate the effects oi agitation speed, pulp concentration, ion concentration ill the slurry solution, printed area of the waste newspaper, immerwng time and the temperature on the defiberation process for the waste newspaper. The defikration efficiency at 50% is twice that of 16%. The efficiency is improved as two times according to elevate the agtation speed as two times in the range of 200-2WO r.p.m.. Defiberation with NaOH 1X10-'M solution has higher efficiency than that of NaOH 1 x 1 0 - M solution as 3 times at the conditions of 16%, 1200 r.p.m, and 1% pulp concentration The temperature of immersing salut~on aifects on the efficiency more than immersing time does. Increasing the printed area of newspaper decreases the velocity of defiberation. The alkaline solution is effective to defiberate and the defiberation efficiency at the same dosage of alkalinity is in the order a1 NaOH) KOH) Na,SiO, ) Na,CO, ) Ca(OH)2.

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Study on the Room Temperature Degreasing Conditions of Steel Sheet for Electrogalvanizing (전기아연도금용 강판의 상온 탈지 조건 연구)

  • Tae-Yeon Park;Chae-Won Kim;Su-Mi Yang;Hee-Jun Hong;In-Chul Choi
    • Journal of the Korean Society for Heat Treatment
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    • v.37 no.1
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    • pp.16-22
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    • 2024
  • The conventional degreasing process involves removing oil and contaminants at temperatures above 80℃, resulting in excessive energy consumption, increased process costs, and environmental issues. In this study, we aimed to find the optimal degreasing conditions for the pre-treatment process of electro-galvanizing cold-rolled steel sheets, conducted efficiently at room temperature without the need for a separate heating device. To achieve this, we developed a room temperature degreasing solution and a brush-type degreasing tool, aiming to reduce energy consumption and normalize the decrease in degreasing efficiency caused by temperature reduction. Alkaline degreasing solution were prepared using KOH, SiO2, NaOH, Na2CO3, and Sodium Lauryl Sulfate, with KOH and NaOH as the main components. To enhance the degreasing performance at room temperature, we manufactured additives including sodium oleate, sodium stearate, sodium palmitate, sodium lauryl sulfate, ammonium lauryl sulfate, silicone emulsion, and EDTA-Na. Room temperature additives were added to the alkaline degreasing solution in quantities ranging from 0.1 to 20 wt.%, and the uniformity of degreasing and the adhesion of the galvanized layer were evaluated through Dyne Test, T-bending Test, OM, SEM, and EDS analyses. The results indicated that the optimal degreasing solution composition consisted of NaOH (30 g/L), Na2CO3 (30 g/L), SLS (6 g/L), and room temperature additives (≤1 wt%).

Study on the Stability of NaBH4 Solution during Storage Process (NaBH4수용액 저장과정 중 안정성에 관한 연구)

  • Sim, Woojong;Jo, Jaeyoung;Choi, Daeki;Nam, Sukwoo;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.322-326
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    • 2010
  • Stability of sodium borohydride solution during storage was studied. In order to enhance the $NaBH_4$ stability, NaOH and KOH were added to the $NaBH_4$ solution. The effect of concentration of the borohydride and alkaline solution, temperature and materials of storage vessels on the rate of borohydride hydrolysis was investigated. The rate of hydrogen evolution decreased as the concentration of alkaline increased due to increase of $NaBH_4$ stability in the solution. The stability of $NaBH_4$ solution decreased when the borohydride concentration raised from 10 to 15 wt% and then increased when the $NaBH_4$ concentration increased above 15 wt% due to increase in the pH of the concentrated solution. The activity coefficient of hydrolysis of $NaBH_4$ solution(NaOH 3.0 wt%, $NaBH_4$ 25 wt%) was 115.1 kJ/mol and this value was 1.5~4.0 times higher than that of hydrolysis of $NaBH_4$ solution with catalyst. The borohydride solutions in glass and stainless-steel vessel were more stable than the solution in plastic(PE) vessel.

