• 제목/요약/키워드: Iron Metal

검색결과 853건 처리시간 0.029초

나주 복암리 3호분 출토 철제유물의 금속학적 조사 (Microstructure investigation of iron artifacts excavated from No. 3 tomb of Bogam-ri in Naju City, Chollanam-do Province)

  • 유재은;고형순;황진주
    • 보존과학연구
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    • 통권22호
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    • pp.115-132
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    • 2001
  • No. 3 Tomb of Bogam-ri, in Naju City, Chollanam-do Province, was a site excavated and inspected from 1996 to 1998 and had a various grave forms, including jar-coffins, stone-chambers and stone-cists. Although most of the metal artifacts excavated from it were severely corroded, we could implement microstructure investigation by collecting samples from the iron axes, iron coffin-nails and iron clamps in which the metal parts were remained. The metal structures were inspected by using metallographic microscope and SEM, and fine components analysis was implemented by ICP. To examine the hardness differences in accordance with the structure distribution, we measured the hardness by structures with Vickers hardness testing machine. As a result of the metal structure inspection, most of them were pure iron, ferrite, and also pearlite, cementite and widmannstaten structures were displayed. We could confirm carbonization was formed on the surface of the iron axes-B, iron coffin-nails-B, and iron clamps-A. There was no carbonization in the rest of the artifacts, and it is not certain that whether the carbonized parts were peeled off through extreme corrosion or they were not carbonized when they were made. In the particular part of a blade, the quality of the material was strengthened through processing. Due to the processing re-grain was caused and fine grain particles were formed. As a result of the ICP component analysis, there were no addition atoms because pure irons were used as materials. In the mean time, No. 17 jar-coffin where the iron axes-A are excavated, is chronologically ordered as from the late-fourth century to the mid-fifth century, and No. 1 and No. 2 stone chambers, where the rest of the artifacts were excavated, as the early-sixth century. It was difficult to relate the periodic differences with the manufacture technique artifacts which we inspected because there were no distinct characteristics of the manufacture technique of the metal structures and it is impossible to conclude the artifacts and sites are at the same period although their periods are different.

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표면 처리한 Sea sand를 이용한 Se(IV) 제거 - Zeta potential을 통한 Fe(III)간의 반은 메카니즘 연구 (Removal of Se(IV) by the Fe(III)-impregnated Sea sand - Zeta potential approach to depict the binding between Fe(III) and Sea sand)

  • 박상원;강혜정
    • 한국환경과학회지
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    • 제8권2호
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    • pp.205-209
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    • 1999
  • Iron hydroxides are good adsorbents for uncomplexed metals, some metal-ligand complexes and many metal oxyanions. However, their adsorption properties of these precipitations are not fully exploited in wastewater treatment operations because of difficulties associated with their separation from the aqueous phase. This study describes experiments in which iron hydroxides were coated onto the surface of ordinary adsorbents(Sea sand) that are very resistant to acids, The coated adsorbents were used in adsorption of oxyanionic metals. The process was successful in removing some anions such as $SeO_3(-II)$ over a wide range of metal concentrations and sorption of oxyanionic metals increased with decreasing pH. Formation of two surface complexes for oxyanionic metals adsorption on iron hydroxides comprise (1) complexation of the free anion by a positively charged surface site, and (2) protonation of the adsorbed anion (or alternatively adsorption of a protonated form from solution) The coated adsorbents are inexpensive to prepare and could serve as the basis of a useful oxyanionic metal removal.

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비철금속의 선삭시 윗면 절삭각이 표면 거칠기에 미치는 영향에 관한 연구 (Study of Surface Roughness by Cutting Angle at Turning of Non-iron Metal)

  • 전재억;정진서;신규동;구양;하만경
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2000년도 추계학술대회논문집 - 한국공작기계학회
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    • pp.236-241
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    • 2000
  • In the present industry, there is not only the cutting of iron metal, but also the cutting of alloy aluminum, brass and plastic to wood(Paulownia). A variety of material is used and these industry is made need of the cutting material but lots of experiments processing is not enough at the moment. At this point, our team processed the basic experiment about influencing of cutting angle of bite concerned to manufacture in the turning of non-iron metal. Generally speaking, we recognized that there was occurrence of increase of rough surface with increasing of cutting angle in the non-iron metal. but in the cutting of wood we knew, there was special change with change of cutting angle.

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삽입금속을 사용한 구상흑연주철과 2024 알미늄합금의 마찰압접에 관한 연구 (Friction Welding of Spheroidal Graphite Cast iron and 2024 Aluminium Alloys using Insert Metal)

  • 김창규;김치옥;심성보;김광일
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2002년도 추계학술대회 논문집
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    • pp.283-288
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    • 2002
  • This study accompanied with the friction welding of a spheroidal graphite cast iron bar and 2024 Aluminium alloy bar with A1050 insert metal and investigated between conditions of friction welding faces and welded joint strength. This principal results of the experimental investigation could be summarized as follows: If the optimum friction welding is selected, the aspect of the spheroidal graphite cast iron and 2024 Aluminium could be welded with a pure Aluminium insert metal.

