• Korean Journal of Materials Research
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• v.7 no.4
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• pp.347-353
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• 1997

BaTiO$_{3}$물질은 뛰어난 유전체로 널리 알려져 왔으며 특히 Heywang등이 제안한 PTCR특성은 이 물질의 응용범위를 세라믹 필터, 회로보호소자, 온도감지소자 및 저항가열장치 등으로 확대시켰다. 이러한 특성의 발현기구는 아직까지 밝혀지지 않은 상태이지만 제 특성을 향상시키기 위한 노력은 계속되어왔다. 특히 개발목적에 맞게 온도에 따른 정저항 특성(PTCR; Positive temperature constnat of resistivity phenomena)을 설계하려는 시도가 계속되어 왔으며 그 중에서도 페로브스카아트계의 2가와 4가의 양이온 자리를 등가나 원자가가 다른 양이온으로 치환하여 특성을 개선하려는 시도가 계속되어 왔다. 특히 $Ca^{2+}$나 Sr$^{2+}$는 $Ba^{2+}$자리를 치환할 수 있는 물질로 개별적인 첨가에 대한 연구는 많은 연구자들에 의해 진행된 상태이지만 최종적인 영향이나 해석에 대해서는 연구자들간에 이견이 많은 상태이다. 이번 실험에서는 BaTiO$_{3}$계에 합성한 (Ca, Sr)TiO$_{3}$를 Ca와 Sr의 상대적인 비를 변화시키면서 전체적인 첨가량을 변화시켜 그에 따른 전기적 특성 및 미세구조를 살펴보았다. (Ca, Sr)TiO$_{3}$의 첨가로 상온저항 및 PTCR특성을 변화시킬 수 있었으며 이를 통해 PTCR물질의 활용범위를 넓힐 수 있는 발판을 마련할 계기가 되었다. 특히 기존의 연구가 주로 개별적인 Ca나 Sr의 첨가에 의한 미세구조와 전기적 특성변화의 연구에 치중해 있었던 것과는 달리 Sr과 Ca을 함께 치환하여 상대적인 비가 특성에 더 중요한 영향을 끼치는 것을 확인하였으며 적절한 합성비를 선택하면 퀴리온도에서의 저항변화폭을 유지하면서 상온저항을 낮출 수 있음을 확인하였다.문했던 연구소인 Shanghai Research Center of Biotechnology, Shanghai Institute of Industrial Microbiology 및 Scientific Research Institute of Food and Fermentation Industry을 소개하고저 한다. 짧은 기간의 방문이라 주로 해당연구소의 자체소개 자료를 중심으로 방문하면서 느낀점을 기술하고저 한다.초염기성암 기원의 사문암이 열수변질작용을 받아 생성되었음을 명확하게 지시하며, 따라서 활석 광석내에 존재하는 녹니석은 활석의 근원 광물로서 녹니석편암 및 녹니석 편마암 매의 녹니석이 활석화되고 남은 잔존광물이 아니라, 주변암에 의해 성분상의 영향을 받은 열수와 사문암과의 변질교대작용에 의한 활석화과정 중에 주로 생성된 것으로 추정된다. 이러한 결과는 연구지역의 활석광상이 초염기성암의 사문암화 작용과 활석화 작용의 두 가지 변질작용에 의해 형성되어졌음을 알려준다.농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았다이 낮았으나 통계학적 의의는 없었다[10.0%(4/40) : 8.2%(20/244), p>0.05]. 결론: 비디오흉강경술에서 재발을 낮추기 위해 수술시 폐야 전체를 관찰하여 존재하는 폐기포를 놓치지 않는 것이 중요하며, 폐기포를 확인하지 못한 경우와 이차성 자연기흉에 대해서는 흉막유착술에 더 세심한 주의가 필요하다는 것을 확인하였다. 비디오흉강경수술은 통증이 적고, 입원기간이 짧고, 사회로의 복귀가 빠르며, 고위험군에 적용할 수 있고, 무엇보다도 미용상의 이점이 크다는 면에서 자연기흉에 대해 유용한 치료방법임에는 틀림이 없으나 개흉술에 비해 재발율이 높고 비용이 비싸다는 문제가 제기되고 있는 만큼 더 세심한 주의와 장기 추적관찰이 필요하리라 사료된다.

