• 제목/요약/키워드: Isobutene

검색결과 15건 처리시간 0.019초

몬테 카를로 시뮬레이션을 이용한 2차원 X-선 검출기에 대한 연구 (A Study of 2-dimensional X-ray Detector using Monte Carlo Simulation)

  • 신형섭;이학재;이기성;강정원
    • 반도체디스플레이기술학회지
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    • 제9권4호
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    • pp.67-70
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    • 2010
  • X-ray absorption rate and multiplication factor of X-ray detector were calculated with Garfield code. High Z (= atomic number) was important factor to increase the absorption rate but low Z is also important to increase the multiplication. Five different gas composition were examined under the condition of 1400 V bias and 400 um gap. Xe 100% gas showed the highest absorption rate and He 96% + isobutene 4% showed the highest multiplication.

삼불화붕소 착물촉매를 사용한 중반응성 폴리부텐의 합성 (Synthesis of Mid-range Vinylidene Content Polyisobutylene by Using BF3/Alcohol Catalyst)

  • 박민섭;김영준
    • 공업화학
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    • 제29권3호
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    • pp.307-311
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    • 2018
  • 중반응성 폴리부텐을 루이스산 촉매를 이용하여 합성하였다. 40~70% 비닐리덴 함량, 수평균 분자량 500~1,000 g/mol, 동점도 20~210 cSt (at $100^{\circ}C$)을 지닌 중반응성 폴리부텐은 노르말프로판올 조촉매와 삼불화붕소 주촉매로 구성된 착물촉매를 사용하여 $-8{\sim}5^{\circ}C$, 2.5 kg 조건에서 가장 좋은 결과로 얻어졌다. 비닐리덴 함량은 반응 온도를 조절하여 쉽게 변화시킬 수 있었다.

Gas Chromatography 에 依한 까스炭化水素의 分析 (Analysis of Gas Hydrocarbons by Gas-Liquid Partition Chromatography)

  • 성좌경;노익삼;김정엽
    • 대한화학회지
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    • 제7권2호
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    • pp.128-132
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    • 1963
  • A study has been made on the applicability of gas-liquid partition chromatography to the qualitative and quantitative analysis of complex mixture of gaseous hydrocarbons. While phthalate columns are widely used for this $purpose^9$, they separates neither saturated hydrocarbons from the unsaturated nor n-butane from isobutene or butene-1, therefore combined columns such as phthalate and dimethylsulfolane have been used for the perfect separation of gaseous hydrocarbons. It is shown by this study, however, that hydrocarbons having $C_1$ through $C_4$ can be separated with a 2-meters tetraethyleneglycol dimethylether column except ethane from ethylene, and trans-from cis-2-butene especially operated at $15^{\circ}C$$ using helium as the carrier gas. The column effluents were in order of methane, (ethane, ethylene), propane, propylene, isobutane, n-butane, isobutylene, butene-1, (trans-& cis-2-butene, isopentane), (butadiene-1, 3, n-pentane). Two kinds of liquified petroleum gases in market are analysed qualitatively and quantitatively. The results indicate that use of this 2-meters TEGDE column permits the separation and identification of all the commonly encountered aliphatic gaseous hydrocarbons.

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이소부탄의 산화탈수소반응에 대한 여러 담지체에 따른 V-Sb 산화물 촉매 성능 효과 (Effect of Various Supports on the Catalytic Performance of V-Sb Oxides in the Oxidative Dehydrogenation of sobutane)

  • Shamilov, N.T.;Vislovskiy, V.P.
    • 대한화학회지
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    • 제55권1호
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    • pp.81-85
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    • 2011
  • 이소부탄의 산화탈수소반응(ODH)에 대한 $V_{0.9}Sb_{0.1}O_x$ 촉매계의 5가지 담지체의 촉진효과를 조사하였다. 사용된 5가지 담지체는 감마-알루미나, 알파-알루미나, 실리카-알루미나, 실리카겔, 마그네슘 산화물이다. 촉매는 사용된 담지체에 따라 그 효과가 다르게 나타났다: ${\gamma}-Al_2O_3$ > $\alpha$-$Al_2O_3$ > Si-Al-O> $SiO_2$ $\approx$MgO$\gg$unsupported. V-Sb-O 비율은 별로 촉매 활성과 선택성에 영향을 미치지 않았다. 촉매 성분들이 담지체에 골고루 잘 분포된 이유로 인해 감마-알루미나에 담지된 $V_{0.9}Sb_{0.1}O_x$ 촉매계가 성능이 제일 뛰어났다.

Measurement of TOF of fast neutrons with 238U target

  • Li, Meng;Guan, Yuanfan;Lu, Chengui;Zhang, Junwei;Yuan, Xiaohua;Duan, Limin;Yang, Herun;Hu, Rongjiang;He, Zhiyong;Wei, Xianglun;Ma, Peng;Gan, Zaiguo;Yang, Chunli;Zhang, Hongbin;Chen, Liang;Qiu, Tianli;Hou, Yikai
    • Nuclear Engineering and Technology
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    • 제53권6호
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    • pp.1964-1969
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    • 2021
  • We developed a Dual-PPACs detector for fast neutron measurements that consists of two sets of PPAC: conventional PPAC and fission PPAC. A238U(U3O8) coating is placed in the fission PPAC's anode, which is used as the neutrons conversion layer. An experiment was performed to measure neutron time-of-flight (TOF) in which 252Cf spontaneous fission source was used. An excellent time resolution of 164ps has been observed at 6 mbar in isobutene gas. With the excellent time resolution of Dual-PPACs detector, exact neutron energy can be extracted from the timing measurement. The experimental detection efficiency was 1.9 × 10-7, consistent with the efficiency of 2.5 × 10-7 given by a Geant4 simulation. Ultimately, the results show that the Dual-PPACs detector is a suitable candidate for measuring fast neutrons in the future CiADS system.