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Hydrogenase Enzyme for Photoelectrochemical Hydrogen Production from Water Splitting (광전기화학 물분해 수소 제조 기술에서 수소화효소 엔자임 활용)

  • CHO, HYEKYUNG;JUNG, HYEONMIN;YOON, JAEKYUNG;YI, KWANGBOK;KIM, HANSUNG;JOO, HYUNKU
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.507-514
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    • 2022
  • There is growing interest in sustainable energy sources that can reduce fossil fuel dependence and environmental pollution while meeting rapidly growing energy demands. Hydrogen have been investigated as one of the ideal alternative energies because it has relatively high efficiency without emitting pollutants. The light-sensitized enzymatic (LSE) system, which uses hydrogenase-enzymes, is one of the methods towards economically feasible system configurations that enhance the rate of hydrogen generation. Hydrogenase is an enzyme that catalyzes a reversible reaction that oxidizes molecular hydrogen or produces molecular hydrogen from protons and electrons. In this paper, utilization of [NiFe]-hydrogenase (from Pyrococcus furiosus) in photoelectrochemical hydrogen production system such as handling, immobilization, physicochemical and electrochemical analysis, process parameters, etc. was introduced.

A Study on the Mechanical Properties of Polymer Electrolyte Membrane according to Temperature (온도에 따른 고분자전해질막의 기계적 특성에 관한 연구)

  • EO, JUNWOO;KIM, SEUNGHWAN;SEO, YOUNGJIN;KO, HYUNGJONG;HWANG, CHULMIN;JUNG, YOUNGGUAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.566-573
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    • 2022
  • In this study, the mechanical properties of the polymer electrolyte membrane according to the temperature were studied. The test specimens of polymer electrolyte membrane were heat treated at 40℃, 60℃, 80℃, 100℃, and 120℃, and then the tensile tests were performed. As results of this study, the residual stress of the polymer electrolyte membrane was removes by the heat treatment and the elastic modulus decreased due to the decrease in internal energy. In addition, in the plastic region, the mechanical properties and crystallization rate of the polymer electrolyte membrane increased in proportion according to increase of the heat treatment temperature.

Status of Hydrogen Bus Operations and Charging Stations and Policy Reviews in California, USA (미국 캘리포니아 수소 버스와 충전소 운영 현황과 정책 고찰)

  • KIM, CHANGMO;JIN, SANGKYU;JIN, GOANG SUNG;KWON, YOUNG-IN;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.463-469
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    • 2022
  • After reviewing the current status of hydrogen buses and hydrogen charging stations in the United States, as well as related laws and programs, it was found that the federal and state governments supported the supports of hydrogen buses and the deployment of hydrogen charging infrastructure through various policies and programs. In order to promote the spread of domestic and overseas hydrogen buses and hydrogen charging infrastructure, it is necessary to develop and apply various legal systems and programs that can provide incentives to hydrogen bus manufacturers, hydrogen charging station installers, hydrogen bus operating organizations and entities. It is necessary to develop and apply various legal systems and programs that can provide incentives to hydrogen bus manufacturers, hydrogen charging station installers, hydrogen bus operating organizations and entities.

Numerical Analysis in a 1 kWe SOFC Stack for Variation of the Channel Height in Separators (분리판의 채널 높이에 따른 1 kWe 급 고체산화물 연료전지 스택 수치 해석)

  • YIN, HAOYUAN;KIM, YOUNG JIN;YI, KUNWOO;KIM, HYEON JIN;YUN, KYONG SIK;YU, JI HAENG
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.550-556
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    • 2022
  • In this study, the flow uniformity was analyzed by performing numerical analysis on the 1 kWe internal manifold type solid oxide fuel cell stack according to the channel height of the separator. Also, it was examined by varying the fuel utilization rate and oxygen utilization rate. From the calculation results, we found that as the channel height of the separator decreased, the pressure drop increased exponentially. In addition, it was found that as the channel height of the separator decreased, the gas flow resistance inside the unit cell increased, and the flow resistance increased the pressure drop, thereby improving the flow uniformity inside the stack. Finally, the calculation results showed that as the fuel and oxygen utilization increased, the flow uniformity also improved.

Kinetic Parameter Estimation of Ru Catalyst for Steam Methane Reforming (증기 메탄 개질 반응의 Ru 촉매 Kinetic Parameter 예측)

  • JOO, CHONGHYO;KIM, MYUNGJUN;CHO, HYUNGTAE;LEE, JAEWON;KIM, JUNGHWAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.499-506
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    • 2022
  • This study proposes kinetic parameters of Ru catalyst for steam methane reforming (SMR). First, extensive experiments are performed under different SMR conditions to evaluate performance of the catalyst in SMR. Second, a kinetic model is designed and developed for parameter estimation and validation using gPROMS. Finally, estimated parameters are fitted to the kinetic model and then, the model results are compared with the experimental data. The model results are in a good agreement with the experimental data.