• Economic and Environmental Geology
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• v.24 no.2
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• pp.83-96
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• 1991

Haenam pyrophyllite deposit occurred in the rhyolitic tuff of late Cretaceous age is located in the northern part of Haenam-gun, Jeonranam-do. The ore of the Haenam deposit is predominantly composed of pyrophyllite and illite accompanying such clay minerals as kaolinite, chlorite, and smectite. Pyrophyllite ore at the center of altered mass is often associated with kaolin minerals and high temperature minerals such as corundum, andalusite, and diaspore. On the basis of mineral assemblage the Haenam deposit can be devided into three alteration zones from the center to the margin of the deposit; the pyrophyllite zone, kaolinite zone, and illite zone. All alteration zones are associated with appreciable amounts of chalcedonic quartz. Those mineral assemblages indicate that hydrothermal solution which produced the Haenam deposit is strongly acidic solution with high silica and hydrogen activity and low $SO_4{^{2-}}$ activity. Discriminant analysis shows that $Na_2O$, $K_2O$, and $Al_2O$, of major elements are discriminant elements which classify alteration zones, while in case of trace elements Cr, Ni, and Sr turned out to be discriminant elements in this deposit. According to the mineral assemblage and illite geothermometry, pyrophyllite ore is considered to have been formed at about $240-290^{\circ}C$. K-Ar isotopic age for illite from this deposit indicates that it was formed at much the same age of later stage volcanics in the area, suggesting that the hydrothermal alteration of these deposits is associated with later volcanism of the area.

• Economic and Environmental Geology
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• v.46 no.3
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• pp.267-278
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• 2013

The East African Rift System(EARS) is known to be hosted epithermal Au-Ag deposits, and the best-known example is Main Ethiopian Rift Valley(MER) related to Quaternary bimodal volcanism. Large horst-graben system during rifting provides open space for emplacement of bimodal magmas and flow channel of geothermal fluids. In recent, large hydrothermally altered zones(Shala, Langano, and Allalobeda) and hot spring related to deeply circulating geothermal water have been increasing their importance due to new discoveries in MER and Danakil depression. The hot springs in Shala and Allalobeda occur as boiling pool and geyser on the surface, whereas some areas didn't observe them due to decreasing ground water table. The host rocks are altered to quartz, kaolinite, illite, smectite, and chlorite due to interaction with rising geothermal water. The hot springs in MER are neutral to slightly alkaline pH(7.88~8.83) and mostly classified into $HCO_3{^-}$ type geothermal water. They are strongly depleted in Au, and Ag, but show a higher Se concentration of up to 26.7 ppm. In contrast, siliceous altered rocks around hot springs are strongly enriched in Pb(up to 33 ppm, Shala), Zn(up to 313 ppm, Shala), Cu(up to 53.1 ppm, Demaegona), and Mn(up to 0.18 wt%t, Shala). In conclusion, anomalous Se in hot spring water, Pb, Zn, Cu, and Mn in siliceous altered rocks, and new discoveries in MER have been increasing potential for epithermal gold mineralization.

• Economic and Environmental Geology
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• v.50 no.4
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• pp.313-324
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• 2017

Tsogttsetsii area, an intrusive complex associated with Cu mineralization, is located in the South Gobi, Mongolia. We performed the cross geochemical and extended exploration survey in Tsogttsetsii area. Cu mineralization in Tsogttsetsii area is porphyry Cu type related with alkali granite intruded in Late Carboniferous to Early Permian. In the concentrated occurring to malachite appears extensively prophylitic alteration zone having a chlorite and epidote. As results of the survey, Cu contents of potable XRF and of chemical composition for altered rocks ranges 1.08 to 18.3% in the 30 points and 1.08 to 32.9% in the 13 points, respectively. Ore minerals identified in XRD analysis and polarizing microscope that samples of copper oxides were composed mainly of malachite, azurite, permingeatite and cuprite and the other minerals are pyrite, chalcopyrite, pyrargyrite, dickite, calcite, chlorite and epidote. Mineralization can be considered occurring to selectively some granite of the surrounding aplite and faults in the only upper part coming up the hydrothermal solution of the remaining residual magma after the aplite intrusion.

