• Title/Summary/Keyword: KOH Solution

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Electrochemical Characteristics of Aqueous Polymeric Gel Electrolyte for Supercapaictor (수퍼커패시터용 수용성 고분자 젤 전해질의 전기화학적 특성)

  • Kim, Han-Joo;Ishikawa, Masashi;Morita, Masayuki;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.93-96
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    • 2001
  • We have reported to make nanostructured cobalt oxide electrode that have large capacitance over than 400F/g (specific capacitance) and good cycleability. But, It had serious demerits of low voltage range under 0.5V and low power density. Therefore, we need to increase voltage range of cobalt oxide electrode. we report here on the electrochemical properties of sol-gel-derived nanoparticulate cobalt xerogel in 1M KOH solution and aqueous polymeric gel electrolyte. In solution electrolyte, cobalt oxide electrode had over than 250F/g capacitance consisted of EDLC and pseudocapacitance. In gel electrolyte, cobalt oxide electrode had around l00F/g capacitance. This capacitance was only surface EDLC. In solution electrolyte, potassium ion as working ion reacted with both of layers easily. However, In gel electrolyte, reacted with only surface-active layer. Its very hard to reach resistive layer. So, we have studied on pretreatment of electrode to contain working ions easily. We'll report more details.

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Electrochemical Characteristics of Aqueous Polymeric Gel Electrolyte for Supercapacitor (수퍼커패시터용 수용성 고분자 젤 전해질의 전기화학적 특성)

  • ;Masashi ISHIKAWA;Masayuki MORITA
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.93-96
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    • 2001
  • We have reported to make nanostructured cobalt oxide electrode that have large capacitance over than 400F/g (specific capacitance) and good cycleability. But, It had serious demerits of low voltage range under 0.5V and low power density. Therefore, we need to increase voltage range of cobalt oxide electrode. we report here on the electrochemical properties of sol-gel-derived nanoparticulate cobalt xerogel in 1M KOH solution and aqueous polymeric gel electrolyte. In solution electrolyte, cobalt oxide electrode had over than 250F/g capacitance consisted of EDLC and pseudocapacitance. In gel electrolyte, cobalt oxide electrode had around 100F/g capacitance. This capacitance was only surface EDLC. In solution electrolyte, potassium ion as working ion reacted with both of layers easily. However, In gel electrolyte, reacted with only surface-active layer. Its very hard to reach resistive layer. So, e have studied on pretretmetn of electrode to contain working ions easily. We'll report more details.

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A Basic Study on the River Basin Routing Using Numerical Analysis (수치해석을 이용한 자연하천의 하도추적에 관한 기초적연구)

  • Kim, Sung Woon;Koh, Byung Ryoun;Koh, Chang Jong
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.2
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    • pp.127-139
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    • 1998
  • The objectives of this study is at the development of the channel routing model which can be used for flood prediction. Among the routing models, the hydraulic technique of the implicit scheme in the dynamic equation is selected to route the unsteady varied flow in the open channel. The channel routing model is catchment runoff which computed by the conceptual and transfer function model. The conceptual and transfer function model can simulate the catchment runoff accurately. As a result of investigating the channel routing model, the optimal weighting factor ${\theta}$ which fixes two points between time line is chosen, and also, the optimal error tolerance which satisfies computing time and converge of solution is determined in this study.

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Synthesis of Barium Titanate Spherical Particles by Sol-Gel Method (졸-겔 법에 의한 구형 미분체 Barium Titanate의 제조)

  • Kim, Yong-Ryul
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.3
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    • pp.246-252
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    • 2007
  • $BaTiO_3$ powders were prepared by sol-gel method from different concentration of KOH aqueous solution and Ba/Ti molar ratio. Particle shape, size and crystal structure of prepared $BaTiO_3$ powders were analyzed by SEM, XRD, and FT-IR. As the result of KOH concentration changing, spherical particles were obtained by condition more than 3 M and particle size decreased as concentration increasing. Different appearance showed between dried and sintered powders against changing of Ba/Ti molar ratio. In case of dried powders, the crystallinity decreased as molar ratio increasing. On the other hand, increased as molar ratio increasing in case of sintered powders.

The removal of saw marks on diamond wire-sawn single crystalline silicon wafers

  • Lee, Kyoung Hee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.5
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    • pp.171-174
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    • 2016
  • The diamond wire sawing method to produce silicon wafers for the photovoltaic application is still a new and highly investigated wafering technology. This technology, featured as the higher productivity, lower wear of the wire, and easier recycling of the coolant, is expected to become the mainstream technique for slicing the silicon crystals. However, the saw marks on the wafer surface have to be investigated and improved. This paper discusses the removal of saw marks on diamond wire-sawn single crystalline silicon wafer. With a pretreatment step using tetramethyl ammonium hydroxide ($(CH_3)_4NOH$, TMAH) and conventional texturing process with KOH solution (1 % KOH, 8 % IPA, and DI water), the saw marks on the surface of the diamond wire-sawn silicon wafers can be effectively removed and they are invisible to naked eyes completely.

