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The Effect of Chamber Pressure and Nitrogen Flow Rate on Deposition Characteristics of $(Ni_{0.8}Fe_{0.2})_{20}Ag_{80}$ Thin Films

  • Oh, T.S.;Choo, W.K.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.275-280
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    • 1997
  • We have investigated the deposition characteristics of (Ni0.8Fe0.2)20Ag80 thin films as a function of chamber pressure and nitrogen flow rate with scanning electron microscopy(SEM), atomic force microscopy(AFM), XRD and $\alpha$-step. The deposition rate of these film is decreased with increasing the chamber pressure and the nitrogen flow rate. With raising the chamber pressure, the growth mode of thin film is changed from island growth to columnar one, which is probably due to energy of atom. Contrary, the nitrogen flow rate is raised, growth mode is changed from columnar to island one. According to the XRD patterns, the preferred orientation is inhibited as the nitrogen flow rate is kept above 10 sccm, but that is nearly independent on the chamber pressure. When the chamber pressure decrease or the nitrogen flow rate increase, phase separation into permoally and silver is occured.

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Aerosol Size Distribution and Composition at Kosan, Cheju Island : Measurements in April 1998 (제주도 고산에서의 에어로솔 입경분포별 조성: 1998년 4월 측정 연구)

  • 김용표;배귀남;지준호;진현철;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.677-685
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    • 1999
  • Aerosol mass size distributions were measured at Kosan, Cheju Island in April 1998 and their compositions were analyzed. Microorifice Uniform Deposit Impactor(MOUDI) was used to collect aerosols. Sulfate and ammonium ions were predominatly present at fine mode of the aerosols while nitrate, chloride, and metal ions were mostly at coarse mode. Based on the size distribution of nitrate, it is suggested that most nitrate were from gas to particle conversion on coarse particles. Non-sea salt(nss) fraction of sulfate accounted for more than 90% of total sulfate mass concentration. In general, ion concentrations in this study are lower than those measured at the same site from the previous studies. Ion balance and chloride ion levels indicates that there had been anthropogenic chloride emission sources near to the site during the measurements.

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Ionic Compositions of PM10 and PM2.5 Related to Meteorological Conditions at the Gosan Site, Jeju Island from 2013 to 2015

  • Song, Jung-Min;Bu, Jun-Oh;Lee, Jae-Yun;Kim, Won-Hyung;Kang, Chang-Hee
    • Asian Journal of Atmospheric Environment
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    • v.11 no.4
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    • pp.313-321
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    • 2017
  • $PM_{10}$ and $PM_{2.5}$ were collected at the Gosan Site on Jeju Island from 2013 to 2015, and their ionic and elemental species were analyzed to examine the variations in their chemical compositional characteristics related to different meteorological conditions. Concentrations of nss-$SO_4{^{2-}}$ and $NH_4{^+}$ were respectively 6.5 and 4.7 times higher in the fine particle mode ($PM_{2.5}$) compared to the coarse particle mode ($PM_{10-2.5}$), however $NO_3{^-}$ concentrations were 2.4 times higher in the coarse mode compared to the fine particle mode. During Asian dust days, the concentrations of nss-$Ca^{2+}$ and $NO_3{^-}$ increased to 8.2 and 5.0 times higher in $PM_{10}$, and 3.5 and 6.0 times higher in $PM_{2.5}$, respectively. During haze days, the concentrations of secondary pollutants increased by 3.1-4.7 and 3.2-7.9 in $PM_{10}$ and $PM_{2.5}$, respectively, and they were, respectively, 1.2-2.1 and 0.9-2.1 times higher on mist days. The aerosols were acidified largely by sulfuric and nitric acids, and neutralized mainly by ammonia in the fine particle mode during the haze days, but neutralized by calcium carbonate in coarse particle mode during the Asian dust days. Clustered back trajectory analysis showed that concentrations of nss-$SO_4{^{2-}}$, $NO_3{^-}$, and $NH_4{^+}$ were relatively high when air masses travelled from China.