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금형주조 구상흑연주철의 칠 형성 경향에 미치는 화학조성 및 열처리의 영향 (Effects of Alloying Elements and Heat-Treatment on the Tendency of Chill Formation of Ductile Cast Iron Produced by Metal Mold Cast)

  • 김석원;박진성;김기곤
    • 한국주조공학회지
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    • 제27권1호
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    • pp.24-30
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    • 2007
  • The effects of C, Si and RE additions on the tendency of chill formation of ductile cast iron obtained from metal mold casting were investigated. In case of metal mold cast, the ductile cast iron with 2.5%Si had pearlitic matrix, and specimens with 2.9%Si had bull's eye type regardless of C contents. As-cast specimen with a large amount of fine graphites could be obtained by adding 0.2% RE. Normalizing process was necessary to remove carbide and form a large amount of spheroidal graphites for the as-cast specimens. Good mechanical properties could be obtained by heat-treatment of as-cast specimens with pearlitic matrix. Normalizing the specimens with RE caused the reduction in mechanical properties.

Development of Metal Recovery Process for Municipal Incineration Bottom Ash (MIBA)

  • Kuroki, Ryota;Ohya, Hitoshi;Ishida, Kazumasa;Yamazaki, Kenichi
    • 자원리싸이클링
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    • 제28권3호
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    • pp.21-25
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    • 2019
  • The utilization of incineration ash from municipal waste must be promoted to solve the social problem on the shortage of final disposal site. In this research, metals should be recovered to avoid the damage of the crushing machine during the utilization of incineration ash in cement industry. In fact, incineration bottom ash from municipal waste contains iron in 3-5%. Nonferrous metal and stainless steel in 1% is also included. The research and development on the physical recovery process was performed not only to remove the metals but also to recover high grade products. Metals were separated from incineration ash in Maruya Co. Ltd.. In fact, iron scrap recovered by magnetic separation can be selled. After that, mixed metal was separated from incineration ash using screen. In this research, mixed metal tried to divided copper, aluminum, brass and stainless steel using drum type magnetic separation, eddy current separation and high magnetic separation. As a result, recovered iron had an 80% for the grade. Aluminum was recovered by eddy current separation without copper and brass.

전이금속 산화물이 고정된 하이드로탈사이트에 이산화질소 흡착 (Adsorption of Nitrogen Dioxide on Transition-Metal-Oxide-Incorporated Hydrotalcites)

  • 박지원;서곤
    • Korean Chemical Engineering Research
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    • 제46권6호
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    • pp.1029-1038
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    • 2008
  • 전이금속 산화물의 전구체가 들어있는 합성모액을 수열 반응시켜 전이금속 산화물이 고정된 하이드로탈사이트를 제조하여 이들에 대한 이산화질소의 흡착 성질을 조사하였다. 전이금속 산화물의 분산도, 이산화질소의 흡착량 및 흡착상태를 XRD, SEM, XPS, 질소 흡착등온선, 중량식 흡착법, FT-IR, 승온탈착법으로 조사하였다. 전이금속 산화물은 주로 하이드로탈사이트의 표면에 분산 담지되었으며, 철과 니켈 산화물이 고정된 하이드로탈사이트에 이산화질소가 많이 흡장되었다. 철 산화물이 표면에 분산되어 담지되면 이산화질소의 흡장량이 많지만, 철 산화물이 지나치게 많이 담지되면 덩어리져서 표면의 염기점을 차폐하므로 이산화질소의 흡장량이 오히려 줄어들었다. 철 산화물의 고정량이 적절하면 하이드로탈사이트에서 이산화질소의 흡장세기는 약해지지만, 흡장량은 많아지고 수열 안정성이 증진되었다.

삽입금속을 사용한 구상흑연주철과 2024 알루미늄합금의 마찰압접에 관한 연구 (Friction Welding of Spheroidal Graphite Cast Iron and 2024 Aluminium Alloys using Insert Metal)

  • 김창규;김치옥;김광일
    • 한국해양공학회지
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    • 제17권5호
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    • pp.76-81
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    • 2003
  • Friction welding of GCD45 spheroidal graphite cast iron and 2024 aluminum alloy has been studied, especially in terms of the joint faces and strength of friction welding. For appropriate results of the friction welding of GCD45 graphite cast iron and 2024 aluminum alloy, an insert of A1050 pure aluminum metal was used. The joint strength of the A1050 pure aluminum insert approached the maximum strength of 165.7Mpa, compared to 128MPa for the joint between GCD45 graphite cast iron and A1050 pure aluminum without the insert metal. Maximum strength, 165.7Mpa, was possible for the following optimum conditions: 20MPa for the friction pressure, P1, 60MPa for the upsetting pressure, P2, 1 second for the friction time, t1, 3000rpm for the rotation, N, and 0.3 seconds for the brake time, tB.

