• Title/Summary/Keyword: Iron minerals

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A Study on Iron Compounds Accompanied in Korean Kaolin Minerals (국산 Kaolin 광물에 수반된 철화합물의 종류 및 존재상태 구명에 관한 연구)

  • 박금철;최석진;박영갑
    • Journal of the Korean Ceramic Society
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    • v.11 no.2
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    • pp.22-30
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    • 1974
  • This study was carried out to investigate the species of iron compounds in kaolin mineral and the bonding relation between the major kaolin and its subordinate iron compound existing as incidental mineral in common clay by means of chemical composition, X-ray diffraction, thermal differential and thermogravimetrie analysis for the application of clays in the field of ceramic raw material. The domestic clay are produced abounduntly in many places, but San-Cheong kaolin, Chu-An clay, and Yeong-Am clay were selected as samples in this experiment because of their frequent utilization in porcelain industry. Two kinds of samples with low and high iron content are picked up respectively from the place of production and elutriated under two micron size to determine the properties and concentration of iron compound very fine particles or colloidal substance of low crystalline grade. Therefore, hydrothermal treatment in autoclave was conducted considering the existence of low crystalline grade of iron compounds known as an amorphoue state in X-ray diffraction pattern furthermore, de-iron treatment of hydrothermal compound was done in order to identify the related iron compound before and after hydrothermal reaction and iron compound which is one of the samples was synthesized for the determination of their compounds state in more detail. The obtained results in this study are as follows: In San-Cheong kaolin, Chu-An clay and Yeong-Am clay 1) It is proved that species accompanying iron compound is $\alpha$-FeOOH form. 2) Iron compound is composed of very fine particles or colloidal substance. 3) The iron substance encircles the fine parts of clay minerals under 2 micron and acts as cementizing agent.

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A Preliminary Study on the Roles of Fe Content and Neoformed Ca-rich Minerals in the Coloration of Ceramic Glazes

  • Lee, Min Hye;Han, Min Su;Kim, Ji Hye
    • Journal of Conservation Science
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    • v.36 no.4
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    • pp.275-283
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    • 2020
  • Iron oxides are the essential coloring oxides in traditional ceramic glazes. However, when Fe is involved in the coloration in the form of ions or colloids in glazes with low Fe content, it is difficult to identify the iron oxide phases. Generally, in many these glazes, Ca-rich minerals are observed by X-ray diffraction (XRD) or microscopic images, owing to their devitrification by the high Ca content. This study attempts to elucidate the correlation between the crystalline structure and coloration in the glazes while mainly focusing on neoformed Ca-rich minerals and Fe content. An experimental firing was carried out to produce tree ash glazes, with pine tree ash and Buyeo feldspar. In the case of oxidation glazes, the scanning electron microscopy (SEM) images and XRD patterns did not exhibit any Ca-rich crystals, and all the visible light reflectance spectra lines exhibited a similar shape. In contrast, the reduction glazes divided into blue glazes and other colored glazes according to the shapes of their reflectance spectra. It was confirmed that the influence of Ca-rich minerals on the glaze color was more pronounced than the blue color of the reduction glazes when the Ca and feldspar contents were sufficiently high and low, respectively, to form wollastonite. As the Ca content increased and the elemental composition of the reduction glazes changed, the neoformation of the Ca-rich minerals, such as wollastonite, anorthite, diopside, and akermanite was sequentially observed.

The Changing Patterns of Demand-Supply and Role of Mineral Resources in Economic Growth during Industrialization of the Republic of Korea (한국공업화과정(韓國工業化過程)에서의 광물자원(鑛物資源)의 수급구조변화(需給構造變化)와 경제성장(經濟成長)에 있어서의 역할(役割))