Source Signature of Mass, Nitrate and Sulfate in Supermicron and Submicron Aerosols at Gosan Superstation on Jeju Island (제주 고산 조대입자와 미세입자의 질량, 질산염, 황산염 변화와 고농도 특성)

  • Lim, S.H.;Lee, M.;Lee, G.;Kang, K.S.
    • Atmosphere
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    • v.20 no.3
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    • pp.221-228
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    • 2010
  • Aerosol particles with different size-cuts ($PM_{10}$, $PM_{2.5}$, and $PM_{1.0}$) were collected at Gosan Superstation on Jeju Island from August 2007 to June 2008. Mean concentrations of $PM_{10}$, $PM_{2.5}$ and $PM_{1.0}$ were $29.28{\mu}gm^{-3}$, $17.83{\mu}gm^{-3}$, and $14.30{\mu}gm^{-3}$, respectively. Soluble ions comprised 45.7%, 53.9%, and 60.3% of the total mass of $PM_{10}$, $PM_{2.5}$, and $PM_{1.0}$, respectively. While sulfate was the most dominant species of fine mode ($PM_{1.0}$), nitrate was enriched in coarse mode ($PM_{1.0-10}$). When the concentrations of coarse mode particles were greatly increased, nitrate tended to be enhanced in coarse mode with high calcium but low sulfate concentrations. During the high $PM_{1.0}$ events, however, nitrate was increased with sulfate at fine mode. Particularly, nitrate concentrations were substantially enhanced during high particle episodes, leading high ratios of nitrate to sulfate in air under northwest wind during wintertime. On the other hand, the levels of nitrate were lower than those of sulfate at average particle concentrations. The backward air mass trajectories indicated that nitrate concentrations were elevated in air arriving Gosan passing through Santung peninsula or near South Korea.

Ecological Contemplation on Native Plant of Bracken at Micheon Cave in Je-ju Island (제주 미천동굴 고사릿과 자생식물의 생태 고찰 (I))

  • Soh, Dea-Wha
    • Journal of the Speleological Society of Korea
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    • no.88
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    • pp.31-37
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    • 2008
  • There are many beautiful volcano caves in Je-ju island which is biggest volcanic island in Korea. The typical volcano caves are ManJang-gul, HyupJe-gul and MiCheon-gul, etc. Among them the MiCheon-gul name is originated from the beautiful things of cave which were more than thousands in there. This MiCheon-gul cave has another feature in special. It is about a native plant bracken living among the various live creatures and plants in MiCheon-gul cave, however, it is growing contrary under the vertex of the cave grown at retro-gravity, as one of the famous things of the proud cave. Therefore, it was contemplated and investigated on the habitat of a mode of life and ecological adaptation on the native plant of bracken include the geomorphic and geographic features of the MiCheon-gul cave.

The Analysis of Oil Spill Spreading Using SAR Images (SAR영상을 이용한 유류 오염 분포 분석)

  • Kim Taerim;Lee Soo Hyung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.2 no.2
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    • pp.38-48
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    • 1999
  • The oil spill accident near Goeje Island on April 3, 1997 was analyzed using two RADARSAT SAR images. The first scene was acquired 3 days after the accident as an extended low beam mode and the second scene was acquired 12 hours after the first scene as a standard beam mode. The two scenes showed slicks not only by oil spills but also by oil spill look-alikes caused by wind sheltering, low wind, natural film, and etc. These slicks were analyzed and classified, and natural films produced from aquaculture farms around Goeje Island were also suggested as a strong candidate for slicks on SAR images. The study with two SAR imags indicated the oil spill patterns which spreaded to the southwest immediately after the accident and switched the direction to the east. The spreading patterns shown in two SAR images also showed good agreement with in-situ observations.

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Influences of Asian Dust, Haze, and Mist Events on Chemical Compositions of Fine Particulate Matters at Gosan Site, Jeju Island in 2014 (황사, 연무, 박무 현상이 미세먼지 화학조성에 미치는 영향: 2014년 제주도 고산지역 측정)

  • Song, Jung-Min;Bu, Jun-Oh;Yang, Seung-Hyuk;Lee, Jae-Yun;Kim, Won-Hyung;Kang, Chang-Hee
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.1
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    • pp.67-81
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    • 2016
  • In order to examine the variation characteristics of chemical compositions in accordance with the different meteorological conditions, $PM_{10}$ and $PM_{2.5}$ were collected at Gosan site of Jeju Island in 2014, and then their ionic and elemental species were analyzed. The concentrations of nss-$SO{_4}^{2-}$ and $NH_4{^+}$ were respectively 4.3 and 3.3 times higher in fine particle mode ($PM_{2.5}$) compared to coarse particle mode ($PM_{10-2.5}$), however $NO_3{^-}$ concentration was 1.6 times higher in coarse mode compared to fine particle mode. During Asian dust days, the concentrations of nss-$Ca^{2+}$ and $NO_3{^-}$ increased highly as 7.7 and 4.5 times in coarse particle mode, and 3.0 and 4.9 times higher in fine particles, respectively. Especially, the concentrations of the crustal species (Al, Fe, Ca, K, Mn, Ba, Sr, etc.) indicated a noticeable increase during the Asian dust days. For the haze days, the concentrations of secondary pollutants increased 2.2~2.7 and 2.9~6.0 times in coarse and fine particles, respectively, and they were 0.8~1.1 and 1.8~2.4 times, respectively, during the mist days. The aerosols were acidified largely by sulfuric and nitric acids, and neutralized mainly by ammonia in fine particle mode during the haze days, but neutralized by calcium carbonate in coarse particle mode during the Asian dust days. The clustered back trajectory analysis showed that the concentrations of nss-$SO{_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ were relatively high when the inflow pathway of air mass was from the southern part of China.