CFD Numerical Calcultion for a Cavity Matrix Combustor Applying Biogas (바이오가스 적용 캐비티 매트릭스 연소기 CFD 수치연산)

  • CHUN, YOUNG NAM;AN, JUNE
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.598-606
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    • 2022
  • With the advancement of industry, the use of various sustainable energy sources and solutions to problems affecting the environment are being actively requested. From this point of view, it is intended to directly burn unused biogas to use it as energy and to solve environmental problems such as greenhouse gases. In this study, a new type of cavity matrix combustor capable of low-emission complete combustion without complex facilities such as separation or purification of biogas produced in small and medium-sized facilities was proposed, and CFD numerical calculation was performed to understand the performance characteristics of this combustor. The cavity matrix combustor consists of a burner with a rectangular porous microwave receptor at the center inside a 3D cavity that maintains a rectangular parallelepiped shape composed of a porous plate that can store heat in the combustor chamber. As a result of numerical calculation, the biogas supplied to the inlet of the combustor is converted to CO and H2, which are intermediate products, on the surface of the 3D matrix porous burner. And then the optimal combustion process was achieved through complete combustion into CO2 and H2O due to increased combustibility by receiving heat energy from the microwave heating receptor.

Analysis of Thermal Flow Characteristics according to the Opening Ratio of High-Pressure Valve for Hydrogen Storage Tank (수소 저장 탱크용 고압 밸브의 개도율에 따른 열·유동 특성 분석)

  • JUNG, DA WOON;CHOI, JIN;SUH, HYUN KYU
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.525-533
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    • 2022
  • In this study, in order to numerically analyze the heat flow characteristics in the valve according to the opening rate for the solenoid valve for hydrogen supply applied to the hydrogen storage tank, flow characteristics were comparatively analyzed. Through the analysis of pressure and temperature distributions within the valve according to the high-pressure supply condition of 70 MPa or more, the heat flow characteristics in the valve, inlet and outlet passage according to the opening rate of the valve were identified. As a result a sudden change in the fluid behavior appears in the neck region of the valve, and it is understood that the flow separation caused by the flow path shape of the expanded tube has a dominant influence on the flow characteristics. And, it was confirmed that the shape of the valve seat is a factor significantly affecting the improvement of flow rate and differential pressure performance.

Deep Learning Based Electricity Demand Prediction and Power Grid Operation according to Urbanization Rate and Industrial Differences (도시화율 및 산업 구성 차이에 따른 딥러닝 기반 전력 수요 변동 예측 및 전력망 운영)

  • KIM, KAYOUNG;LEE, SANGHUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.591-597
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    • 2022
  • Recently, technologies for efficient power grid operation have become important due to climate change. For this reason, predicting power demand using deep learning is being considered, and it is necessary to understand the influence of characteristics of each region, industrial structure, and climate. This study analyzed the power demand of New Jersey in US, with a high urbanization rate and a large service industry, and West Virginia in US, a low urbanization rate and a large coal, energy, and chemical industries. Using recurrent neural network algorithm, the power demand from January 2020 to August 2022 was learned, and the daily and weekly power demand was predicted. In addition, the power grid operation based on the power demand forecast was discussed. Unlike previous studies that have focused on the deep learning algorithm itself, this study analyzes the regional power demand characteristics and deep learning algorithm application, and power grid operation strategy.

Mid-Temperature Operation Characteristics of Commercial Reforming Catalysts: Comparison of Ru-Based and Ni-Based Catalyst (상용 개질촉매의 중온 영역 운전 특성: Ru 촉매와 Ni 촉매 비교)

  • KIM, YOUNGSANG;LEE, KANGHUN;LEE, DONGKEUN;LEE, YOUNGDUK;AHN, KOOKYOUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.3
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    • pp.149-155
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    • 2021
  • Most of the reformer experiments have been conducted only in high-temperature operation conditions above 700℃. However, to design high efficiency solid oxide fuel cell, it is necessary to test actual reaction performance in mid-temperature (550℃) operation areas. In order to study the operation characteristics and performance of commercial reforming catalysts, a reforming performance experiment was conducted on mid-temperature. The catalysts used in this study are Ni-based FCR-4 and Ru-based RuA, RuAL. Experiments were conducted with a Steam-to-carbon ratio of 2.0 to 3.0 under gas hourly space velocity (GHSV) 2,000 to 5,000 hr-1. As a result, RuA and RuAL catalysts showed similar gas composition to the equilibrium regardless of the reforming temperature. However, the FCR-4 catalyst showed a lower hydrogen yield compared to the equilibrium under high GHSV conditions.

Optimization Process of Type 4 Composite Pressure Vessels Using Genetic and Simulated Annealing Algorithm (유전 알고리즘 및 담금질 기법을 활용한 Type 4 복합재료 압력용기 최적화 프로세스)

  • SONG, GWINAM;KIM, HANSANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.4
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    • pp.212-218
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    • 2021
  • In this study, we conducted a design optimization of the Type 4 composite pressure vessels to enhance the pressure-resistant performance of the vessels while keeping the thickness of the composite layer. The design variables for the optimization were the stacking angles of the helical layers of the vessels to improve the performance. Since the carbon fibers are expensive material, it is desirable to reduce the use of the carbon fibers by applying an optimal design of the composite pressure vessel. The structural analysis and optimization process for the design of Type 4 composite pressure vessels were carried out using a commercial finite element analysis software, Abaqus and a plug-in for automated simulation, Isight, respectively. The optimization results confirmed the performance and safety of the optimized Type 4 composite pressure vessels was enhanced by 12.84% compared to the initial design.