Design of Single-wafer Wet Etching Bath for Silicon Wafer Etching (실리콘 웨이퍼 습식 식각장치 설계 및 공정개발)

  • Kim, Jae Hwan;Lee, Yongil;Hong, Sang Jeen
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.2
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    • pp.77-81
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    • 2020
  • Silicon wafer etching in micro electro mechanical systems (MEMS) fabrication is challenging to form 3-D structures. Well known Si-wet etch of silicon employs potassium hydroxide (KOH), tetramethylammonium hydroxide (TMAH) and sodium hydroxide (NaOH). However, the existing silicon wet etching process has a fatal disadvantage that etching of the back side of the wafer is hard to avoid. In this study, a wet etching bath for 150 mm wafers was designed to prevent back-side etching of silicon wafer, and we demonstrated the optimized process recipe to have anisotropic wet etching of silicon wafer without any damage on the backside. We also presented the design of wet bath for 300 mm wafer processing as a promising process development.

Design and fabrication of mirror for optical pick-up head (광기록장치의 pick-up 헤드용 미러의 설계 및 제작)

  • Chon, Joong-Hyun;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 1999.07g
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    • pp.3292-3294
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    • 1999
  • In this paper, electrostatic scanner mirror for optical pick-up head is designed and fabricated. The mirror size is $20{\mu}m{\times}2400{\mu}m{\times}2400{\mu}m$ and torsional beam size is $10{\mu}m{\times}20{\mu}m{\times}500{\mu}m$. Static deflection angle is calculated ${\pm}0.4$ degrees when the maximum driving voltage is 20 V. Silicon mirror was fabricated using KOH etching and deep RIE. For passivation of the patterned mirror from KOH solution, parylene thin film was used and its usefulness has been verified. Driving electrode was fabricated using UV LIGA process. Mirror and electrode were bonded.

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Development of apparatus for Single-sided Wet Etching and its applications in Corrugated Membrane Fabrication

  • Kim, Junsoo;Moon, Wonkyu
    • Journal of Sensor Science and Technology
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    • v.30 no.1
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    • pp.10-14
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    • 2021
  • Wet etching is more economical than dry etching and provides a uniform etching depth regardless of wafer sizes. Typically, potassium hydroxide (KOH) and tetra-methyl-ammonium hydroxide (TMAH) solutions are widely used for the wet etching of silicon. However, there is a limit to the wet etching process when a material deposited on an unetched surface reacts with an etching solution. To solve this problem, in this study, an apparatus was designed and manufactured to physically block the inflow of etchants on the surface using a rubber O-ring. The proposed apparatus includes a heater and a temperature controller to maintain a constant temperature during etching, and the hydrostatic pressure of the etchant is considered for the thin film structure. A corrugation membrane with a diameter of 800 ㎛, thickness of 600 nm, and corrugation depth of 3 ㎛ with two corrugations was successfully fabricated using the prepared device.

Preparation and Properties of Modified Polyethylenes: 1. Preparation and Properties of Dispersions in Water (변성 폴리에틸렌의 제조 및 물성 : 1. 제조 및 수분산 특성)

  • Lee, Jae Heung;Lee, Sang-Hun
    • Journal of Adhesion and Interface
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    • v.3 no.3
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    • pp.7-14
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    • 2002
  • Modified polyethylenes with polar side groups of -COOK, $-CONH_2$, and -COOH were prepared at a dispersion state in water by reacting poly(ethylene-co-methylacrylate) (PEMA) with aqueous solution of KOH and ammonia. Types and their contents of side groups were investigated by infrared spectroscopy, elemental analysis and atomic absorption analysis. Solution viscosity and surface tension were also measured as a function of solid contents. Stability and transparency of the dispersions were greatly affected by the content of COOK in the side groups. The stable dispersion could be prepared at a composition of COOK of 20 mole% at least. The transparency was increased with increasing the COOK contents, but decreased with increasing the amide content at a constant composition of COOK. Solution viscosities increased abruptly at a lower solid content when the COOK contents were increased, implying higher entanglement between the chains in dispersions with higher content of hydrophilic COOK group. The dispersions of higher COOK content revealed lower surface tension values.

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Determining Optimum Condition of Acid Hydrolysis Technique for Food Waste Reduction

  • Kim, Eui Yeong;Choi, Young Gwang;Kim, Sung Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.606-614
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    • 2017
  • Amount of food waste has been increased annually in Korea and re-use of food waste as a fertilizer or soil amendment in agricultural field has been studied. Therefore, main purpose of this research was to determine optimum condition of hydrolysis for food waste management. Three different solvents, HCl, $H_2SO_4$, and KOH, were used and varied concentration at the range of 10~30% and hydrolysis time at the range of 1~3 hours were evaluated. In general, reduction rate of food waste was increased when concentration of solvent and hydrolysis time was increased except when KOH was used. Among different solvents, concentration, and hydrolysis time, the highest reduction rate (97.79%) was observed when 30% of HCl was used with temperature of $140^{\circ}C$ at 2 hours of hydrolysis time. In addition, neutralization effect of alkalic materials, shell waste (SW) and egg shell (ES) was evaluated. Both SW and ES increased pH of finished acid hydrolysis solution up to 7.61 indicating that neutralization effect of SW and ES was sufficient for finished acid hydrolysis solution. Contents of organic matter was also at the range of 10.7~13.04% and 5.53~8.04% respectively when HCl and $H_2SO_4$ were used as solvent. Overall, hydrolysis technique can be used to manage food waste with selected optimum condition in this study and characteristics of finished hydrolysis solution after neutralization might be suitable for soil amendments.