3가철 함유 흡착제를 이용한 수용액상의 중금속 및 페놀제거연구 (Removal of Heavy Metal and Phenol from Aqueous Solution Using Fe(III) loaded Adsorbent)

  • 김석준;김원기;이승목;양재규;이남희
    • 대한환경공학회지
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    • 제31권7호
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    • pp.541-548
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    • 2009
  • 본 연구에서는 매립장 침출수 같은 중금속과 유기물을 함께 함유하고 있는 폐수를 처리하기위하여, Fe(III)을 활성탄, 모래, 불가사리와 같은 담체에 첨착 및 코팅시킨 흡착제를 사용하였다. 제조된 Iron Impregnated Activated Carbon(Fe-AC), Iron Coated Sand(ICS), Iron Coated Starfish(ICSF)는 EPA 3050B 방법을 통하여 각 매질에 함유된 철 함량을 분석하였으며, 회분식 반응조에서의 흡착실험을 통하여 각 흡착제의 Mn(II), Zn(II) 및 Cu(II)의 제거성능을 비교하였다. Fe-AC 및 ICS의 철 함유량은 각각 1,612 mg/kg 및 1,609 mg/kg으로서 매우 유사하였으며 ICSF의 철 함유량은 1,768 mg/kg으로 ICSF의 철 코팅함량이 다른 두 가지에 비해 150 mg/kg 정도 높게 나타났다. 회분식 실험에서의 Mn(II), Zn(II), Cu(II)의 제거효율은 ICSF, Fe-AC, ICS의 순으로 높은 제거율을 보였다. 각 흡착제를 단일 및 다중층으로 충전한 칼럼반응기에 의한 연속식 실험결과, 단일 흡착제에 비해 ICS, Fe-AC, ICSF의 순으로 충전한 시스템에서 높은 중금속 및 페놀제거효율을 나타내었으며, Cu(II)와 Zn(II)에 대해서는 뚜렷한 파과능을 보였으나 Mn(II) 제거율은 상대적으로 낮게 나타났다. 각 흡착제를 병합 충전한 다중층 칼럼반응시스템은 중금속 및 phenol제거에 효과적임을 알 수 있었다.

Effects of developmental iron deficiency and post-weaning iron repletion on the levels of iron transporter proteins in rats

  • Oh, Sugyoung;Shin, Pill-kyung;Chung, Jayong
    • Nutrition Research and Practice
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    • 제9권6호
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    • pp.613-618
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    • 2015
  • BACKGROUND/OBJECTIVES: Iron deficiency in early life is associated with developmental problems, which may persist until later in life. The question of whether iron repletion after developmental iron deficiency could restore iron homeostasis is not well characterized. In the present study, we investigated the changes of iron transporters after iron depletion during the gestational-neonatal period and iron repletion during the post-weaning period. MATERIALS/METHODS: Pregnant rats were provided iron-deficient (< 6 ppm Fe) or control (36 ppm Fe) diets from gestational day 2. At weaning, pups from iron-deficient dams were fed either iron-deficient (ID group) or control (IDR group) diets for 4 week. Pups from control dams were continued to be fed with the control diet throughout the study period (CON). RESULTS: Compared to the CON, ID rats had significantly lower hemoglobin and hematocrits in the blood and significantly lower tissue iron in the liver and spleen. Hepatic hepcidin and BMP6 mRNA levels were also strongly down-regulated in the ID group. Developmental iron deficiency significantly increased iron transporters divalent metal transporter 1 (DMT1) and ferroportin (FPN) in the duodenum, but decreased DMT1 in the liver. Dietary iron repletion restored the levels of hemoglobin and hematocrit to a normal range, but the tissue iron levels and hepatic hepcidin mRNA levels were significantly lower than those in the CON group. Both FPN and DMT1 protein levels in the liver and in the duodenum were not different between the IDR and the CON. By contrast, DMT1 in the spleen was significantly lower in the IDR, compared to the CON. The splenic FPN was also decreased in the IDR more than in the CON, although the difference did not reach statistical significance. CONCLUSIONS: Our findings demonstrate that iron transporter proteins in the duodenum, liver and spleen are differentially regulated during developmental iron deficiency. Also, post-weaning iron repletion efficiently restores iron transporters in the duodenum and the liver but not in the spleen, which suggests that early-life iron deficiency may cause long term abnormalities in iron recycling from the spleen.