  • Yun, Suckew
    • Economic and Environmental Geology
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    • v.18 no.1
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    • pp.65-92
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    • 1985
  • A total of 12 mineral commodities significant in domestic output, economy and/or strategy of the Republic of Korea are chosen to examine the structural changes in production and demand-supply of these minerals during the last two decades of her industrialization. These include iron and manganese ores as the raw materials for iron and steel making, copper, zinc and tungsten ores among other non-ferrous metallic minerals, limestone (cement), kaolin, talc, pyrophyllite and graphite among other non-metallic minerals, and anthracite coal as the only domestic source of fossil energy. These are reviewed historically in time-series based on the statistical data which are tabulated and graphed in terms of domestic output, export, import, apparent demand-supply, its increasing rate, and self-sufficiency rate of each commodity. The increasing rates of demand-supply (IRDS) of some more important commodities are compared with those of Gross Domestic Production (GDP) and Economic Growth Rate (EGR) to evaluate how the IRDS contributed to the GDP and EGR. The major results revealed are as follows: Among the 12 commodities, the domestic output of 8 commodities appeared to have grown with steady upward trends: they are ores of lead, zinc and tungsten, limestone (cement), kaolin, talc, pyrophyllite and anthracite coal. Two commodities, ores of iron and copper, continued with unchanging or slightly declining trends and varied fluctuations, in spite of their cardinal importance to the heavy industry and strategy of Korea. The remaining two, graphite and manganese ore, have gradualy declined in domestic output in which the former has still enough resource potential but the latter has not and virtually ceased its domestic output. Trade patterns for mineral commodities in the Republic of Korea during the last two decades have changed greatly, being marked by a shift from mineral-exporting to mineral importing, mainly because of increasing consumption of mineral raw materials for industrialization rather than beceuse of decreasing output of domestic mineral commodities in quantity. In terms of trade patterns, the 12 commodities concerned in this study can be classified into the following four groups. The 1st group - ores of lead and tungsten have only been exported without imports. The 2nd group - amorphous graphite, and pyrophyllite have mainly been exported but partly been imported. The 3rd group - kaolin, talc and crystalline graphite have equally been exported and imported, but quantity of imports have rapidly been increased with time. The 4th group - ores of iron, manganese and zinc have shifted from exports to imports during the industrialization, particularly owing to the initiation of iron and steel making by the Pohang Iron and Steel Company in the middle 1970' s and the new establishment of the Onsan Zinc Refinery in the late 1970' s. All of the 12 commodities under considerations were far above 100% in self-sufficiency rate before or in the early 1960' s. Recently, however, most of them have been declined to below 100% except for those of limestone (cement) and pyrophyllite. It is particularly serious to identify that the self-sufficiency rates of the three important metallic minerals, iron, copper and manganese ores in 1982 appeared to be 5.1%, 0.5%, and 0.01%, respectively. The average self-sufficiency rate of the total domestic minerals produced in 1982 was 14.4% (in value) for that year. Mining industry appeared to be extremely high in its intermediate demand rate whereas its intermediate input rate to be quite low indicating that mineral raw materials have been exerted strong forward linkage effects upon the other industries rather than backward linkage effects. In comparing the curves of increasing rates of demand-supply of several major minerals - iron ore, manganese ore, copper ore, limestone (cement), kaolin, and anthracite coal - with those of Gross Domestic Production and Economic Growth Rate drawn on every graph, it is clearly shown that the curves of increasing rates of demand-supply comprise around 6 to 7 periods of cycles which roughly harmonious with those of the curves of GDP and EGR, except for the curve of anthracite coal of which the configuration seems to have resulted from the (artificial) government's mineral policy rather than from economic free market mechanism. The harmonic feature of these curves well suggests that the increasing rates of demand-supply of major minerals have been significantly contributed to the GDP and EGR. In addition, the wider amplitudes of the iron, manganese and copper curves than those of the limestone (cement) and kaolin curves indicate that the contribution of the former, metallic commodities, has been greater than that of the latter, non-metallic commodities.

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Concentrations of Major Minerals and Trace Elements in Sera of The Breast-fed and Formula-fed Infants (모유영양아와 인공영양아의 혈청무기질 및 미량원소 함량비교)

  • 안홍석;박성혜;박윤신
    • Korean Journal of Community Nutrition
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    • v.2 no.2
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    • pp.133-140
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    • 1997
  • The serum concentrations of the major minerals(calcium, phosphorus, magnesium, sodium, potassium) and trace elements(iron, Zinc, copper manganese)were datermined in 23 breast fed infants living in Eumsung, Choong-buk region. The results obtained are summarized as follows: 1)The mean levels of calcium, phosphorus, magnesium, sodium and potassium of the serum of total subjects were 8.15$\pm$0.33mg/dI, 11.06$\pm$0.16mg/dI, 2.00$\pm$0.14mg/dI, 3.4476$\pm$17.99mg/dI and 9.06$\pm$2.04mg/dI respectively. 2)The serum concentrations of iron, zinc, copper and manganese in total subjects averaged 95.83$\pm$0.33mg/dI, 93.79$\pm$7.06$\mu$g/dI and 98.57$\pm$7.06 $\mu$g/dI and 4.93$\pm$0.62$\mu$g/dI respecitively. 3)Breast fed infants had significantly higher serum calcim, magnesium, sodium and iron concentrations than the formula fed groups. Otherwise, serum potassium, copper and manganese levels in breast milk fed infants were significantly lower than those in formula fed infants. 4) In formula fed infants, serum potassium and copper levels increased increased significantly with months after birth.

