• Title/Summary/Keyword: Iron minerals

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Production of Fungal Lipid (Part III) The Composition of the Lipid Produced by Mucor plumbeus (곰팡이 유지 생산에 관한 연구 (제 3 보) Mucor plumbeus 균체지방질 구성에 대하여)

  • 신동화;김창식
    • Microbiology and Biotechnology Letters
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    • v.10 no.2
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    • pp.79-86
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    • 1982
  • Mucor plumbeus FRI 0007 was grown on media containing starch solely as carbon source, urea as nitrogen source and minerals including magnesium, calcium and iron of different concentration. The ratio of nonpolar and polar lipid of the total lipid produced by the Muror plumbeus FRI 0007 changed by minerals added in the medium and incubation period. The nonpolar lipid content was higher on the medium containing only one mineral rather than 5 minerals and the nonpolar lipid consisted mainly of trig1yceride, free fatty acid and free sterol. The triglyceride content was higher on the medium containing one mineral and decreased with the incubation time lapse. The major fatty acid composition of total, nonpolar and polar lipid were oleic, palmitic and linoleic acid which comprised about 90% of total fatty acids and their compositions changed slightly depending on the minerals added in the medium.

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Assessment of concrete properties with iron slag as a fine aggregate replacement

  • Noufal, E. Rahmathulla;Kasthurba, A.K.;Sudhakumar, J.;Manju, Unnikrishnan
    • Advances in concrete construction
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    • v.9 no.6
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    • pp.589-596
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    • 2020
  • In an effort to find alternate, environment friendly and sustainable building materials, the scope of possible utilization of iron slag (I-sand), generated as a by-product in iron and steel industries, as fine aggregates in reinforced cement concrete (RCC) made with manufactured sand (M-sand) is examined in this manuscript. Systematic investigations of the physical, mechanical, microstructural and durability properties of I-sand in comparison with RCC made with M-sand have been carried out on various mix designs prepared by the partial/full replacement of I-sand in M-sand. The experimental results clearly indicate the possibility of utilizing iron slag for preparing RCC in constructions without compromising on the property of concrete, durability and performance. This provides an alternate possibility for the effective utilization of industrial waste, which is normally disposed by delivering to landfills, in building materials which can reduce the adverse environmental effects caused by indiscriminate sand mining being carried out to meet the growing demands from construction industry and also provide an economically viable alternative by reducing the cost of concrete production.

New Iron-Containing Electrode Materials for Lithium Secondary Batteries

  • Hong, Young-Sik;Ryu, Kwang-Sun;Chang, Soon-Ho
    • ETRI Journal
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    • v.25 no.5
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    • pp.412-417
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    • 2003
  • Using a galvanostatic charge/discharge cycler and cyclic voltammetry, we investigated for the first time the electrochemical properties of iron-containing minerals, such as chalcophanite, diadochite, schwertmannite, laihuite, and tinticite, as electrode materials for lithium secondary batteries. Lithium insertion into the mineral diadochite showed a first discharge capacity of about 126 mAh/g at an average voltage of 3.0 V vs. $Li/Li^+$, accompanied by a reversible capacity of 110 mAh/g at the 60th cycle. When the cutoff potential was down to 1.25 V, the iron was further reduced, giving rise to a new plateau at 1.3 V. Although the others showed discharge plateaus at low potentials of less than 1.6 V, these results give an important clue for the development of new electrode materials.

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Effect of Inorganic Cementing Agents on Soil Aggregate Formation in Reclaimed Tidelands (무기 결합재의 처리가 간척지 토양의 입단형성에 끼치는 영향)

  • Son, Jae-Gwon;Choi, Jin-Kyu;Cho, Jae-Young
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.4
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    • pp.43-47
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    • 2009
  • Soil aggregation is an important part of influencing the soil behaviors in reducing rainfall-runoff and soil erosion, aeration, infiltration, and root penetration. Some inorganic materials such as clay minerals, Fe and Al oxides/hydroxides, and calcium carbonate can act as cementing agents within macroaggregates. The objective of this study was to determine the effects of different cementing agents (Fe, Mn, and Al) on soil aggregate formation in reclaimed tidelands. Water stable aggregate ratio and MWD (mean weight diameter) were higher in iron dioxides treatment than two other treatments. This result indicates significant correlation between soil aggregate formation and iron dioxides.

