• Transactions of the Korean hydrogen and new energy society
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• v.33 no.4
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• pp.363-371
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• 2022

In this study, the operation characteristics of the internal reforming type molten carbonate fuel cell (MCFC) were studied using computational fluid dynamics (CFD) analysis according to the steam to carbon ratio (S/C ratio), operating temperature, and gas utilization. From the simulation results, the distribution of gas composition due to the electrochemical reaction and the reforming reaction was predicted. The internal reforming type showed a lower temperature difference than the external reforming type MCFC. As the operating temperature decreased, less hydrogen was produced and the performance of the fuel cell also decreased. As the gas utilization rate decreased, more gas was injected into the same reaction area, and thus the performance of the fuel cell increased.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.749-760
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• 2022

An efficient computational fluid dynamics model was proposed for simulating microchannel-type steam/methane reformers with thin washcoat catalyst layers. In this model, by using the effectiveness factor correlations, the overall reaction rate that occurs in the washcoat catalyst layer could be accurately estimated without performing the detailed calculation of heat transfer, mass transfer, and reforming reactions therein. The accuracy of the proposed model was validated by solving a microchannel-type reformer, once by fully considering the complex steam/methane reforming (SMR) process inside the washcoat layer and again by simplifying the SMR calculation using the effectiveness factor correlations. Finally, parametric studies were conducted to investigate the effects of operating conditions on the SMR performance.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.769-775
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• 2022

Global efforts to reduce carbon emissions have focused attention on the development of hydrogen energy and the development of various hydrogen mobility requires mobile hydrogen charging stations. In this study, the flow characteristics of the flow control hydrogen valve for mobile hydrogen charging equipment were studied according to the temperature change of hydrogen gas. The inlet pressure was 100 MPa, the outlet pressure to 70 MPa, and temperature condition was set -40℃ to 85℃. As a result, the difference in the valve flow coefficient, which determines the capacity of the valve, showed a difference within 5% depending on the temperature.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.607-615
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• 2022

In this study, economic analysis program was developed for economic evaluation of hydrogen production, storage/delivery, and utilization technologies as well as overseas import of hydrogen. Economic analysis program can be used for the estimation of the levelized cost of hydrogen for hydrogen supply chain technologies. This program include five hydrogen production technology on steam methane reforming and water electrolysis, two hydrogen storage technologies (high compressed gas and liquid hydrogen storage), three hydrogen delivery technologies (compressed gas delivery using tube trailer, liquid hydrogen, and pipeline transportation) and six hydrogen utilization technologies on hydrogen refueling station and stationary fuel cell system. In the case of overseas import hydrogen, it was considered to be imported from five countries (Austraila, Chile, India, Morocco, and UAE), and the transportation methods was based on liquid hydrogen, ammonia, and liquid organic hydrogen carrier. Economic analysis program that was developed in this study can be expected to utilize for planning a detailed implementation methods and hydrogen supply strategies for the hydrogen economy road map of government.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.616-622
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• 2022

At the present time, interest in hydrogen is increasingly growing worldwide to tackle climate change. Korea also takes an action by announcing the first hydrogen economy implementation basic plan with the import targets of 22.9 million tons of hydrogen from oversea in 2050. To achieve this plan, it is very essential to establish an overseas hydrogen supply chain. In this paper, the study estimates the import price for hydrogen into basic scenario and comprehensive scenario, and also analyses economic feasibility considering price of the each technology.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.684-691
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• 2022

Hydrogen fuel cell electric vehicles are typically refueled at a wide range of temperatures (-40℃ to 85℃) in the hydrogen refueling station in accordance with the worldwide accepted standard. Currently, there is no traceable method by which to verify and calibrate the hydrogen flowmeters to be used at hydrogen refueling stations except for a water calibration process as a conventional method. KRISS hydrogen field test standard based on the gravimetric principle was developed to verify the measurement accuracy of the mass flowmeter to be used at hydrogen refueling stations for the first time in Korea.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.692-698
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• 2022

With the expansion of domestic hydrogen fuelling station infrastructure, it is necessary to secure reliability among hydrogen traders, and for this, technology to accurately measure hydrogen is important. In this study, 4 types of hydrogen trading volume calculation models (model 1-4) were presented to improve the accuracy of the hydrogen trading volume. In order to obtain the reference value of model 4, and experiment was conducted using a flow rate measurement equipment, and the error rate of the calculated value for each model was compared and analyzed. As a result, model 1 had the lowest metering accuracy, model 2 had the second highest metering accuracy and model 3 had the highest metering accuracy until a certain point. But after the point, model 2 had the highest metering accuracy and model 3 had the second metering accuracy.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.715-722
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• 2022

Pt-Fe/carbon black nanocatalysts were prepared by spontaneous reduction reaction of Platinum(II) acetylacetonate and Iron(II) acetylacetonate in a nucleophilic solvent and they were characterized by scanning electron microscopy (SEM), energy dispersive X-ray analyzer (EDS), thermogravimetric analyzer (TGA), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) surface area analysis and anion exchange membrane (AEM) water electrolysis test station. The distribution of the Pt and Fe nanoparticles on carbon black was observed by TEM, and the loading weight of Pt-Fe nanocatalysts on the carbon black was measured by TGA. Elemental ratio of Fe:Pt was estimated by EDS and it was found that elemental ratio of Pt and Fe was changed in the range of 1:0 to 0:1, and the loading weight of Pt-Fe nanoparticles on the carbon black was 5.95-6.78 wt%. Specific surface area was greatly reduced because Pt-Fe nanocatalysts blocked the pores. I-V characteristics were estimated.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.819-826
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• 2022

Fuel cell systems are being supplied to households and buildings to reduce greenhouse gases. The fuel cell systems have problems of high cost and slow startup due to fuel processors. Greenhouse gas reduction of the fuel cell systems is also limited by using natural gas. The problems can be solved by using a hydrogen generator consisting of a reformer and pressure swing adsorption (PSA). However, part load operation of the hydrogen generator is required depending on the hydrogen consumption. In this paper, PSA operation strategies are investigated for part load of the hydrogen generator. Adsorption and purge time were changed in the range of part load ratio between from 0.5 to 1.0. As adsorption time increased, hydrogen recovery increased from 29.09% to 48.34% at 0.5 of part load ratio. Hydrogen recovery and hydrogen purity were also improved by increasing adsorption and purge time. However, hydrogen recovery dramatically decreased to 35.01% at 0.5 of part load ratio.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.623-635
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• 2022

As global warming accelerates, clean hydrogen production becomes more important to mitigate it. However, importing hydrogen is necessary for countries that have high energy demands but insufficient resources to produce clean hydrogen. In line with the trend, this study investigated both the economic and environmental viability of an overseas hydrogen supply chain between Australia and the Republic of Korea. Several possible methods of water electrolysis and hydrogen carriers are compared and effect of renewable electricity price on the cost of hydrogen production is evaluated.