• 제목/요약/키워드: Isotropic Materials Properties

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Characterization of the effect of He+ irradiation on nanoporous-isotropic graphite for molten salt reactors

  • Zhang, Heyao;He, Zhao;Song, Jinliang;Liu, Zhanjun;Tang, Zhongfeng;Liu, Min;Wang, Yong;Liu, Xiangdong
    • Nuclear Engineering and Technology
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    • v.52 no.6
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    • pp.1243-1251
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    • 2020
  • Irradiation-induced damage of binderless nanoporous-isotropic graphite (NPIG) prepared by isostatic pressing of mesophase carbon microspheres for molten salt reactor was investigated by 3.0 MeV He+ irradiation at room temperature and high temperature of 600 ℃, and IG-110 was used as the comparation. SEM, TEM, X-ray diffraction and Raman spectrum are used to characterize the irradiation effect and the influence of temperature on graphite radiation damage. After irradiation at room temperature, the surface morphology is rougher, the increase of defect clusters makes atom flour bend, the layer spacing increases, and the catalytic graphitization phenomenon of NPIG is observed. However, the density of defects in high temperature environment decreases and other changes are not obvious. Mechanical properties also change due to changes in defects. In addition, SEM and Raman spectra of the cross section show that cracks appear in the depth range of the maximum irradiation dose, and the defect density increases with the increase of irradiation dose.

Synthesis and Properties of Unsymmetric Dimesogenic Liquid Crystal Compounds Containing Lateral Substituent (측면에 치환기를 포함하고 있는 비대칭 이메소젠 액정화합물의 합성 및 성질)

  • Park, Jong-Ryul;Cho, Kuk Young;Bang, Moon-Soo
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.280-286
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    • 2015
  • Two series of unsymmetric dimesogenic compounds containing a butylene or pentamethylene group as the flexible spacer were synthesized and their thermal and mesomorphic properties were studied. Mesogenic groups of the synthesized compounds consisted of a cholesteryl and an azobenzene group with lateral substituent. Chemical structures and mesomorphic properties of the synthesized compounds were investigated by FT-IR, $^1H$-NMR, differential scanning calorimeter (DSC), and polarizing optical microscope (POM). All synthesized compounds, apart from $D5-OCH_3$, showed enantiotropic liquid crystal phases. Compounds having an even number of carbon atoms in the flexible spacer exhibited wide mesophase temperature ranges and high isotropic transition temperatures. Regarding the effect of lateral substituents, compounds with bulky substituents exhibited decreased mesophase temperature ranges and isotropic transition temperatures, while those with polar substituents showed the increased thermal stability of the smectic phase.

Experimental Analysis for Core Losses Prediction in Electric Machines by Using Soft Magnetic Composite (복합 연자성 소재의 전동기 코어손실 예측을 위한 실험적 분석)

  • Park, Eui-Jong;Kim, Yong-Jae
    • The Journal of the Korea institute of electronic communication sciences
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    • v.16 no.3
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    • pp.471-476
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    • 2021
  • Soft magnetic composite (SMC) materials based on powder metallurgy have a number of advantages over the conventional electrical steel sheets commonly used in electric machines. Thus, technologies related to these materials have shown significant improvement in recent years. In general, SMCs are magnetically isotropic owing to the shape of the powder, which makes them suitable for the construction of electric machines with three-dimensional flux and complex structures. However, the materials with isotropic magnetic properties (such as SMCs) have complex vector hysteresis; thus, it is very difficult to predict accurate loss properties. Therefore, we manufactured ring-type specimens of electrical steel sheets and SMC, which analyzed their magnetic properties according to the specimen size, and performed the electromagnetic field analysis of a high-speed permanent magnet (PM) motor driven at 800 Hz or higher using the measured magnetic information to compare the core loss of the motor. The reliability of this paper has been verified by measuring the efficiency after manufacturing the motor.

Fracture Properties of Nuclear Graphite Grade IG-110 (원자로용급 흑연인 IG-110의 파괴특성)

  • Han, Dong-Yun;Kim, Eung-Sun;Chi, Se-Hwan;Lim, Yun-Soo
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.439-444
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    • 2006
  • Artificial graphite generally manufactured by carbonization sintering of shape-body of kneaded mixture using granular cokes as filler and pitch as binder, going through pitch impregnation process if necessary and finally applying graphitization heat treatment. Graphite materials are used for core internal structural components of the High-Temperature Gas-cooled Reactors (HTGR) because of their excellent heat resistibility and resistance of crack progress. The HTGR has a core consisting of an array of stacked graphite fuel blocks are machined from IG-110, a high-strength, fine-grained isotropic graphite. In this study, crack stabilization and micro-structures were measured by bend strength and fracture toughness of isotropic graphite grade IG-110. It is important to the reactor designer as they may govern the life of the graphite components and hence the life of the reactor. It was resulted crack propagation, bend strength, compressive strength and micro-structures of IG-110 graphite by scanning electron microscope and universal test machine.

Determination of the elastic properties in CFRP composites: comparison of different approaches based on tensile tests and ultrasonic characterization

  • Munoz, Victor;Perrin, Marianne;Pastor, Marie-Laetitia;Welemane, Helene;Cantarel, Arthur;Karama, Moussa
    • Advances in aircraft and spacecraft science
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    • v.2 no.3
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    • pp.249-261
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    • 2015
  • The mechanical characterization of composite materials is nowadays a major interest due to their increasing use in the aeronautic industry. The design of most of these materials is based on their stiffness, which is mainly obtained by means of tensile tests with strain gauge measurement. For thin laminated composites, this classical method requires adequate samples with specific orientation and does not provide all the independent elastic constants. Regarding ultrasonic characterization, especially immersion technique, only one specimen is needed and the entire determination of the stiffness tensor is possible. This paper presents a study of different methods to determine the mechanical properties of transversely isotropic carbon fibre composite materials (gauge and correlation strain measurement during tensile tests, ultrasonic immersion technique). Results are compared to ISO standards and manufacturer data to evaluate the accuracy of these techniques.

