• Title/Summary/Keyword: KOH Solution

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1-D photonic crystals of free-standing DBR PSi for sensing and drug delivery applications (비고정화 된 일차원 광결정의 DBR 다공성 실리콘을 이용한 센서와 Drug Delivery로의 응용)

  • Koh, Young-Dae;Kim, Ji-Hoon;Park, Jong-Sun;Kim, Sung-Gi;Kim, Dong-Su;Cho, Sung-Dong;Sohn, Hong-Lae
    • Journal of Sensor Science and Technology
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    • v.15 no.6
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    • pp.391-396
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    • 2006
  • Free-standing multilayer distributed Bragg reflectors (DBR) porous silicon dielectric mirrors, prepared by electrochemical etching of crystalline silicon using square wave currents are treated with polystyrene to produce flexible, stable composite materials in which the porous silicon matrix is covered with caffeine-impregnated polystyrene. Optically encoded DBR PSi/polystyrene composite films retain the optical reflectivity. Optical characteristics of DBR PSi/polystyrene composite films are stable and robust for 2 hrs in a pH=7 aqueous buffer solution. The appearance of caffeine and change of DBR peak were simultaneously measured by UV-vis spectrometer and Ocean optics 2000 spectrometer, respectively.

The development of ultrasonic transmitter to enhance the efficiency of heat transfer rate in boiler (보일러내 열 전달 효율 개선을 위한 초음파발신기 개발)

  • Heo, Pil-Woo;Lee, Yang-Lae;Lim, Eui-Su;Koh, Kwang-Sik
    • Journal of Sensor Science and Technology
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    • v.12 no.2
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    • pp.95-101
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    • 2003
  • Ultrasonic transmitter used for scale prevention in boiler or heat exchanger is composed of the magnetostrictive material which transforms electric energy into ultrasonic wave and the horn which amplifies generated ultrasonic wave and transfers it into medium loaded. In this paper, we have performed the shape design for magnetostrictive material and analyzed a few type of horns which amplify generated ultrasonic wave and found each solution theoretically. Final length of the horn has been determined by measuring the sound pressure in medium between theoretical value and experience data. At last we have given the results of our study for the effects of ultrasonic wave irradiated by manufactured ultrasonic transmitter on preventing scale deposition on test pipe under the similar condition to boiler.

An Ultrasonic Application with High Frequency for the Efficiency Elevation of the Hydrogen Fuel Production (On the Pole Interval and the Temperature) (수소연료 생산의 효율향상을 위한 고주파수 초음파 응용 (극간격과 온도 중심으로))

  • Song, Min-Geun;Son, Seung-Woo;Ju, Eun-Sun
    • Journal of Hydrogen and New Energy
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    • v.13 no.2
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    • pp.127-134
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    • 2002
  • A Study on the application of ultrasonic with high frequency is carried out as a plan to rise the efficiency of the hydrogen fuel production in an electrolysis of water. KOH is selected as an electrolyte and concentrations are 0 %, 10 %, 20 %, and 30%. The solvent is city water. A measurable device of buoyancy by an electronic balance and a measurable device of voltage with a sensor of pressure are planned newly as a measuring device to measure the quantity of hydrogen production. An ultrasonic transducer with high frequency of 2 MHz is selected to give them the ultrasonic forcing. In results, it is clarified that ultrasonic influences the decrease of overpotential in the electrolytic solution. And basic data according to the pole interval and the temperature are obtained.

