• 한국환경과학회지
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• 제13권12호
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• pp.1067-1078
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• 2004

Atmospheric particulate matters were collected by 8-stage non viable cascade impactor from October 2002 to August at Jeju City. Eight water-soluble ionic components $(Na^+,\;NH_{4}_{+},\;K^+,\;Ca{2+},\;Mg^{2+},\;CI^-,\;NO_{3}^-\;and\;SO_{4}^{2-})$ were analyzed by Ion Chromatography. The concentration of particulate matters and eight water-soluble ionic components were determined to investigate their size distributions. Particulate matters exhibited a tri-modal distribution with peak value around $0.9,\;4.0{\mu}m\;and\;9.5{\mu}m.$ In summer, the last peak value was lower than other season values likely due to particulate matter scavenged by rain water. Four ionic components $(Na^+,\;Ca^{2+},\;Mg^{2+}\;and\;CI^-)$ exhibited a bi-modal distribution in the coarse mode whereas three ionic components $(NH_{4}^+,\;K^+\;and\;SO_{4}^{2-})$ in the fine mode, with maximum peak value around $0.9{\mu}m.\;NO_{3}^-$ was found in both the coarse and the fine mode. The enrichment factor (E.F.) of each ionic components was calculated. Based upon E.F., it is considered that $Na^+,\;CI^-,\;and\;K^+$ in coarse paricle mode were delivered form oceanic source, but other components might have other source origins.

• 한국환경보건학회지
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• 제22권2호
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• pp.124-129
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• 1996

In order to investigate the deposition chara.cteristics of water-soluble ionic components in dustfall in Kwangju city, dustfall samples were collected by deposit jar for one year from December 1992 to November 1993. The depositjon amount of dustfall and water-soluble ionic components ($SO_4^{2-}, NO_3^-, Cl^-, NH_4^+, Na^+, Ca^{2+}, Mg^{2+}, K^+$) were measured. The total deposition amount of dustfall was 10.0 ton/$km^2$/month and showed seasonal trend of Summer and Spring > Fall and Winter. The total deposition amounts of water-soluble components showed 2.41 ton/$km^2$/month and seasonal trend of Summer > Fall > Spring > Winter. Deposition amount of $SO_4^{2-}$ was 0.99 ton/$km^2$/month which makes up 41% of water-soluble components. The deposition amounts of dustfall and watersoluble components according to the sampling points were approximately similar to each other. From this result, it can be estimated that the deposition amounts of dustfall and water-soluble components in dustfall were more influenced by the seasonal variation than the regional emission characteristics of pollution source. The content of each ionic component to the deposition amount of water-soluble components showed in order of $SO_4^{2-} > Cl^- > NH_4^+ > Na^+ > Ca^{2+} = K^+ > NO_3^- > Mg^{2+}$ respectively.

• 한국대기환경학회지
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• 제2권1호
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• pp.41-54
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• 1986

Methods used for averaging PH's of rainwater and site representation have been studied, Statistical analysis was attempted regarding effects of ionic components on PH's utilizing 847 data altogether obtained in two years, 1984 and 1985. The outcome of the study may be assumarized as follows: 1. Methods for Averaging PH Volume weighted method is considered to be acceptable providing that precipitation is measured at the same time when the samples are taken. Without precipitation data a simple averaging method should be the next choice. 2. Site Representation A statistical method used for optimizing a monitoring newtork was applied using the data collected. Because of a limited number of data, no discernible conclusion can be reached suggesting that the method can serve as a good guide when the data base becomes more reliable. 3. A good correlation appears to exist betwen conductivities and ionic components in rainwater. It would, therefore, be possible to certain extend to estimate ionic concentrations from conductivity measurements by correlation equations. 4. The acidity of rainwater is effected by $SO_4^{2-}, NO_3^-, Cl^- and NH_4^+ with SO_4^{2-}$ being the most significant as demonstrated by standardized regression analysis.