Molecular Dynamics Study on Mechanical Behavior and Load Transfer of CNT/PET Nanocomposites : the Effects of Covalent Grafting (탄소나노튜브/폴리에스터 복합재의 역학적 거동과 하중전달에 관한 분자 동역학 전산모사 : 그래프팅 가공의 영향)

  • Jin, Juho;Yang, Seunghwa
    • Composites Research
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    • v.30 no.3
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    • pp.193-201
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    • 2017
  • Molecular dynamics simulation and the Mori-Tanaka micromechanics study are performed to investigate the effect of the covalent grafting between CNT and polyester on the mechanical behavior and load transfer of nanocomposites. The transversely isotropic stress-strain curves are determined through the tension and shear simulations according to the covalent grafting. Also, isotropic properties of randomly dispersed nanocomposites are obtained by orientation averaging the transversely isotropic stiffness matrix. By addressing the grafting, the transverse Young's modulus and shear moduli of the nanocomposites are improved, while the longitudinal Young's modulus decreases due to the degradation of the grafted CNT.

Preparation of Carbon Fiber from Heavy Oil Residue through Bromination

  • Park, Young-Ok;Yang, Kap-Seung
    • Fibers and Polymers
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    • v.2 no.4
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    • pp.178-183
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    • 2001
  • A pitch precursor for a general purpose carbon fiber was prepared by condensation of pyrolized fuel oil (petroleum residual oil) with bromine under nitrogen blowing. such a condensation raised the softening point of the pitch from 4$0^{\circ}C$ to $265^{\circ}$ with a yield of 43%. The pitch precurosr showed an enhanced aromaticity and enlarged molecular size, which led to a reduction in molecular mobility and optical isotropy. The precursor was spun into fibers of $20\mu\textrm{m}$ diameter at a take-up speed of 700m/min. The fiber was stepwise stabilized in air and carbonized in Ar gas to obtain an isotropic carbon fiber. The carbon fiber exhibited tensile strengths of 500-800 ㎫though the fiber was formed via a crude method. The electric conductivity of the carbon fiber was relatively high, 2.2$\times$$10^2$S/cm, sufficient to be used as electrode materials.

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Sound Absorption Effects in a Rectangular Cavity According to the Surface Impedance of Wall (벽면의 임피던스변화에 따른 폐공간 내부에서의 음장특성 분석)

  • 오재응;김상헌;도중석
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1997.04a
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    • pp.687-694
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    • 1997
  • The anisotropy and shape of distributed piezopolymer actuator have advantages over isotropic piezo ceramic materials, since these features of PVDF can be utilized as another design variable in control application. This study is interested in the reduction of sound transmission through elastic plate into interior space by using the PVDF actuator. The plate-cavity system is adopted as a test problem. The vibration of composite plate and the sound fields through plate are analyzed by using the coupled finite element and boundary element method. Some numerical simulations are performed on sound transmission through elastic plates. To investigate the effects of anisotropy and shape of distributed piezopolymer actuator, various kinds of distributed PVDF actuators are applied in sound control simulation for isotropic and anisotropic plates. The PVDF actuators applied are different from each other in their shapes and laminate angles. The results of control simulation show that the control effectiveness of distributed PYDF actuator can be enhanced by using the coupling between shape of actuator and vibration modes of structure and the anisotropy of piezoelectric properties of PVDF.

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Bulk graphite: materials and manufacturing process

  • Lee, Sang-Min;Kang, Dong-Su;Roh, Jea-Seung
    • Carbon letters
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    • v.16 no.3
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    • pp.135-146
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    • 2015
  • Graphite can be classified into natural graphite from mines and artificial graphite. Due to its outstanding properties such as light weight, thermal resistance, electrical conductivity, thermal conductivity, chemical stability, and high-temperature strength, artificial graphite is used across various industries in powder form and bulk form. Artificial graphite of powder form is usually used as anode materials for secondary cells, while artificial graphite of bulk form is used in steelmaking electrode bars, nuclear reactor moderators, silicon ingots for semiconductors, and manufacturing equipment. This study defines artificial graphite as bulk graphite, and provides an overview of bulk graphite manufacturing, including isotropic and anisotropic materials, molding methods, and heat treatment.

Magnetic Properties of Sr-ferrite Powder Prepared by Intensive Mechanical Milling Technique

  • Kwon, H.W.;Bae, J.W.
    • Journal of Magnetics
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    • v.8 no.3
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    • pp.118-120
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    • 2003
  • As an alternative promising way of producing high coercivity Sr-ferrite for a permanent magnet application, intensive mechanical milling process was applied to the raw materials of the Sr-ferrite with different composition. Synthesising reactivity for the Sr-ferrite of the mechanically milled raw material containing $SrCO_3$, $La_2O_3$, $Fe_2O_3$, $Co_3O_4$, and $SiO_2$ was inferior to that of the raw material containing $SrCO_3$ and $Fe_2O_3$, The Sr-ferrite prepared from mechanically milled raw materials had profoundly improved magnetic properties compared to the Sr-ferrite prepared by conventional method. Beneficial effect of the substituting ($La_2O_3$, $Co_3O_4$) and additive ($SiO_2$) oxides for improving the magnetic properties was not exploited in the Sr-ferrite prepared from the mechanically milled raw material. The Sr-ferrite powder prepared from the mechanically milled raw materials was magnetically isotropic in nature.