Improved stress analyses of dental systems implant by homogenization technique (균질화기법을 이용한 치과 임플란트 시스템의 응력해석)

  • Koh, Chul-Su;Lee, Man-Sup;Choi, Kui-Won
    • Journal of Periodontal and Implant Science
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    • v.27 no.1
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    • pp.263-290
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    • 1997
  • Homogenization technique is employed to investigate the series of stress analyses of mandible for three different types of dental implants. This technique helps to make proper material model of bone and analyze such a non homogeneous structure at the level of individual microstructural unit. The stress analyses with homogenization technique show much higher stress level in the sponge bone, compared to those of conventional FEM. It also manifested that even a minor lateral force results in crucial stresses in the dental implant system and that the macroscale model should take the shape and size after real mandible to produce reasonable solution in the analyses of dental implant systems. The shapes of dental implants simulated in this study are rectangular-cross-sectioned type, hemi-sphere rooted type, and wedge type implant. The stress states of mandible with hemisphere rooted type implant and wedge type implant show similar levels, while those with sectioned rectangular implant results in higher stresses. It is suggested that the distance between the implant tip and cortical bone be kept far enough to prevent stress concentrations in the mandible.

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Synthesis and Characterization of Phase Pure NiO Nanoparticles via the Combustion Route using Different Organic Fuels for Electrochemical Capacitor Applications

  • Srikesh, G.;Nesaraj, A. Samson
    • Journal of Electrochemical Science and Technology
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    • v.6 no.1
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    • pp.16-25
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    • 2015
  • Transition metal oxide nanocrystalline materials are playing major role in energy storage application in this scenario. Nickel oxide is one of the best antiferromagnetic materials which is used as electrodes in energy storage devices such as, fuel cells, batteries, electrochemical capacitors, etc. In this research work, nickel oxide nanoparticles were synthesized by combustion route in presence of organic fuels such as, glycine, glucose and and urea. The prepared nickel oxide nanoparticles were calcined at 600℃ for 3 h to get phase pure materials. The calcined nanoparticles were preliminarily characterized by XRD, particle size analysis, SEM and EDAX. To prepare nickel oxide electrode materials for application in supercapacitors, the calcined NiO nanoparticles were mixed with di-methyl-acetamide and few drops of nafion solution for 12 to 16 h. The above slurry was coated in the graphite sheet and dried at 50℃ for 2 to 4 h in a hot air oven to remove organic solvent. The dried sample was subjected to electrochemical studies, such as cyclic voltammetry, AC impedance analysis and chrono-coulometry studies in KOH electrolyte medium. From the above studies, it was found that nickel oxide nanoparticles prepared by combustion synthesis using glucose as a fuel exhibited resulted in low particle diameter (42.23 nm). All the nickel oxide electrodes have shown better good capacitance values suitable for electrochemical capacitor applications.

Design of Standard Model for 3D Cadastre System Development (3D 지적시스템 개발을 위한 표준모델 설계)

  • Jung, Young-Jin;Kwak, Byung-Yong;Koh, June-Hwan
    • Journal of Cadastre & Land InformatiX
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    • v.45 no.1
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    • pp.193-205
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    • 2015
  • The existing 2D cadastre as the core engine of land administration systems met with the difficulty of managing and representing the real 3D world. As a result, a 3D cadastre system has emerged as a solution oriented towards managing, representing and providing 3D spatial information related to physical status, land rights, restrictions and responsibilities. The aim of this study is to establish the foundation of the 3D cadastre information system. With this in mind, this paper aims not only to set up the data range of the 3D cadastre, but also to design a conceptual model based on an LADM (Land Administration Domain Model) through the investigation of legal restrictions and land uses relating to spaces in 3D.

Preparation and Characterization of Proton Conducting Composite Membranes From P(VDF-CTFE)-g-PSPMA Graft Copolymer and Heteropolyacid

  • Seo, Jin-Ah;Roh, Dong-Kyu;Koh, Jong-Kwan;Kim, Jong-Hak
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.20-25
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    • 2008
  • Proton conducting composite membranes were prepared by solution blending of poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-poly(sulfopropyl methacrylate) (P(VDF-CTFE)-g-PSPMA) graft copolymer and heteropolyacid (HPA). The P(VDF-CTFE)-g-PSPMA graft copolymer was synthesized by atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of P(VDF-CTFE). FT-IR spectroscopy revealed that HPA nanoparticles were incorporated into the graft copolymer via hydrogen bonding interactions. The water uptake of membranes continuously decreased with increasing HP A concentration up to 45wt%, after which it slightly increased. It is presumably due to the decrease in number of water absorption sites due to hydrogen bonding interaction between the HP A particles and the polymer matrix. The proton conductivity of membranes increased with increasing HPA concentration up to 45wt%, resulting from both the intrinsic conductivity of HP A particles and the enhanced acidity of the sulfonic acid of the graft copolymer.

