• Applied Chemistry for Engineering
• /
• v.9 no.6
• /
• pp.822-828
• /
• 1998

Binary system of water and polyoxyethylene dodecyl ether, $C_{12}H_{25}(OCH_2CH_2)nOH$, have been studied by $^1H$ NMR techniques. For n=5($C_{12}EO_5$) and n=8($C_{12}EO_8$), the self-diffusion coefficients of nonionic surfactants in the isotropic phase($L_1$) have been measured by using pulsed field gradient technique for a range of temperature and concentrations. In addition the line widths of the different proton signals have been monitored, and samples of some liquid crystalline characteristic were also studied. Dramatic Broadening of the methylene signals of the alkyl($C_{12}H_{25}$) chain is observed as the hexagonal liquid crystalline phase is approached in the $C_{12}EO_5-$water system, while only small broadening is observed in the $C_{12}EO_8-$water system. It was shown that there was a growth of $C_{12}EO_5$ micelles to rods with increasing concentrations, while the $C_{12}EO_8-$ micelles at low temperature remain small in the concentration range. The self-diffusion coefficients of the surfactants decrease rapidly with increasing concentration until a minimum is reached after which there is slow increase. The location of the minimum point occurs at lower concentrations the temperature is close to the cloud point, where the system separate into two isotropic phase. In the line width studies, broadening is found at a certain temperature interval when the concentration is increased in the $C_{12}EO_5$ system. The results indicate that the surfactant aggregates grow in size at the cloud point is approached. The aggregates seem to be flexible and probably not to be of a definite shape close to the cloud point. In the $C_{12}EO_8$ system, the micelles are much less affected by an increase in temperature and micellar growth can't be unambiguously established. The methylene signals of the ethylene oxide moieties consistantly show narrower $^1H$ signals, showing that in the aggregates they are less ordered than the chain methylenes. The various changes in aggregate size and shape are correlated with the stability ranges of the isotropic and liquid crystalline phases according to phase diagrams from the literature. Both aggregate size and phase structure are in qualitative agreement with concentration based on the effective shape of the molecules at different temperature and concentration.

• Journal of Magnetics
• /
• v.15 no.2
• /
• pp.61-63
• /
• 2010

We used $^1H$ nuclear magnetic resonance (NMR) to study the phase transitions and molecular dynamics in a characteristic ferroelectric liquid crystal with a carbon number n = 7, S-2-methylbutyl 4-n-heptyloxybiphenyl-4'-carboxylate (C7). The results were compared with those of our recent work on S-2-methylbutyl 4-n-octanoyloxybiphenyl-4'-carboxylate (C8), with a carbon number n = 8. While the recrystallization and isotropic phase transitions exhibited a first-order nature in the $^1H$ NMR spin-lattice and spin-spin relaxation measurements, a second-order nature was shown at the Sm-A - Sm-$C^*$ liquid crystalline phase transition. A soft-mode anomaly arising from the tilt angle amplitude fluctuation of the director, of which only a hint had been noticed in the C8 system, was manifested in the C7 system at this transition.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.33 no.5A
• /
• pp.517-525
• /
• 2008

In this paper, we cary out system level simulations to investigate the effect of cell shape(i.e., different base station displacements in the two directions defined by the street grid) on minimizing transmitter power, interference power, and blocking probability for CDMA system in urban microcellular environments. In urban microcell, path loss to the base station depends on the orientation of the street where the mobile is located. Interference from mobile stations to the base station in the reference cell is considered up to second tier. The wrap around method is used to include the second tier interference with realistic computational complexity without reducing the accuracy of interference calculations. The investigation shows that the transmitter power, interference power, and blocking probability in a cell can be reduced by proper selection of the efficient cell shape.

• Journal of Pharmaceutical Investigation
• /
• v.29 no.2
• /
• pp.99-103
• /
• 1999

Self-Emulsifying System(SES), an isotropic mixture of oil and surfactant which forms oil-in-water emulsion, is expected to improve in vitro drug dissolution and enhance in vivo drug absorption. A poorly water soluble drug, ibu-profen(IBP) was incorporated into the SES to improve absorption, and enhance bioavailability of drug. Medium chain triglyceride, glyceryl tricaprylate(GTC) as an oil, and Tween 85 as a surfactant were used to formulate SES. To characterize SESs with various concentrations of Tween 85, the phase separation and solubility of IBP-SEDDS containing IBP as a function of Tween 85 concentration were conducted, and the particle size was measured using photon correlation spectroscopic method. The SES with optimal concentration of Tween 85(35%(w/w)) was selected based on its high drug loading, small particle size and low surfactant concentration. After an oral administration of IBP-SEDDS and IBP suspension in methyl cellulose equivalent to 40.0 mg/kg to rats, the pharmacokinetic parameters were compared. The $C_{max}(163.17\;vs\;88.82\;{\mu}g/ml)$, $AUC(12897.01\;vs\;8751.13\;{\mu}g\;min/ml)$ and Bioavailability(86.44 vs 58.65%) significantly increased but $T_max(10\;vs\;20\;min)$ was significantly advanced. The current SEDDS containing IBP provide an alternative to improve an oral bio-availability of IBP.