• Economic and Environmental Geology
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• v.44 no.4
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• pp.273-288
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• 2011

Chon-Ashuu copper mining claim area is located, in terms of the geotectonic setting, in the northern part of the suture line which is bounded with the marginal part of Issik-kul micro-continent on the southern part of North Tien-Shan terrane. The geological blocks of Chon-Ashuu districts belong to the southern tip of Kazakhstan orocline. The rock formation of this area are composed of the continental crust or/and arc collage and the paleo-continental fragments-accretionary wedge complex of pre-Altaid orogenic materials. ASI(Alumina Saturation Index) of Paleozoic plutonic rocks in Chon-Ashuu area belong to the peraluminous and metaluminous rocks which were generated from fractional crystallization of Island and volcanic arc crusts in syn-post collisional plate. The geology of the ChonAshuu area consists of upper Proterozoic and Paleozoic rock formations. According to Harker variation diagrams for Chon-Ashuu arenaceous sedimentary rocks, the silty sandstone of Chon-Ashuu area showing the mineralogical immaturity were derived from Island arc or the marginal environments of active continent in Cambro-Carboniferous period. Numerous intrusive rocks of Chon-Ashuu area are distributed along north east trending tectonic structures and are bounded on four sides by the conjugate pattern. The most common type of the plutonic rocks are granodiorite and monzodiorite. According to the molecular normative An-Ab-Or composition (Barker, 1979), the plutonic rocks in Chon-Ashuu area are classified into tonalite - trondhjemite - granodiorite (TTG) series which are an aggregation of rocks which is the country rock of copper mineralization, that are formed by melting of hydrous mafic crust at high pressure.

• 한국지구물리탐사학회:학술대회논문집
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• 2005.05a
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• pp.65-70
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• 2005

A low resistivity zone is found in many places such as a fractured fault zone, weathered zone and aquifer. The electrical resistivity is influenced mainly by pore fluid as well as the clay mineral types and contents, Hence, it is very important to understand the relationship between the electrical resistivity and clay contents associated with the low resistivity zone for geotechnical applications such as civil engineering. This study examines the characteristics of clay mineral types and contents to electrical resistivity through sample measurements, and proposes an expression relating the resistivity and clay content. The electrical resistivity is measured for an artificial agar specimen with clay minerals instead of a natural rock. The clay minerals used are Kaolinite and Montmorillonite. Montmorillonite shows remarkably lower resistivity than Kaolinite, although its clay content is fewer than that of Kaolinite. Also, the proposed expression shows a good correlation coefficient as high as 0.89 or more in all clay minerals.

• The Journal of Engineering Geology
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• v.18 no.4
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• pp.577-586
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• 2008

The formation of acid mine drainage is closely related to water chemistry and ochreous sprecipitates formed at the bottom of creeks because it is initially derived from the possible water-rock interaction in abandoned waste metals at the mine. According to analyses on water, precipitates, and alteration characters of ore metals in Dalseone mine, whitish precipitates formed at pHs above 5 while schwertmannite formed at pH $3{\sim}4$. Water chemistry vary with seasons. The water chemistry of the treatment site measured ir Octoter 2002 is characterized by lower pH, and higher Al, Zn, Cu contents relative to those in March, 2003. In the latter case, As and Cl contents are very high. $^{27}Al$ MAS NMR data show the presence of predominant octahedral Al in whitish precipitates. Metal ore minerals dissolve at margins, cleavage, or comer of crystals where reactive sites are potential. Pyrite dissolves, forming etch pits or smooth faces on the edge.