• 한국대기환경학회지
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• 제11권4호
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• pp.331-337
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• 1995

This study was carried out to investigate the chemical composition of dustfall at Cheju(mean sea level; 71.7m, 33$^{\circ}$17'N, 126$^{\circ}$10'E) and Ullung island(mean sea level; 22.1m, 38$^{\circ}$29'N, 130$^{\circ}$54'E) from October 1993 to september 1994. The dustfall matter samples were collected by deposit gauges. The ionic components of each samples was analyzed by Ion Chromatograpy (Dionex 4000i), While heavy metals by Inductively Coupled Plasma Atomic Emission Spectrometry(ICP/AES; Shimadzu ICP-4). The results for seasonal variation of dustfall matter matter total amount, water-soluble ionic components and water-soluble ionic components total deposition amount to two sites were compared each other. The seasonal variations of dustfall amount at Ullung and Cheju island were found in order of Spring>Winter>Fall>Summer, and the maximum of dustfall amount were during the Yellow Sand period. Also, Total amount of water-soluble components except for $F^{[-10]}$ were high in Cheju more than Ullung island.more than Ullung island.

• Journal of Korean Society for Atmospheric Environment
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• 제19권E4호
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• pp.177-186
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• 2003

The total of 1,454 aerosol samples were collected by high volume tape sampler at the Gosan Site in Jeju Island from 1992 to 1999, and the major water-soluble ionic components were chemically analyzed. The mean concentrations of nss-S $O_4$$^{2-}$, N $H_4$$^{＋}$, and N $O_3$$^{[-10]}$ showed high values, which were 6.73, 1.45, and 1.45 ${\mu}{\textrm}{m}$/㎥, respectively, while $Ca^{2+}$ and $K^{+}$ concentrations were low with the values of 0.49 and 0.42 $\mu\textrm{g}$/㎥. The concentrations of most components increased in spring but decreased in summer, especially with the remarkable increase of $Ca^{2+}$ and N $O_3$$^{[-10]}$ concentrations in spring. The seasonal comparison of nss-S $O_4$$^{2-}$ concentrations showed higher values with the order of spring > fall 〉 winter〉 summer, but spring 〉 winter〉 fall 〉 summer for N $O_3$$^{[-10]}$ Meanwhile, the concentration levels of N $a^{+}$ and C $l^{[-10]}$ increased more in winter season. According to the investigation of wind direction effect, the concentrations of most aerosol ionic components showed higher values consistently at the westerly and northerly wind conditions. Based on the factor analysis, the atmospheric aerosols in the Gosan Site are considered to be largely affected by marine sources, followed by anthropogenic and soil sources.urces..

• 한국환경보건학회지
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• 제26권3호
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• pp.18-24
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• 2000

The collection of PM10 samples were collected by a PM10 hi-vol. air sampler from June, 1998 through May, 1999 in Kunsan located at western coastal region of Korea. We obtained 84 samples during sampling period. Samples were analyzed to quantify the concentration of ionic and metallic components such as SO42-, NO3-, Cl-, NH4+, K+, Na+, Mg2+, Zn, Cd, Cr, Pb and Fe. Seasonal variations of the concentrations by wind directions of each component were studied. We found that PM10 concentration had the highest level in winter and the lowest level in summer. When the wind direction is from west to east, the concentration of most ionic and metallic species were higher compared to reverse direction. That implied the effect of air pollutants from industrial area. Also, substantial amount of Na+ and Cl- were observed, which was assumed to the effect from the sea.

• 한국환경과학회지
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• 제31권6호
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• pp.515-524
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• 2022

This study investigated characteristics of meteorological parameters and ionic components of PM_2.5 during Asian dust events on November 28 and 30, 2018 at Busan, Korea. The seasonal occurrence frequencies of Asian dust during 1960~2019 (60 years) were 81.7% in spring, 12.2% in winter, and 6.1% in autumn. Recently, autumn Asian dust occurrence in Busan has shown an increasing trend. The result of AWS (automatic weather station), surface weather chart, and backward trajectory analyses showed that the first Asian dust of Nov. 28, 2018, in Busan came with rapid speed through inner China and Bohai Bay from Mongolia. The second Asian dust of Nov. 30, 2018, in Busan seems to have resulted from advection and deposition of proximal residual materials. These results indicated that understanding the characteristics of meteorological parameters and ionic components of PM_2.5 during Asian dust events could provide insights into establishing a control strategy for urban air quality.