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Mineral Retention in Young Broiler Chicks Fed Diets Based on Wheat, Sorghum or Maize

  • Thomas, D.V.;Ravindran, V.
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.1
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    • pp.68-73
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    • 2010
  • The aim of the present study was to determine the changes in mineral retention of broiler chicks fed diets based on wheat, sorghum or maize during the first two weeks post-hatch. The retention of five major minerals (calcium, phosphorus, potassium, sodium and magnesium) and four trace minerals (iron, manganese, zinc and copper) was determined on days 3, 5, 7, 9 and 14 of age. The retention coefficients of individual minerals differed widely and the retention coefficients of major minerals were found to be considerably higher than those of trace minerals. Age effects were significant (p<0.05) for all minerals. In general, mineral retention coefficients were highest at day 3, declined to day 7, and remained unchanged to day 14. Decline in mineral retention with age was similar on all three diets. The cereal effect was significant (p<0.05) for several minerals, with a general tendency for the sorghum-based diet to have greater retention than maize- or wheat-based diets.

Effect of Cation and Ionic Strength on Dispersion and Coagulation of Hwangto and Clay Minerals (양이온의 종류와 농도에 따른 황토와 점토광물의 분산과 응집)

  • Park, Bo-Kyeong;Kim, Kyung-Min;Kim, Young-In;Yum, Seo-Yun;Lee, Jeong-Woo;Hyung, Seuug-Woo;Hwang, Jun-Ho;Kim, Yu-Mi;Kong, Mi-Hye;Kim, Cheong-Bin;Roh, Yul
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.3
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    • pp.249-259
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    • 2009
  • The objective of this research was to find out the physical properties, such as dispersion and coagulation, of soil minerals depending on the types and concentrations of the cations in aqueous solution. Hwangto samples were obtained from 90 to 130 cm from surface at Jangdong-ri, Donggang-Myon, Naju, Chonnam Province. The clay fraction (< $2\;{\mu}m$) was separated by sedimentation method from the bulk soils. Both Hwangto and clay fractions, and the same samples after removal of amorphous and crystalline iron oxides were used in this experiment. The effect of 4 cations ($Na^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$) and their concentrations on settling speed and basal spacing of the minerals were observed to examine the physical properties of the soil and clay minerals. Hwangto mainly consisted of quartz, and the clay fractions consisted of kaolinite, illite, and vermiculite. The bulk soils contained 16.3 mg/kg of amorphous iron oxides and 436 mg/kg of crystalline iron oxides. Clay fractions were dispersed better than bulk soils due to their smaller particle size than that of the bulk samples in the aqueous solution. The bulk and clay samples were dispersed better when iron oxides were removed because of coating of minerals by the iron oxides. Clay minerals were settled faster as the charge and the concentration of cations added increased. The d-spacing of kaolinite and illite did not change when 4 types of cations were added. The d-spacing of vermiculite showed $14.04\;{\AA}$ when divalent cations were added while that of vermiculite showed $13.9\;{\AA}$ when monovalent cations were added. It may be attributed to the hydration radii of cations. This study indicated that both coating of iron oxides on minerals and types and concentrations of cations affect dispersion of minerals in solution and d-spacing of expanding clay minerals such as vermiculite.

Biomineralogical Study on the Microbial Mats formed from the Mine Drainage of the Abandoned Ilkwang Mine in Pusan, Korea (일광광산 폐갱 유출수에 의해 형성된 바이오매트의 생광물학적 연구)

  • 안윤희;황진연;김근수
    • Journal of the Mineralogical Society of Korea
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    • v.12 no.1
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    • pp.32-42
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    • 1999
  • Microbial mats, the yellow and reddish brown deposits formed from the mine drainage, occur on the bottom of drain and mine tailing pond of the Ilkwang mine in Pusan, Korea. The constituents of microbial mats and their biomineralization were studied by using XRD, IR, and SEM-EDX. The upper part of the microbial mat is yellow-colored and composed of tube-shaped and small spheroid bacterial materials, which are mainly made up of amorphous and poor-crystalline iron-oxide minerals. The shape and composition of bacterial materials suggest that they are probably belong to iron-oxide mineral aggregates. The iron-oxide minerals of the yellow microbial mats are mainly goethite, but those of the reddish brown microbial mats contain abundant hematite along with goethite. This implies that with the evolution of biomats, goethite may be transformed to hematite.

