• Journal of the Mineralogical Society of Korea
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• v.28 no.2
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• pp.187-193
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• 2015

The purpose of the present study is to trace the provenance of lead raw materials using the lead isotope ratio of 9 lead glasses excavated from the Sarira hole of Mireuksaji stone pagoda and to determine correlation between them and other lead glasses excavated from the Wanggungri site. The results of chemical analysis of the 9 lead glasses show that they are common lead glass system($PbO-SiO_2$) with respect to the contents of PbO (70 wt.%) and $SiO_2$ (30 wt.%). The lead isotope ratios of them plot to northern Korean peninsula when applied to the distribution map of lead isotopes of East Asia. On the other hand, southern Korean peninsula is verified as the main deposits of the lead ore in the distribution map of lead isotopes of South Korea. With respect to the results, it is notable that the provenance of the 9 lead glasses can be very different depending on the distribution map. In addition, a comparative study between them and the lead glasses excavated from the Wanggungri which was built in the same region and period shows that their lead isotopes are highly correlated.

• Korean Journal of Heritage: History & Science
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• v.49 no.3
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• pp.4-11
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• 2016

This study compares eight bronze spoons in the Goryeo Dynasty and analyzes their components and lead isotopes in order to confirm the relationship between their production sites and excavation sites. Most of the excavated spoons have elliptical heads, and their handles are categorized into two types. Bronze spoons are made of binary Cu-Sn alloys, but Pb is not added. The same artifacts can have different trace elements depending on location, and the spoons had high Ag content. According to an analysis of their lead isotopic ratio, they were made with raw materials produced in Zone 3 of the South Korean galena map. If the data of the trace elements in the raw ores of the bronze is accumulated, it can be used to indicate the provenance of the artifacts.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.3
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• pp.174-182
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• 2011

The present study evaluated the major lead sources in a steel metallurgy industrialized city by measuring lead isotopes/lead concentrations of ambient air and potential sources in an industrial area and residential areas according to relative distance. The quality control program obtained during the measurement procedure for lead isotopes and concentrations exhibited $0.5ng/m^3$ for method detection limit, more than 90% for recoveries of standard particulate matters, and lower than 0.2% for reproducibility errors of four lead isotopes ($^{204}Pb$, $^{206}Pb$, $^{207}Pb$, $^{208}Pb$). For all three lead isotope ratios ($^{206}Pb/^{204}Pb$, $^{207}Pb/^{206}Pb$, $^{208}Pb/^{206}Pb$), the ratios were obtained in the industrial area were closer to nearby residential area than those of a residential area far away from the industrial area, thereby suggesting that lead sources were more similar each other in the industrial and nearby residential area. Furthermore, for both summer and winter seasons ambient lead concentrations were more than four times higher in the industrial area than in the residential areas and in turn, they were higher in the nearby residential area compared with the far-away residential area. As a result, it was suggested that lead emitted from the industrial area would influence more the ambient lead in the nearby residential area than the far-away residential area. Both slag and traffic emissions are likely to be major lead sources in the industrial and nearby residential areas, since their three lead isotope ratios ($^{206}Pb/^{204}Pb$, $^{207}Pb/^{206}Pb$, $^{208}Pb/^{206}Pb$) were similar to the ratios obtained from ambient air of these two areas. In addition, the lead isotope ratios revealed different pattern between seasons, and the ambient lead concentrations were higher for winter than for summer.

• Economic and Environmental Geology
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• v.57 no.3
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• pp.343-352
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• 2024

Composition analysis and lead isotope ratio analysis were conducted to determine the coloring machanism on lead glaze used in Gyeongbokgung Palace and the provenance of the lead used as a flux. 31 blue tiles were classified into green, blue, and yellow. The chemical analysis of lead glazes on the blue tiles revealed that Pb, Si, and Cu were the main components, and trace amounts of Fe, Ca, Mg, and Al were detected. The Cu content was high in blue lead glaze, while Cu was not detected in yellow or brown lead glaze which instead had high Fe content. Therefore, it was found that lead was used as a flux and copper oxide as a coloring agent in the production of lead glaze. In addition, the lead isotope ratios of the lead glaze used in the blue tiles of Gyeongbokgung palace were plotted in zone 3 on the distribution map of lead isotope ratios on the Korean Peninsula, which includes Chungcheong-do and Jeolla-do. It is presumed that the flux for the lead glaze was sourced from galena found in these regions. The lead isotope ratios of the green glaze from the Three Kingdoms and Unified Silla period were mostly located outside the Korean Peninsula, showing that the provenance of lead had changed. In particular, the lead isotope ratios of the green glaze from the Three Kingdoms and Unified Silla period suggest exchange with neighboring countries. Also the lead isotope ratios of the green glazes from the same temple are different, so it is believed that they were made at different times or in different workshops.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.25 no.3
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• pp.392-404
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• 2015