Preparation of $BaTiO_3$ Powder by Coprecipitation Method (공심법에 의한 $BaTiO_3$ 분말제조)

  • Kim, Yoon-Ho;Lee, Joon;Han, Il-Ho
    • Journal of the Korean Ceramic Society
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    • v.23 no.4
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    • pp.11-16
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    • 1986
  • $BaTiO_3$ ceramics powder was prepared by coprecipitation method either in oxalic acid solution or in potassium hydroxide solution. Thermal decomposition of coprecipitated $BaTiO(C_2O_4)_2$.$4H_2O$ powder in oxalic acid solution was investigated by means of Themogravimetry Differential Thermal Analysis and X-ray Diffraction Analysis. Low temperature decomposition of coprecipitated $BaTiO(C_2O_4)_2$.$4H_2O$ caused narrow particle size distribution whereas high temperature decomposition caused fairly wide particle size distribution by partial sintering. As the reaction time increased the average particle size of coprecipitated $BaTiO_3$ powder in KOH solution was increased. The most narrow paticle size distribution was obtained when the coprecipi-tates were ripened for 4hrs.

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Stability Tests on Anion Exchange Membrane Water Electrolyzer under On-Off Cycling with Continuous Solution Feeding

  • Niaz, Atif Khan;Lim, Hyung-Tae
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.369-376
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    • 2022
  • In this study, the stability of an anion exchange membrane water electrolyzer (AEMWE) cell was evaluated in an on-off cycling operation with respect to an applied electric bias, i.e., a current density of 500 mA cm-2, and an open circuit. The ohmic and polarization resistances of the system were monitored during operation (~800 h) using electrochemical impedance spectra. Specific consideration was given to the ohmic resistance of the cell, especially that of the membrane under on-off cycling conditions, by consistently feeding the cell with KOH solution. Owing to an excess feed solution, a momentary increase in the polarization resistance was observed immediately after the open-circuit. The excess feed solution was mostly recovered by subjecting the cell to the applied electric bias. Stability tests on the AEMWE cell under on-off cycling with continuous feeding even under an open circuit can guarantee long-term stability by avoiding an irreversible increase in ohmic and polarization resistances.

Study on the Efficiency in Silocin Solar Cell (실리콘 태양전지 셀 효율에 관한 연구)

  • Hyun, Il-Seoup;Oh, Teresa
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.7
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    • pp.2565-2569
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    • 2010
  • It was researched the correlation between the Solar cell and the effect of texturing. The samples were textured by using the IPA mixed solution with $HNO_3$, KOH and NaOH. The samples were analyzed by the X-ray Diffraction pattern and Fourier Transform Infrared spectroscopy. The FTIR spectra in the range of 950~1350 $cm^{-1}$ was related to the peak's formation as the bonding structure. The split of peaks means that the inter reaction between the molecular did not activate and then increased the efficiency because of low reflectance as shown the cell treated in NaOH mixed solution.

Study on the Coating Electrode for the Alkaline Water Electrolysis (알칼리 수전해용 코팅 전극에 관한 연구)

  • MIN-JI KANG;CHEOL-HWI RYU;GAB-JIN HWANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.6
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    • pp.575-580
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    • 2023
  • An electrode was prepared by dip-coating NiFe2O4 powder on stainless steel (SUS) support for the application in the alkaline water electrolysis. The prepared electrode was analyzed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDXS), and was evaluated for the voltage properties with the change of current density in oxygen evolution reaction (OER) and hydrgen evolution reaction (HER) using 1, 3 and 7 M KOH solution. From the SEM and EDXS analysis, it was confirmed that the prepared electrode had NiFe2O4 on the SUS support. In OER and HER, the voltage in the 7 M KOH solution had a value of 1.35 and -1.90 V at 0.2 and -0.2 A/cm2 of the current density, respectively. It was considered that the prepared electrode could be use as an electrode in the alkaline water electrolysis from the experimental results.