Study on Wet Electric Precipitation with Electrospray for Removal of PM1.0 in Exhaust Gas (배가스 내 PM1.0 미세먼지 제거를 위한 정전분무 습식 전기집진기에 대한 연구)

  • Cho, Yeonjoo;Lim, Hyunjeong;Kim, Soyeon;Choi, Sangmi;Jeong, Min Kyu;Kim, Minsung
    • Plant Journal
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    • v.16 no.1
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    • pp.34-37
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    • 2020
  • The need to improve the performance of the dust collector by increasing the fine dust pollution in Korea is eminent. In this study, electrostatic spray wet electrostatic precipitator is used to remove Particulate Matter (PM). In order to enter the Cone-jet mode, which is the most stable spray mode among the various modes of electrostatic spraying, an appropriate voltage-flow condition must be satisfied, and a voltage-flow interval enabling this can be expressed as Stability Island. The voltage at which the conduit mode starts in the Stability Island section is referred to as the electrostatic spray minimum voltage (Onset Voltage). However, the conventional electrostatic spray is uses a very low flowrate, at most few millilitres per minute. The use of much higher flowrates has introduced different patterns of electrospray modes. In this study, the different spray modes will be studied in detail.

Growth Mode of Tungsten Thin Film by Using Si$H_4$ Reduction of W$F_6$ in LPCVD System (저압 화학 기상 증착 조건에서 Si$H_4$, W$F_6$ 환원 반응에 의한 텅스텐 박막의 성장 양식)

  • Kim, Sung Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.3 no.2
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    • pp.107-116
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    • 1993
  • Tungsten thin film was deposited on Si( 100) substrate by either Si substrate reduction of W$F_6$( case 1) or Si$H_4$ reduction of W$F_6$( case 2) in LPCVD system The morphology and properties of deposited films for both cases were examined. The crystal structure for both cases was determined to be bec (body centered cubic). The amount of tungsten and the grain size in thin films were increased as the film grows. From the experimental results and theoretical considerations, it can be understood that the tungsten thin film grows by the volmer-weber growth mode, that is, island growth. The detailed tungsten thin film growth mode is presented. It was also found that the initial polycrystal structure of tungsten thin film developed into single crystal structure as the film grew in thickness.

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Growth mode of epitaxial $Si_{0.5}Ge_{0.5}$ alloy layer grown on Si(100) by ion beam assisted deposition (이온선보조증착에 의한 Si(100)기판에 정합성장된 $Si_{0.5}Ge_{0.5}$박막의 성장방식)

  • Park, Sang-Uk;Baek, Hong-Gu
    • Korean Journal of Materials Research
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    • v.5 no.3
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    • pp.297-309
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    • 1995
  • 본 연구에서는 이온선보조증착법에 의해 Si(100)기판위에 정합성장된 $Si_{0.5}$Ge_{0.5}$층의 핵성성과 성장을 고찰하였다. 성장층에 대한 AFM(Atomic Force Microscopy), RHEED(Reflection High Energy Electron diffraction) 등의 분석결과 Si(100)기판위에 이온선보조증착에 의하여 성장된 $Si_{0.5}$Ge_{0.5}$층은 Stranski-Kranstanov(SK)기구로 성장되며, 300eV, 10 $\mu$A/$cm^{2}$의 Ar이온선을 조사시키는 경우 결정성이 향상되었고, SK 성장 방식의 임계두께가 증가하였다. Ar 이온선 조사에 의해 MBE에 의한 정합성장온도(55$0^{\circ}C$-$600^{\circ}C$)보다 훨씬 낮은 20$0^{\circ}C$에서 정합성장이 가능하였으며, $x_{mn}$값은 10.5%로 MBE에 의한 정합성장시 보고된 $x_{mn}$ 값보다 낮았다. 이온충돌에 의해 발생한 3차원 island의 분해와 표면확산의 증가가 $Si_{0.5}$Ge_{0.5}$층의 성장에 현저한 영향을 미쳤으며, 이온충돌의 영향은 3차원 island의 생성보다 3차원 island의 분해가 더 안정한 낮은 증착온도에서만 관찰되었다.

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