The Study of Nutrient Intake and Mineral Contents of Hair and Urine in Autistic Children (자폐증 아동의 영양소 섭취 및 두발과 소변 중의 무기질 함량에 관한 연구)

  • 허귀엽;손숙미
    • Korean Journal of Community Nutrition
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    • v.1 no.3
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    • pp.346-353
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    • 1996
  • The anthropometric measurements, nutrient intake, concentrations of minerals in scalp hair and urine and urinary 5-hydroxyindoleacetic acid(5-HIAA) of 30 autistic children not taking psychoactive drugs and 30 nonautistic control children were determined. The autistic children were taking significantly lower amounts of vitamin A, niacin, ascorbic acid and iron. The intake of vitamin A, niacin, and iron in autistic children were found to be 22$\%$, 75$\%$ and 58 of RDA, respectively. The decreased anthropometric measurements in height and weight of autistic children seems partly due to lower intake of these micronutrients. The food intake in vitamin and mineral group of autistic children was significantly lower. It is probably related to decreased intake of fruit in autistic children. There was no toxicity of cadmium and aluminum in both groups according to their contents in scalp hair. Autistic children showed elevated levels of hair calcium and zinc but lowered levels of copper and iron. The urinary excretion urinary excretion of 5-HIAA.

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Microbial Leaching of Iron from Shinyemi Magnetite Ore (미생물을 이용한 신예미 자철광으로부터 철 침출에 관한 연구)

  • Roh, Yul;Oh, Jong-Min;Suh, Yong-Jae;Jang, Hee-Dong
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.4
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    • pp.357-366
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    • 2007
  • Microorganisms participate in a variety of geochemical processes such as weathering and formation of minerals, leaching of precious metals from minerals, and cycling of organic matter The objective of this study was to investigate biogeochemical processes of iron leaching from magnetite ore by iron-reducing bacteria isolated from intertidal flat sediments, southwestern part of Korea. Microbial iron leaching experiments were performed using magnetite ore, Shinyemi magnetite ore, in well-defined media with and without bacteria at room temperature for a month. Water soluble Fe and Mn during the leaching experiments were determined by ICP analysis of bioleached samples, and the resulting precipitated solids were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The extent of iron leaching from magnetite in the aerobic conditions (Fe = 15 mg/L and Mn = 3.41 mg/L) was lower than that in the anaerobic environments (Fe = 32.8 mg/L and Mn = 5.23 mg/L). The medium pH typically decreased from 8.3 to 7.2 during a month incubation. The Eh of the initial medium decreased from +144.9 mV to -331.7 mV in aerobic environments and from -2.3 mV to -494.6 mV in anaerobic environments upon incubation with the metal reducing microorganisms. The decrease in pH is due to glucose fermentation producing organic acids and $CO_2$. The ability of bacteria to leach soluble iron from crystalline magnetite could have significant implications for biogeochemical processes in sediments where Fe(III) in magnetite represents the largest pool of electron acceptor as well as to use as a novel biotechnology for leaching precious and heavy metals from raw materials.

Reductive Degradation of hexachloroethane by using Iron Minerals: Kinetics studies (철 광물에 의한 헥사클로에탄의 환원적 분해: 반응 속도 연구)

  • Kim, Sung-Kuk;Park, Sang-Won
    • Journal of Soil and Groundwater Environment
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    • v.9 no.2
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    • pp.20-27
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    • 2004
  • Kinetic characteristics dependent on several factors such as iron mineral and organic solvents were investigated. When F $e^{0}$ , FeS and Fe $S_2$ were used as mediators, minerals affecting reaction rate were in the following order : $Fe_{0}$ 0/ > FeS > $FeS_2$ when in contact $C_2$C $l_{6}$ . The more chloride substituted, the higher reaction rate were observed. The reaction rates were dependent on pH, shaking rate, temperature and specific surface area. 1, 10-phenanthroline and EDTA degradation rates were fast, indicating that they adsorbed on the surface of the iron which makes the electron transfer reaction easy. Nitrate which has $\pi$* orbital of molecular can increase electron transfer rate because it is delocalized in its entity. The reaction rates were not affected by hydroquinone. Degradation rates were much enhanced with naturally occurring kaolinite because of the surface corrosion of Fe mineral. However, The reaction rate was not affected by F $e^{2+}$ or S $O_4$$^{2-}$ presented in solution.n.