Synthesis and Characterization of Fe-Co/mesoHZSM-5 : Effect of Desilication Agent and Iron-cobalt Composition

  • Jimmy, Jimmy;Roesyadi, Achmad;Suprapto, Suprapto;Kurniawansyah, Firman
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.163-169
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    • 2020
  • Synthesis of Fe-Co/meso-HZSM5 catalyst, intended to be applied in Fischer-Tropsch (FT) reaction was investigated. The study emphasized the effect of desilication agents, NaOH and KOH, on the catalyst materials properties. Impregnation composition of active metal (Fe and Co) was also examined. HZSM-5, converted from ammonium ZSM-5 through calcination, was treated with NaOH and KOH for desilication, followed by impregnation with 10% metal loading. Fe composition in the initial mixture was varied at 10-50% from total composition. After impregnation, reduction was applied by flowing hydrogen gas at 400 ℃ for 10 hours. The use of KOH solution induced greater mesoporous volumes; however, it had a detrimental effect on zeolite crystal structure. NaOH solutions, on the other hand, increased mesopore area as high as 100%, indicated from surface area increase from 266.28 m2/g of HZSM-5, to 526.03 m2/g of NaOH-desilicated HZSM-5. In addition, the application of NaOH solution increased pore volume from 0.14 cc/g to 0.486 cc/g. Further, more Fe-Co alloys and less oxide of iron (Fe2O3) as well cobalt (Co3O4) had been commonly observed in the produced catalysts. The largest Fe-Co alloys could be found in 50Fe-50Co/HZSM-5

Purification and Characterization of Fish Oil Obtained from Hydrolysates of Mackerel (Scomber japonicus) By-products (고등어(Scomber japonicus) 부산물 가수 분해물로부터 분리된 유지의 정제 및 특성)

  • Kim, Sung-hoon;Shin, Jiyoung;Kim, Hyeon-Jeong;Kim, Jin-hee;Yang, Ji-young
    • Journal of Life Science
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    • v.26 no.9
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    • pp.1049-1055
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    • 2016
  • This study aimed to investigate an effective method of purifying oil from hydrolysates of mackerel by-products. A hydrolyzed sample was separated into lipids and other material. After degumming of crude lipids with 6% citric acid solution, the phosphorous content (45 mg/kg) decreased to 5.8 mg/kg, and the acid value (18.03 mg /g) decreased to 1.19 mg KOH/g. Following the addition of 8% sodium hydroxide solution, the peroxide value (30.25 meq/kg) dropped to 3.18 meq/kg, and the chromaticity decreased from 0.488 nm to 0.057 nm. Bleaching was performed by adding 5% activated charcoal for 60℃ for 20 min under vacuum conditions. After bleaching, the acid value was 0.17 mg KOH/g, and the peroxide value was 1.21 meq/kg, but the chromaticity was not changed remarkably (0.062 nm). Crystallization was conducted to increase the amount of unsaturated fatty acids. After crystallization, the total amount of docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA) was 228.83 mg/g. The results suggest that the product can be used as an omega-3 fatty acid resource for functional food.

Manufactures of Functional Materials by Using Xylan from Agricultural & Forest Residues(I) - The Isolation and Purification of Xylan - (농산 및 임산폐자원의 xylan을 이용한 기능성 물질 생산(I) - Xylan의 단리 및 정제 -)

  • Byun, Ji-Hye;Lim, Bu-Kug;Yang, Jae-Kyung;Chang, Jun-Pok;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.3
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    • pp.25-33
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    • 2000
  • This study was carried out to find the optimal isolation conditions of xylan from steam-exploded materials, such as rice straw(Oryza sativa), barley straw(Hordeum vulgare) and oak wood(Quercus mongolica), In the chemical composition, we found that the contents of water-extractives and ash of rice straw and barley straw were more than those of oak wood. Rice straw, barley straw and oak wood were steam-exploded at 20kgf/$cm^2$ for 3 minutes or 6 minutes. The content of lignin in three different steam-exploded materials was higher than that of non-treated materials. The crude xylan was extracted with hot water and 0.5% KOH solution from steam-exploded materials. In the sugar type of crude xylan extracted with hot water and 0.5% KOH solution, the oligomer content of crude xylan extracted with hot water was much more than that of crude xylan extracted with 0.5% KOH solution. The crude xylan was purified with 5% barium hydroxide Solution and ethanol precipitation procedure. The content of xylose of purified xylan was over 85%, but other sugar residues(arabinose, mannose, galactose and glucose) were not removed completely.

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