• 한국지반공학회논문집
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• 제15권1호
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• pp.185-196
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• 1999

실내실험에 의하여 사질토 간극수의 이온 성분들사이 관계를 규명하기 위하여 흙의 비저항측정 상자와 STING-Rl비저항 측정기를 이용하여 분석을 수행하였다. 실험은 이온성분들의 농도를 변화시키면서 실시하였다. 또한 2~3가지 성분을 혼합한 경우에 대해서도 비저항값의 변화를 측정하였다. 실험결과는 성분중에서 비소(As)의 비저항값의 감소가 가장 컸으며, 나머지 성분들은 일반성분들과 큰 차이를 보이지는 않았다. 또한 혼합성분의 경우에는 비저항값의 범위가 간극수에 포함된 성분들의 비저항값에 따라 달라지는 것으로 나타났다.

• 한국대기환경학회지
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• 제8권3호
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• pp.191-197
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• 1992

In order to investigate the chemical components of acid precipitation at Kangwha near the Yellow Sea and Seoul in Korea, the precipitation samples were collected by wetonly precipitation sampler from February 1991 to January 1992, and pH, electric conductivity(E. C.) and major water-soluble ionic components were analyzed. Strong negative linear correlations were observed between the rainfall amount and the sum of major ionic components in $\mu eq/\ell$ at two sites. The sum of major ionic components also correlated negatively with rain intensity. The analytical results of precipitation samples at two sites were compared each other. Average values of volume-weighted pH were found to be 5.21 at Kangwha and 5.09 at Seoul. The cationic abundance($\mu eq/\ell$) in rainwater showed the general trend $NH_4^+ > Na^+ > Ca^{2+} > Mg^{2-+} > H^+ > K^+$ at Kangwah and $NH_4^+ > Ca^{2+} > Na^+ > H^+ > Mg^{2+} > K^+$ at Seoul. The anionic abundance showed the general trend $SO_4^{2-} > Cl^- > NO_3^-$ at Kangwha and $SO_4^{2-} > NO_3^- > Cl^-$ at Seoul. The concentrations of seasalt such as $Na^+ and Cl^-$ were higher at Kangwha than Seoul. The concentrations of $nss-SO_4^{2-}, nss-Cl^- and NO_3^-$ which are acid composition were higher at Seoul(96.3 $\mu eq/\ell$) than Kangwha(69.0 $\mu eq/\ell$). The contribution of seasalt to the composition of precipitation were higher at Kangwha(34.1%) than Seoul(15.7%). Ammonia and calcium species in rainwater at Kangwha and Seoul are interpreted to have 91% of neutralizing capacity of the original sulfuric and nitric acids. Provided that the precipitation acidity originates primarily from sulfate and nitrate, sulfate was found to contribute about 73-75% of the free precipitation acidity.

• 공업화학
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• 제31권3호
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• pp.305-309
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• 2020

본 연구에서는 에테르가 기능화된 이온성 액체인 [DMIm][MPEGP] (1,3-dimethylimidazolium (2-methoxy(2-ethoxy(2-ethoxy)))-ethylphosphite)와 리튬염인 LiTf₂N (lithium bis(trifluoromethanesulfonyl)imide)을 혼합하였고, 리튬염의 함량을 조절하여 전해질을 특성을 조사하였다. 제조된 전해질은 리튬염 혼합에 따라 불투명해지고 흐름성이 제한된 열방성 액정을 형성하였으며, 이때 리튬염의 함량에 따라 형성되는 이온성 액정의 자기조립구조와 이온 전도 현상을 다양한 분광학적 분석을 통해 조사하였다. 그 결과 이온성 액정의 향상된 이온전도도는 정렬된 구조를 통한 이온 전도 특성과 관계가 있음을 확인하였으며, 리튬이온전지 특성 평가에서 우수한 전기화학적 특성을 나타냄을 확인하였다.