Chemical Weathering of Glacial Debris of the Barton Peninsula of King George Island, South Shetland Islands, Antarctica: Microtextural Evidences (남극 사우스셰틀란드 킹죠지섬 바톤반도 빙하쇄설물의 화학적 풍화작용: 미조직학적 증거)

    • Journal of the Mineralogical Society of Korea
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    • v.16 no.2
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    • pp.181-189
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    • 2003
  • Diverse microtextures and secondary minerals formed by chemical weathering were observed in the glacial debris of King George Island. Weathering rind was observed in the block of basaltic andesite tuff due to dissolution of calcite producing voids. Eolian volcanic glass altered to mixtrure of allophane-like materials and iron oxyhydroxides at grain edges with relative concentration of Al. Fe, and Ti. Biotite in granodiorite area was transfarmed to vermiculite and interstratified biotite-vermiculite or very rarely to kaolinite and gibbsite. Pyrite in the hydrothermal alteration zone was repalced by iron oxides, resulting in sulfuric acid which locally accelerated alteration of chlorite to expandable clay minerals. Weathering of plagiociase and K-feldspar was negligible. Although glacial debris of the Barton Peninsula has undergone weak chemical weathering with formation of some secondary minerals, massive formation of smectite, abundant in nearby marine sediments, didn't occur.

Effects of Microbial Iron Reduction and Oxidation on the Immobilization and Mobilization of Copper in Synthesized Fe(III) Minerals and Fe-Rich Soils

  • Hu, Chaohua;Zhang, Youchi;Zhang, Lei;Luo, Wensui
    • Journal of Microbiology and Biotechnology
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    • v.24 no.4
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    • pp.534-544
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    • 2014
  • The effects of microbial iron reduction and oxidation on the immobilization and mobilization of copper were investigated in a high concentration of sulfate with synthesized Fe(III) minerals and red earth soils rich in amorphous Fe (hydr)oxides. Batch microcosm experiments showed that red earth soil inoculated with subsurface sediments had a faster Fe(III) bioreduction rate than pure amorphous Fe(III) minerals and resulted in quicker immobilization of Cu in the aqueous fraction. Coinciding with the decrease of aqueous Cu, $SO_4{^{2-}}$ in the inoculated red earth soil decreased acutely after incubation. The shift in the microbial community composite in the inoculated soil was analyzed through denaturing gradient gel electrophoresis. Results revealed the potential cooperative effect of microbial Fe(III) reduction and sulfate reduction on copper immobilization. After exposure to air for 144 h, more than 50% of the immobilized Cu was remobilized from the anaerobic matrices; aqueous sulfate increased significantly. Sequential extraction analysis demonstrated that the organic matter/sulfide-bound Cu increased by 52% after anaerobic incubation relative to the abiotic treatment but decreased by 32% after oxidation, indicating the generation and oxidation of Cu-sulfide coprecipitates in the inoculated red earth soil. These findings suggest that the immobilization of copper could be enhanced by mediating microbial Fe(III) reduction with sulfate reduction under anaerobic conditions. The findings have an important implication for bioremediation in Cu-contaminated and Fe-rich soils, especially in acid-mine-drainage-affected sites.

Distribution of Minerals within the Degermed Brown Rice Kernel (배아를 제거한 현미립내의 무기질의 분포)

  • Song, Bo-Hyeon;Kim, Dong-Youn;Kim, Sung-Kon;Kim, Young-Du;Choi, Kap-Seong
    • Applied Biological Chemistry
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    • v.31 no.2
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    • pp.162-168
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    • 1988
  • The contents of minerals of the milled fractions of degermed Japonica and J/Indica brown rices were determined. The fraction I(about 4.4% of the kernel weight) contained 14.8 times as much sodium as did the original kernel; phosphorus, 5.7 times; potassium and iron, 5.4 times; magnesium, 4.2 times; calcium, 3.8 times; manganese, 3.7 times; Copper, 3.6 times; and Zinc, 2.3 times. Concentrations of these minerals were the lowest in the residual kernel, which contained less than the original brown rice. Sodium showed the most deepest concentration gradient, while iron was the most evenly distributed within the kernel in all samples.

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