• The Journal of the Petrological Society of Korea
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• v.12 no.4
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• pp.196-206
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• 2003

The geochemical and mineralogical investigation on the rocks and repair material comprising of the Sungryemun (The 1st National Treasure) has been made. Rock of the Sungryemun is highly weathered coarse-grained calc-alkali granite. The rock consists mainly of quartz, perthite, plagioclase and biotite with small amounts of orthoclase, muscovite, chlorite and sericite, which are major weathering products from perthite. For obtaining informations about degree of weathering, mineral composition of the original rock calculated by CIPW norm and weathered rock composition determined by XRD quantitative analysis were plotted on a ternary diagram of quartz-potash feldspar-plagioclase. Original rock compositions are plotted on the central granite area. whereas weathered ones are plotted on the granite area close to quartz. The result means that quartz is more abundant in weathered rock, due to selective chemical weathering of potash feldspar and plagioclase over quartz. On the whole, surface of the rocks were black-coated, exfoliated and highly fractured due to the physical and chemical weathering and heavy load has made the cracks in the lower parts of the stone construction. Also, cement and nails, which was used as repair material, during the repair work in the early 1960's, has accelerated the weathering process. Furthermore, weathered conditions of repair materials are very severe. Therefore, it is very urgent to establish of the conservation plan for the Sungryemun.

• Journal of the Mineralogical Society of Korea
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• v.7 no.1
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• pp.14-24
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• 1994

The Sungsan clay deposits have been formed by the hydrothermal alteration of volcanic and volcanoclastic rocks of the Hwangsan Formation of Cretaceous age. Claystones are mainly composed of dickite, alunite, illitic minerals and tosudite. The mineralogical properties of clay minerals have been studied using X-ray diffraction analysis, electron microscopy, electron microprobe analysis, and infrared absorption analysis. The physicochemical condition for the clay deposits also have been studied by the activity diagrams and mineral assemblages. Dickite, the dominant mineral in clay deposits, occurs generally as massive aggregates. It shows book-structure of well-defined hexagonal plates. Chemistry of dickite agrees with its ideal formula. Peak depth ratios in infrared absorption spectra were used for discrimination between pure and mixture of kaolin minerals. Five hydrothermal alteration zones are divided according to the mineral assemblages. From center to margin, alunite, dickite, illite and albite zones are discernible. Quartz zone occurs as small lenticular form in dickite zone. The formation of dickite and illite zones are promoted by decreasing $a_{k^+}$. An increase in $a_{H_{2}SO_{4}}$ or $a_{K_{2}SO_{4}}$ is required for the formation of alunite zone. Estimated temperature of formation ranges 110-270 $^{\circ}C$

• Mineral and Industry
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• v.17 no.1
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• pp.1-15
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• 2004

장석은 복잡다단한 광물학적 특성에도 불구하고 그 물질적 이해와 용도 측면에서의 단순성 때문에 관련 산업 부문에서 부가가치 향상이 잘 이루어지지 않고 있는 실정이다. 현재 전 세계적으로 10위권 내의 생산 수준을 유지하는 국내산 장석의 광석 유형은 그 관물상과 산출상태에 따라 페그마타이트상 장석, 반화강암질 및 우백질 화강암상의 장석으로 구분 될 수 있다. 현재 국내에서 개발되고 있는 장석들로는 일반적으로 반화강암질 유형의 광석이 가장 흔하다. 이 유형의 광체들은 흔히 알바이트화 작용이나 K-부화를 수반하는 열수변질 작용을 받은 양상을 보이는 것이 특징이다. 광물특성 상으로는 K-장석에 속하는 광체들이 Na-장석 유형들 보다 상대적으로 흔하고 대체적으로 그 부존 규모도 큰 것으로 나타난다. 장석의 부가가치 향상을 위해서는 그 품위를 화학조성에만 의존하지 말고 광물조성 단위로 이해하는 방식이 요구된다. 일반적으로 이 광물자원의 요업적 용도 특성상, 광물특성 평가에서 가장 주요한 기준이 되는 사항은 화학조성, 특히 알칼리 조성, $AI_{2}O_{3}$ 함량 및 철분의 함유도인 것으로 판단된다. 그렇지만 앞으로 그 수요가 확장될 전망이 있는 충진재 용도로 사용될 경우에는 이 같은 화학적 특징보다는 장석광물의 조성과 제반 물성적 특성에 그 품질이 의존될 것으로 여겨진다. 이에 따라 장석 광석의 화학조성과 물성은 기본적으로 장석의 광물상과 조성에 의존된다는 지식기반 하에서, 장석의 품위는 물론 품질 특성 평가에 있어서도 화학조성에만 의존하지 말고 그 광물상과 광물특성도 고려해서 평가하는 지혜가 요구된다.