• 제목/요약/키워드: KOH solution

검색결과 502건 처리시간 0.031초

수퍼커패시터용 수용성 고분자 젤 전해질의 전기화학적 특성 (Electrochemical Characteristics of Aqueous Polymeric Gel Electrolyte for Supercapaictor)

  • 김한주;;;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.93-96
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    • 2001
  • We have reported to make nanostructured cobalt oxide electrode that have large capacitance over than 400F/g (specific capacitance) and good cycleability. But, It had serious demerits of low voltage range under 0.5V and low power density. Therefore, we need to increase voltage range of cobalt oxide electrode. we report here on the electrochemical properties of sol-gel-derived nanoparticulate cobalt xerogel in 1M KOH solution and aqueous polymeric gel electrolyte. In solution electrolyte, cobalt oxide electrode had over than 250F/g capacitance consisted of EDLC and pseudocapacitance. In gel electrolyte, cobalt oxide electrode had around l00F/g capacitance. This capacitance was only surface EDLC. In solution electrolyte, potassium ion as working ion reacted with both of layers easily. However, In gel electrolyte, reacted with only surface-active layer. Its very hard to reach resistive layer. So, we have studied on pretreatment of electrode to contain working ions easily. We'll report more details.

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수퍼커패시터용 수용성 고분자 젤 전해질의 전기화학적 특성 (Electrochemical Characteristics of Aqueous Polymeric Gel Electrolyte for Supercapacitor)

  • 김한주;;;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.93-96
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    • 2001
  • We have reported to make nanostructured cobalt oxide electrode that have large capacitance over than 400F/g (specific capacitance) and good cycleability. But, It had serious demerits of low voltage range under 0.5V and low power density. Therefore, we need to increase voltage range of cobalt oxide electrode. we report here on the electrochemical properties of sol-gel-derived nanoparticulate cobalt xerogel in 1M KOH solution and aqueous polymeric gel electrolyte. In solution electrolyte, cobalt oxide electrode had over than 250F/g capacitance consisted of EDLC and pseudocapacitance. In gel electrolyte, cobalt oxide electrode had around 100F/g capacitance. This capacitance was only surface EDLC. In solution electrolyte, potassium ion as working ion reacted with both of layers easily. However, In gel electrolyte, reacted with only surface-active layer. Its very hard to reach resistive layer. So, e have studied on pretretmetn of electrode to contain working ions easily. We'll report more details.

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수치해석을 이용한 자연하천의 하도추적에 관한 기초적연구 (A Basic Study on the River Basin Routing Using Numerical Analysis)

  • 김성원;고병련;고창종
    • 상하수도학회지
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    • 제12권2호
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    • pp.127-139
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    • 1998
  • The objectives of this study is at the development of the channel routing model which can be used for flood prediction. Among the routing models, the hydraulic technique of the implicit scheme in the dynamic equation is selected to route the unsteady varied flow in the open channel. The channel routing model is catchment runoff which computed by the conceptual and transfer function model. The conceptual and transfer function model can simulate the catchment runoff accurately. As a result of investigating the channel routing model, the optimal weighting factor ${\theta}$ which fixes two points between time line is chosen, and also, the optimal error tolerance which satisfies computing time and converge of solution is determined in this study.

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졸-겔 법에 의한 구형 미분체 Barium Titanate의 제조 (Synthesis of Barium Titanate Spherical Particles by Sol-Gel Method)

  • 김용렬
    • 한국응용과학기술학회지
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    • 제24권3호
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    • pp.246-252
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    • 2007
  • $BaTiO_3$ powders were prepared by sol-gel method from different concentration of KOH aqueous solution and Ba/Ti molar ratio. Particle shape, size and crystal structure of prepared $BaTiO_3$ powders were analyzed by SEM, XRD, and FT-IR. As the result of KOH concentration changing, spherical particles were obtained by condition more than 3 M and particle size decreased as concentration increasing. Different appearance showed between dried and sintered powders against changing of Ba/Ti molar ratio. In case of dried powders, the crystallinity decreased as molar ratio increasing. On the other hand, increased as molar ratio increasing in case of sintered powders.

The removal of saw marks on diamond wire-sawn single crystalline silicon wafers

  • Lee, Kyoung Hee
    • 한국결정성장학회지
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    • 제26권5호
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    • pp.171-174
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    • 2016
  • The diamond wire sawing method to produce silicon wafers for the photovoltaic application is still a new and highly investigated wafering technology. This technology, featured as the higher productivity, lower wear of the wire, and easier recycling of the coolant, is expected to become the mainstream technique for slicing the silicon crystals. However, the saw marks on the wafer surface have to be investigated and improved. This paper discusses the removal of saw marks on diamond wire-sawn single crystalline silicon wafer. With a pretreatment step using tetramethyl ammonium hydroxide ($(CH_3)_4NOH$, TMAH) and conventional texturing process with KOH solution (1 % KOH, 8 % IPA, and DI water), the saw marks on the surface of the diamond wire-sawn silicon wafers can be effectively removed and they are invisible to naked eyes completely.

실리콘 웨이퍼 습식 식각장치 설계 및 공정개발 (Design of Single-wafer Wet Etching Bath for Silicon Wafer Etching)

  • 김재환;이용일;홍상진
    • 반도체디스플레이기술학회지
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    • 제19권2호
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    • pp.77-81
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    • 2020
  • Silicon wafer etching in micro electro mechanical systems (MEMS) fabrication is challenging to form 3-D structures. Well known Si-wet etch of silicon employs potassium hydroxide (KOH), tetramethylammonium hydroxide (TMAH) and sodium hydroxide (NaOH). However, the existing silicon wet etching process has a fatal disadvantage that etching of the back side of the wafer is hard to avoid. In this study, a wet etching bath for 150 mm wafers was designed to prevent back-side etching of silicon wafer, and we demonstrated the optimized process recipe to have anisotropic wet etching of silicon wafer without any damage on the backside. We also presented the design of wet bath for 300 mm wafer processing as a promising process development.