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Effect of bicarbonate concentration on iron biomineralization by psychrotolerant bacteria

  • Lee, Sang-Han;Yul-Roh;Lee, Insung
    • Proceedings of the KSEEG Conference
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    • 2003.04a
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    • pp.236-236
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    • 2003
  • Anaerobic Fe(III)-reducing bacteria are known to be able to reduce crystalline and amorphous Fe(III) oxides. Anaerobic Fe(III)-reducing bacterial reduction can induce several kinds of secondary minerals (Fe(II) containing minerals) such as magnetite, siderite, vivianite [($Fe_{3}(PO_{4}{\cdot}2H_{2}O$], and iron sulfide (FeS) according to variety of geochemical and biological conditions. (omitted)

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Effects of Iron and Selenium Intakes on Utilization of Manganese in Rats (철분과 셀레늄의 섭취수준이 흰쥐의 망간 이용에 미치는 영향)

  • Jun, Ye-Sook;Choi, Mi-Kyeong
    • Journal of the East Asian Society of Dietary Life
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    • v.7 no.2
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    • pp.143-151
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    • 1997
  • The purpose of this study was to investigate the effect of iron and selenium intakes on utilization of manganese in rats fed adequate, 2-fold, 4-fold iron and adequate, high selenium for 6 weeks. There was no difference feed intake across iron and selenium containing diet groups. Body weight gain in 2-fold iron and high selenium group(MFeHSe) was significantly higher than those in other groups. Serum iron level was increased with iron increment, and liver iron content was decreased with selenium supplementation. Selenium and manganese contents in tissues were decreased with iron increment. In the case of manganese balance, manganese excretion through feces was significantly increased as iron intake was increased. However, retention and apparent absorption of manganese were not significantly affected by dietary iron. From these results, it could be suggested that the supplementations of iron and selenium affected the manganese utilization. Therefore, it must be considered interaction with various minerals in micro-nutrient supplementations.

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Iron Intake During Pregnancy on Serum Concentrations of Trace Minerals in Mothers and Neonates (임신기간 중 철 섭취가 모체와 제대 혈청의 미량 무기질 농도에 미치는 영향)

  • Kim, Hye-Ra;Lim, Hyeon-Sook
    • Journal of Nutrition and Health
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    • v.41 no.3
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    • pp.242-253
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    • 2008
  • It is a common clinical practice to recommend taking iron supplements for pregnant women during gestation. Although it is required to ensure adequate iron stores during pregnancy, there has been some debate over the interference effects of excessive iron load, because it is possible to compete in the transport in the intestine and placenta and in binding to serum proteins of other trace minerals. In this study, maternal and neonatal serum concentrations of Fe, Zn, Cu, Se, Cr, Mn, and Co were assessed along with maternal Fe intakes. A total of 124 pregnant women and their term neonates participated voluntarily in this research. The women were divided into one of the three groups {high Fe intake (HFI), median Fe intake (MFI), and low Fe intake (LFI)} by their total Fe intakes and one of the two groups (Anemic and Normal) by their Fe nutritional status. All the data were compared among the three groups and between the two groups also. Total Fe intakes of HFI, MFI, and LFI groups were 140.8 ${\pm}$ 76.1, 68.0 ${\pm}$ 11.2, and 30.2 ${\pm}$ 8.6 mg/day, respectively. Those of Anemic and Normal groups were 90.1 ${\pm}$ 74.8 and 86.6 ${\pm}$ 46.8 mg/day, respectively. Maternal Hb concentration and Hct were not significantly different among HFI, MFI, and LFI groups but those were significantly different between Anemic and Normal groups. However, neonatal Hb concentration was not significantly different among HFI, MFI, and LFI groups and between Anemic and Normal groups either. Maternal serum Fe concentrations of the three groups, HFI, MFI, and LFI, were similar but that of Anemic group was significantly lower compared to Normal group. However, there was no significant difference in neonatal serum Fe concentrations among the three groups and between the two groups either. Serum concentrations of the other trace minerals in both mothers and neonates were not significantly different among HFI, MFI, and LFI groups and between Anemic and Normal groups. In addition, in the maternal serum, Fe concentration was positively correlated to Zn and Se concentration, respectively. As for the neonatal serum, Fe concentration showed a positive correlation to Zn, Cu, Mn, Se, and Co concentration, respectively. No trace mineral concentration was found to correlate negatively to Fe concentration in both maternal and neonatal serum, The results in this study indicate that Fe intakes of pregnant women, even if it is considerably above the level of estimated average requirement (EAR), may not affect serum Fe concentration in both mothers and neonates. In addition it might not influence adversely on the availability of other trace minerals including Zn and Cu in both mothers and neonates.