• 한국염색가공학회지
• /
• 제11권5호
• /
• pp.38-43
• /
• 1999

A calculation method of optimum parameters on dual adsorption isotherm system was examined. The optimum parameters were obtained by non-linear regression analysis based upon a limited solute concentration of dual adsorption isotherm. The results were analyzed with adducing experimental data of formerly reported treaties. The percentage mean deviation of dual adsorption equation calculated with optimum parameters was less than about 5% of experimental data, which was far less than results obtained with parameters of the adduced treatises.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 1998년도 가을 학술발표회 논문집
• /
• pp.367-372
• /
• 1998

• Carbon letters
• /
• 제10권1호
• /
• pp.23-32
• /
• 2009

The adsorption of phenolic compound resorcinol on activated carbons prepared from Moringa oleifera (Drumstick bark) has been investigated. Activated carbon was prepared by impregnating Moringa oleifera with 50% phosphoric acid in the ratio of 1:1 and 1:2(w/w), designated as MOAC1 and MOAC2. Equilibrium and isotherm studies were carried out. The influences of variables such as contact time, initial concentration of resorcinol, carbon dosage in the solution on percentage adsorption and adsorption capacity of the bark have been analysed. The equilibration time was found to be 4 h. Kinetics of resorcinol onto activated carbons was checked for pseudo first order and pseudo second order model. It was found that the adsorption of resorcinol follows pseudo second order kinetics for both MOAC1 and MOAC2. The isotherm data were correlated with isotherm models, namely Langmuir and Freundlich. Adsorption isotherms were satisfactorily fitted by both the Langmuir and Freundlich model for MOAC1 and MOAC2.

• 한국환경과학회지
• /
• 제6권5호
• /
• pp.531-539
• /
• 1997

Lead sorption performances by biomass of nonliving, dried marine brown algae Undaria phnaunda, Hlzikia hsyormls. and Sugassum fulvellum used as biosorbent materials were investigated. As the amount of biosorbent materials added was increased, the lead removal by biosorbent materials Increased but the lead biosorption capacities decreased. However, with increasing Initial lead concentration the lead biosorption capacities by the biosorbent materials Increased but lead removal efficiencies decreased. In the range of Initial lead concentration(Co) 10-500 mg/L the lead biosorption capacities and removal efficiencies by the biosorbent materials Increased with increasing pH. Among the biosorbent materials used in this study, the lead biosorption capacities decreased in the following sequence: U. plilnaunda > H. fusiformis > S. fulvellum. The lead biosorption by biosorbent materials were expressed by the Langmuir Isotherm better than the Freundlich Isotherm. The biosorption rate could be expressed by the first order reaction rate equation for initial lead concentration like that rad : 0.288Co for U. phanda, rad = 0.255Co for H. fusiformis, and rad : 0.161Co for S. fulvellum. Key words : Lead, biosorption, biosorbent, Undaria pinnatinda, Hiztkia fusiformis, Sargassum fulvellum, Langmuir isotherm, Freundlich isotherm, biosorption rate.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1992년도 하계학술대회 논문집 B
• /
• pp.864-867
• /
• 1992

This paper describes optimum conditions for depositing Langumuir Blodgett(LB) films. $\pi$-A isotherm characteristics were studied with the following species, $C_{18}$-Quinolium(TCNQ), $C_{22}$-Quinolium(TCNQ), Azobenzene, Arachidic Acid, by varing length of alkyl chains, temperacture, pH, spreading amount, barrier moving speed and etc. We have observed the change of $\pi$-A isotherm depending on the above variations. From there we investigate the depositing conditions of LB films for each material.

• Advances in environmental research
• /
• 제7권1호
• /
• pp.29-37
• /
• 2018

A simple mathematical model for predicting fixed bed adsorption dynamics is described. The model is characterized by a linear adsorption isotherm and a linear driving force expression for mass transfer. Its analytic solution can be approximated with an algebraic equation in closed form which is easily evaluated by spreadsheet computation. To demonstrate one application of the fixed bed model, a previously published adsorption system is used as a case study in this work. The adsorption system examined here describes chromium breakthrough in a fixed bed adsorber packed with imidazole functionalized adsorbent particles and is characterized by a nonlinear adsorption isotherm. However, the equilibrium behavior of the fixed bed adsorber is in essence governed by a linear adsorption isotherm due to the use of a low influent chromium concentration. It is shown that chromium breakthrough is predicted reasonably well by the fixed bed model. The model's parameters can be easily extracted from independent batch experiments. The proposed modeling approach is very simple and rapid, and only Excel is used for computation.

• 한국결정성장학회지
• /
• 제12권3호
• /
• pp.115-119
• /
• 2002

흡착열 공간분포함수를 외형적으로 포함하는 흡착등온식을 형식화한다. 요철모형 흡착열 공간분포함수를 사용하여 우리가 유도해낸 흡착등온식을 직접 계산해 보고, 계산 결과로부터 모형계의 흡착특성을 분석한다. 이를 통하여 우리가 새로이 형식화한 흡착등온식의 유용성 여부를 확인한다. 본 논문은 통계열역학이 적용되었다.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
• /
• 제1권2호
• /
• pp.157-166
• /
• 1997

The biosorption performances of copper were investigated by the immobilized biomass of nonliving marine brown algae Undaria pinnatifida by each of the Ca-alginate method(Ca-ALG), Ba-alginate method(Ba-ALG), polyethylene glycol method(PEG), and carrageenan method (CARR). The copper removal performance increased but the copper uptake decreased as the biomass amount was increased. However, the copper uptake by the immobilized biomass increased with increasing initial copper concentration. Among the immobilization methods, the copper uptake decreased in the following sequence: Ca-ALG > Ba-ALG > PEG > CARR. The pattern of copper uptake by the immobilized biomass fitted the Langmuir isotherm better than the Freundlich isotherm. Desorption of deposited copper with 0.05 ~0.5M HCI, resulted in no changes of the copper uptake capacity of the immobilized biomass by the immobilization methods except for PEG, through five subsequent biosorption/desorption cycles. There was no damage to the immobilized biomass which retained its macroscopic appearance in repeated copper uptake/elution cycles.

• 한국농업기계학회:학술대회논문집
• /
• 한국농업기계학회 1996년도 International Conference on Agricultural Machinery Engineering Proceedings
• /
• pp.886-895
• /
• 1996

To fit the desorption isotherm and adsorption isotherm for Pangola grass, the modified Henderson model, Chung-Pfost model, modified Halsey model, and modified Oswin model were used to fit the experimental EMC /ERH data. A step-by -step ERH measuring technique was used in this study. The ERH data were collected at three temperature levels of 5 $^{\circ}C$, $25^{\circ}C$ and 5$0^{\circ}C$ for Pangola grass whole plant, stem , and foliage. The modified Halsey model has the best fit for both desorption isotherm and adsorption isotherm of Pangola grass whole plant as compared with other models.

• 자원리싸이클링
• /
• 제27권4호
• /
• pp.65-69
• /
• 2018

용매추출에서 등온추출곡선은 수상과 유기상에서 평형관계에 있는 농도를 나타낸다. 등온추출곡선과 조업선을 동시에 나타낸 McCabe-Thiele도는 물질 전달공정에서 여러 유용한 정보를 제공한다. 추출반응식과 평형상수를 알고 있는 경우 등온추출곡선을 계산으로 구하는 방법을 소개하였다. 또한 분배계수가 일정한 경우 금속 추출에 필요한 추출단수를 추산할 수 있는 Kresmer식을 소개하였다.