광기록장치의 pick-up 헤드용 미러의 설계 및 제작 (Design and fabrication of mirror for optical pick-up head)

  • 천중현;김용권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 G
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    • pp.3292-3294
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    • 1999
  • In this paper, electrostatic scanner mirror for optical pick-up head is designed and fabricated. The mirror size is $20{\mu}m{\times}2400{\mu}m{\times}2400{\mu}m$ and torsional beam size is $10{\mu}m{\times}20{\mu}m{\times}500{\mu}m$. Static deflection angle is calculated ${\pm}0.4$ degrees when the maximum driving voltage is 20 V. Silicon mirror was fabricated using KOH etching and deep RIE. For passivation of the patterned mirror from KOH solution, parylene thin film was used and its usefulness has been verified. Driving electrode was fabricated using UV LIGA process. Mirror and electrode were bonded.

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Development of apparatus for Single-sided Wet Etching and its applications in Corrugated Membrane Fabrication

  • Kim, Junsoo;Moon, Wonkyu
    • 센서학회지
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    • 제30권1호
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    • pp.10-14
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    • 2021
  • Wet etching is more economical than dry etching and provides a uniform etching depth regardless of wafer sizes. Typically, potassium hydroxide (KOH) and tetra-methyl-ammonium hydroxide (TMAH) solutions are widely used for the wet etching of silicon. However, there is a limit to the wet etching process when a material deposited on an unetched surface reacts with an etching solution. To solve this problem, in this study, an apparatus was designed and manufactured to physically block the inflow of etchants on the surface using a rubber O-ring. The proposed apparatus includes a heater and a temperature controller to maintain a constant temperature during etching, and the hydrostatic pressure of the etchant is considered for the thin film structure. A corrugation membrane with a diameter of 800 ㎛, thickness of 600 nm, and corrugation depth of 3 ㎛ with two corrugations was successfully fabricated using the prepared device.

변성 폴리에틸렌의 제조 및 물성 : 1. 제조 및 수분산 특성 (Preparation and Properties of Modified Polyethylenes: 1. Preparation and Properties of Dispersions in Water)

  • 이재흥;이상헌
    • 접착 및 계면
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    • 제3권3호
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    • pp.7-14
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    • 2002
  • Poly(ethylene-co-methylacrylate)(PEMA)를 KOH, 암모니아 수용액으로 가수분해, ammonolysis 시켜서 측기에 -COOK, $-CONH_2$, -COOH를 갖는 수분산 형태의 변성 폴리에틸렌(m-PE)을 제조하였다. Infrared spectroscopy, 원소 분석 및 atomic absorption 분석 등을 통하여 m-PE 측기의 종류 및 조성비를 조사하였으며 수분산액의 고형분 함량에 따른 점도 및 표면장력을 측정하였다. 제조된 수분산액은 측기의 조성에 따라 안정도, 투명도 등이 변화하였다. 측기 중에서 -COOK가 수분산에 가장 큰 영향을 주었으며 -COOK 조성비가 20 mol% 이상이 되어야 안정한 분산을 얻을 수 있었고 또한 -COOK 조성비가 높을수록 수분산액은 투명하였다. 동일 -COOK 조성비에서는 아마이드의 농도가 높을수록 탁도가 증가하여 친수성이 떨어짐을 알 수 있었다. 분산액의 고형분 함량에 따른 점도를 측정하면 -COOK 조성비가 클 경우 낮은 고형분 함량에서 급격한 점도 증가가 일어나 고분자 사슬사이의 얽힘이 쉽게 일어남을 알 수 있으며 표면장력은 -COOK 조성비가 클 경우 작은 값을 나타내었다.

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Determining Optimum Condition of Acid Hydrolysis Technique for Food Waste Reduction

  • Kim, Eui Yeong;Choi, Young Gwang;Kim, Sung Chul
    • 한국토양비료학회지
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    • 제50권6호
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    • pp.606-614
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    • 2017
  • Amount of food waste has been increased annually in Korea and re-use of food waste as a fertilizer or soil amendment in agricultural field has been studied. Therefore, main purpose of this research was to determine optimum condition of hydrolysis for food waste management. Three different solvents, HCl, $H_2SO_4$, and KOH, were used and varied concentration at the range of 10~30% and hydrolysis time at the range of 1~3 hours were evaluated. In general, reduction rate of food waste was increased when concentration of solvent and hydrolysis time was increased except when KOH was used. Among different solvents, concentration, and hydrolysis time, the highest reduction rate (97.79%) was observed when 30% of HCl was used with temperature of $140^{\circ}C$ at 2 hours of hydrolysis time. In addition, neutralization effect of alkalic materials, shell waste (SW) and egg shell (ES) was evaluated. Both SW and ES increased pH of finished acid hydrolysis solution up to 7.61 indicating that neutralization effect of SW and ES was sufficient for finished acid hydrolysis solution. Contents of organic matter was also at the range of 10.7~13.04% and 5.53~8.04% respectively when HCl and $H_2SO_4$ were used as solvent. Overall, hydrolysis technique can be used to manage food waste with selected optimum condition in this study and characteristics of finished hydrolysis solution after neutralization might be suitable for soil amendments.