Measurement of Metal-Film Removal Rate in a Microemulsion Using QCM

  • Ju, Min-Su;Koh, Moon-Sung;Kwon, Yoon-Ja;Park, Kwang-Heon;Kim, Hong-Doo;Kim, Hak-Won
    • Journal of Surface Science and Engineering
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    • v.39 no.3
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    • pp.121-128
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    • 2006
  • A set of Quartz Crystal Microbalances (QCM's) was used to observe the film removal characteristics of three different $CO_2-nitric$ acid microemulsions. QCM's electroplated with nickel or copper were used as specimens. F-AOT, NP-4 and the newly synthesized Proline Surfactant-1 were used as surfactants to create microemulsions. While the F-AOT microemulsion yielded a relatively low removal rate, that of the Proline Surfactant-1 completely removed the Cu metal film within a short period of time. The NP-4 microemulsion removed the metal surface. However, removal rate measurements per QCM were not possible due to the instability of the microemulsion when Cu ions were present in the nitric solution. The reaction kinetics and metal removal capabilities of microemulsions formed by the different surfactants are explained along with the characteristics of reverse micelles.

Electroless Plating of Co-P Magnetic Films from Pyrophosphate Bath (피로인산염욕으로부터 Co-P자성막의 무전해 도금)

  • Jo Jung-San;Koh, Suck-Soo;Lee, Ju-Seong
    • Journal of Surface Science and Engineering
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    • v.19 no.4
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    • pp.140-148
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    • 1986
  • Using sodium pyrophoshate as complexing agent, the characteristics and the magnetic properties of the films deposited from electroless cobalt plating bath have been studied. The result obtained are as following; 1. It was found that the optimum bath compositions consisted of 0.1M cobalt sulfate, 0.2M sodium hypophosphite as reducing agent, 0.4M sodium pyrophosphate as complexing agent and 0.5M ammonium sulfate as buffer agent, whereas good operating conditions were the bath of pH 10.5 adjusted with ammonia and 70$^{\circ}C$ of bath temperature, respectively. 2. The coercive force and the squareness of magnetic films were increased with deposition from the low temperature bath. 3. The phosphorous content in Co-P films deposited from these bath was relatively higher than that from Brenner bath. It was assumed to be due to codeposition of phosphorous from the pyrophosphate anion in the solution.

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A Study on the Ultrasonic Application for the Efficiency Elevation of Hydrogen Fuel Production (On the Decrease of Overpotential by LSV) (수소 연료생산의 효율 향상을 위한 초음파 응용에 관한 연구(LSV에 의한 과전압 저감 중심으로))

  • Ju, Eunsun;Park, Youngchul;Song, Mingeun;Son, Seungwoo
    • Journal of Hydrogen and New Energy
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    • v.14 no.3
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    • pp.187-194
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    • 2003
  • The production of hydrogen fuel depends basically on the water electrolysis. The study on the decrease of overpotential which activates the hydrogen production is the core to elevate the hydrogen production efficiency on principle. Characteristics on the overpotential decrease are observed through the micro reaction by ultrasonic in electrolytic cell. For the above, the electrochemical analyzer, i.e., BAS is applied, Experiments with ultrasonic forcing into 4 kinds of solution such as city water, city water plus nitrogen. distilled water, and distilled water plus nitrogen are carried out. And concentrations of KOH are 0%, 10%, 20% and 30%. The basic characteristics of the overpotential decrease are obtained through the analysis by LSV technique in sweep technique. In results, it is clarified that the ultrasonic influences the decrease of overpotential to obtain the efficiency elevation of hydrogen fuel production.