• Proceedings of the Korean Society of Medical Physics Conference
• /
• 2002.09a
• /
• pp.376-378
• /
• 2002

This work was carried out to evaluate the basic performances for 4D CT, which employed continuously rotating conebeam. The performances were evaluated with the same method as the conventional CT, because the standard method of evaluating 4D CT has not yet been established, and we think this result was helpful to establish it. 4D CT can give dynamic volume imaging data continuously and with high-speed. The results were isotropic except for the evaluation of distortion in which small distortions gradually appeared as coming off the center of phantom in longitudinal direction.

• Proceedings of the Korea Water Resources Association Conference
• /
• 1987.07a
• /
• pp.113-122
• /
• 1987

A numerical simulation technique of three-dimensional finite difference model is developed to study the groundwater flow system in Dcjima, an upland area which faces Kasumigaura Lake. For general perspectives of the groundwater flow system, a steady state three-dimentional model is simulated. For the sedimentary mud formations which are found in the representative formation, three situations of hydraulic conductivity are considered, representing an isotropic condition and situations where the horizontal permeability is equal to 10 times and 100times of the vertical one. The finite difference grid used in the simulation has 60x50x30=90,000 nodes. A converged solution with a tolerance of 0.001 meter of hydraulic head is set. Having determined the flow net by using a steady state three-dimensional model. the results for the three cases of hydraulic conductivity are compared with the results of tracer methods (Bae and Kayane 1987) With the aid of four representative vertical cross-sections, groundwater flow systems in the study area are assumed. Water balances for the three cases indicate very good agreement between total recharge and discharge in each case Analyses of groundwater flow system based on the tritium concentrations and water quality measurements (Bae and Kayane 1987) are confirmed by the numerical simulation and the results obtained by these two methods appeared to be in close agreement.

• Proceedings of the KIEE Conference
• /
• 2006.04b
• /
• pp.140-142
• /
• 2006

Cogging torque is often a principal source of vibration, noise and difficulty of control in permanent-magnet brushless DC motors. Cogging torque can be minimized by sinusoidal air-gap flux density waveform because it is produced by the interaction of the rotor magnetic flux and angular variation in the stator magnetic reluctance. Therefore, this paper will present a design method of magnetization system of bonded isotropic neodynium-iron-boron(Nd-Fe-B) magnets in ring type with sinusoidal air-gap flux density distribution and low manufacturing cost. An analytical technique of magnetization makes use of two-dimensional finite element method(2D FEM) and Preisach model that expresses the hysteresis phenomenon of magnetic materials in order for accurate calculation.

• Journal of the Korea Computer Industry Society
• /
• v.8 no.1
• /
• pp.57-64
• /
• 2007

In the paper, considers the design of a detection system, consisting of n identical detectors, to process the sum of spatially invariant signal fields $S_\jmath(t)$, an additive, homogeneous, spatially isotropic (in the array plane x). covariance_separable, and zero_mean Gaussian random noise field n(t, x). consisting of arrey receivers for use in optical communication through optimum turbulence atmosphers and covriance_circuit, staistical analysis through detection the maximum gain are compared with analysis theoretical analysis theoretical value and get through experimental measured value, as well the measured valus are confirmed to agreement joint Gaussian theoretical curves.

• Journal of the Korean Society of Safety
• /
• v.14 no.3
• /
• pp.12-17
• /
• 1999

In this study, a drop-weight impact tester was manufactured to assess the strength of CFRP laminate plates. The tests were conducted on several laminates of different ply orientation. A system for the impact strength of CFRP laminates was made considering stress wave propagation theory using drop-weight impact tester as one of impact test. Results indicate that absorbed energy of quasi-isotropic specimen, haying four interfaces is higher than that of orthotropic laminates with two interfaces. Absorbed energy in the specimen that ply number, interface number and fiber stacking sequences is same but having hybrid is higher than that of orthotropic laminates without hybrid.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.18 no.11
• /
• pp.2846-2859
• /
• 1994

This work deals with kinematic analysis of fault-tolerant 3 degree-of-freedom spherical modules which have force redundancies in its parallel structure. The performance of a redundantly actuated four-legged module with no actuator failure, a single actuator failure, partial and half failure of dual actuator are compared to that of a three-legged module, in terms of maximum force transmission ratio, isotropic characteristics, and fault-tolerant capability. Additionally, a system with an excess number of small floating actuators is considered, and the contribution of these small actuators to the force transmission and fault-tolerant capability is evaluated. This study illustrates that the redundant actuation mode allows significant saving of input actuation effort, and also delivers a fault tolerance.