Objectives: This study measured and analyzed the concentrations of crystalline silica, elemental carbon and the contribution ratio of pollutants which influence environmental and respiratory disease around the Ansim Briquette Fuel Complex in Daegu, Korea. Methods: We analyzed the crystalline silica and elemental carbon in the air according to FTIR(Fourier Transform Infrared Spectroscopy) and NIOSH(National Institute of Occupation Safety and Health) method 5040, respectively. In addition, lead stable isotopes, and carbon and nitrogen stable isotopes were analyzed using MC-ICP/MS(Multi Collector-Inductively Coupled Plasma/Mass Spectrometer), and IRMS(Isotope Ratio Mass Spectrometer), respectively. Results: The concentration of crystalline silica in the direct exposure area around the Ansim Briquette Fuel Complex was found to be $0.0014{\pm}0.0005mg/Sm^3$, but not to exceed the exposure standards of the ACGIH(American Conference of Governmental Industrial Hygienists). In the case of the autumn, the direct exposure area was found to show a level 2.5 times higher than the reference area, and on the whole, the direct exposure area was found to have a level 1.4 times higher than the reference area. The concentration of elemental carbon in the direct exposure area and in the reference area were found to be $0.0014{\pm}0.0006mg/Sm^3$, and $0.0006{\pm}0.0003mg/Sm^3$, respectively. This study confirmed the contribution ratio of coal raw materials to residentially deposited dusts in the area within 500 meters from the Ansim Briquette Fuel Complex and the surrounding area with a stable isotope ratio of 24.0%(0.7-62.7%) on average in the case of carbon and nitrogen, and 33.9%(26.6-54.1%) on average in the case of lead stable isotopes. Conclusions: This study was able to confirm correlations with coal raw materials used by the Ansim Briquette Fuel Complex and the surrounding area. The concentration of some pollutants, crystalline silica, and elemental carbon emitted to the direct-influence area around the Ansim Briquette Fuel Complex were relatively higher than in the reference area. Therefore, we need to impose continuous and substantive reduction countermeasures in the future to prevent particulate matter and coal raw materials in the study area. It is time for the local government and authorities to prepare active administrative methods such as the relocation of Ansim Briquette Fuel Complex.

• Analytical Science and Technology
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• v.25 no.6
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• pp.429-434
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• 2012

The objective of this study was to identify Pb pollution sources of sediments in Lake Andong. We analysed Pb isotopes in sediments from Lake Andong, soils and mining tails from the watershed as well as sludges and wastewater from zinc smelting facilities which exists in upper stream of Lake Andong. The Pb isotope ratios ($^{207}Pb/^{206}Pb$ and $^{208}Pb/^{206}Pb$) for sediments are $0.827{\pm}0.004$ and $2.041{\pm}0.015$, which showed similar values with those of mining tails, $0.815{\pm}0.002$ and $2.016{\pm}0.006$, respectively. The isotopic ratio values of soils existed in the range of 0.756~0.881 and 1.872~2.187. In imported zinc ores, the isotopic ratio values existed in the range of 0.816~0.956 (mean 0.832) and 2.029~2.219 (mean 2.059). These values were similar to those in zinc and lead concentrate originated from Canada and South America. Additionally, isotopic ratio values for sludge and wastewater were $17.515{\pm}0.155$, $15.537{\pm}0.018$, and $37.357{\pm}0.173$, respectively. The Pb isotopic ratio of sediments showed binary combination patterns with soil and mining tails, which were similar to those for Korean Pb ore.

• Analytical Science and Technology
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• v.5 no.2
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• pp.191-197
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• 1992

An ancient Korean bronze dagger excavated from Yongjai-ri, Iksan-kun, presumed to be manufactured in the pre-historical age, was examined by means of chemical analysis, energy dispersive spectrometry, optical and scanning electron microscopy. Also the measurement of lead isotope ratios was carried out in order to predict the site where raw materials were produced. The composition was identified as 75.3% Cu, 17.1% Sn and 6.8% Pb which was a typical composition of Korean bronze dagger. The microstructure was consisted of ${\alpha}$ and (${\alpha}+{\delta}$) eutectoid. The (${\alpha}+{\delta}$) eutectoid can be easily corroded in comparison with ${\alpha}$. The segregation was frequently observed in the interior of the sample. According to the lead isotopes ratios, raw materials have possibility to be from North China.

• Conservation Science in Museum
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• v.19
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• pp.69-82
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• 2018

The gilt-bronze standing Buddha and bronze standing Buddha statues excavated from Yeongguksa Temple in Yeongdong, currently held in the collection of the Cheongju National Museum, underwent conservation treatment after scientific study. Materials analysis showed that the gilt-bronze statue was made with a ternary alloy of copper, tin, and lead, while the bronze statue is of a binary alloy of copper and tin. The analysis also revealed that the bronze statue contains gold, and it is therefore recommended to change its description to gilt-bronze standing Buddha. The gilt-bronze statue appears to have been made with lead produced in Korea. The material observed on the surface that is presumed to have been used as an adhesive for the gold coloring is thought to be lacquer. For conservation treatment, the statues were minimally cleaned using physical and chemical methods and were treated through consolidation and protective coating.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.4
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• pp.219-226
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• 2021

We examined component analysis and lead isotope ratio analysis to find out the relationship between the excavation and the production site of 25 bronze weapons from prehistoric ages. All 25 bronze weapons are ternary alloys of copper-tin-lead and lead is artificially added. The lead isotope ratios of 25 bronze weapons show that bronze are made by raw materials in the southern regions of the Korean Peninsula, including northern China. The raw materials of narrow-shaped bronze dagger are supplied in zone 1-3 and northern China. In addition, provenance of lead for bronze halberd and pearhead are the rest of the region except for zone 1 and zone 4. Silver are enriched in most samples and zinc and cobalt are deficient. Arsenic and antimony detected only specific samples and can be used as critical parameter for provenance study. Lead isotopes and trace elements of archaeological bronzes will provide conservation scientist with useful tool to study the provenance of raw materials