• Title/Summary/Keyword: Ionic Polymer Metal Composite

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Platinum-Catalyzed and Ion-Selective Polystyrene Fibrous Membrane by Electrospinning and In-Situ Metallization Techniques

  • Hong, Seung-Hee;Lee, Sun-Ae;Nam, Jae-Do;Lee, Young-Kwan;Kim, Tae-Sung;Won, Sung-Ho
    • Macromolecular Research
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    • v.16 no.3
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    • pp.204-211
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    • 2008
  • A platinum-catalyzed polyelectrolyte porous membrane was prepared by solid-state compression of electrospun polystyrene (PS) fibers and in-situ metallization of counter-balanced ionic metal sources on the polymer surface. Using this ion-exchange metal-polymer composite system, fiber entangled pores were formed in the interstitial space of the fibers, which were surrounded by sulfonic acid sites ($SO_3^-$) to give a cation-selective polyelectrolyte porous bed with an ion exchange capacity ($I_{EC}$) of 3.0 meq/g and an ionic conductivity of 0.09 S/cm. The Pt loading was estimated to be 16.32 wt% from the $SO_3^-$ ions on the surface of the sulfonated PS fibers, which interact with the cationic platinum complex, $Pt(NH_3)_4^{2+}$, at a ratio of 3:1 based on steric hindrance and the arrangement of interacting ions. This is in good agreement with the Pt loading of 15.82 wt% measured by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The Pt-loaded sulfonated PS media showed an ionic conductivity of 0.32 S/cm. The in-situ metallized platinum provided a nano-sized and strongly-bound catalyst in robust porous media, which highlights its potential use in various electrochemical and catalytic systems.

Study on the IPMC electrical characteristic change For the utilization of Ocean Current Energy (해양 에너지 활용을 위한 IPMC의 전기적 특성 변화 연구)

  • Son, Kyung Min;Kim, Min;Kim, Gwan-Hyung;Kim, Hyun-jo;Byun, Gi-Sik
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2013.05a
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    • pp.531-533
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    • 2013
  • In this paper, to study the IPMC (Ionic exchange Polymer Metal Composite) material consisting of a sulfonic acid ion and fluoride combination of carbon with Nafion film greatly affected the electro-active polymer (Electro Active Polymer) characteristics and the presence of water and cationshave properties. Use or electrical energy into mechanical energy, mechanical energy, electrical energy, and can be utilized to its characteristics, depending on the water and cations in water varies greatly. Configure the device simulations in order to study the electrical properties of these IPMC. Stepper Motor using MCU and simulator designed for the electrical characterization due to the movement and to the implementation of the mechanical movement of ocean currents. In this study, configuration the IPMC and simulation device to the area of the IPMC to the efficient use of energy currents, frequency, salinity concentration, through the efficient use of the IPMC due to the bend angle of the electrical analysis and research methods we propose.

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Bending Motion Control of Electroactive Polymer Actuator-Sensor Hybrid Structure for Finger Exoskeleton (손가락 외골격용 전기활성 고분자 구동체-센서 하이브리드 구조체의 굽힘 동작 제어)

  • Han, Dong Gyun;Song, Dae Seok;Jho, Jae Young;Kim, Dong Min
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.10
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    • pp.865-871
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    • 2015
  • This study was conducted in order to develop a finger exoskeleton system using ionic polymer metal composites (IPMCs) as the actuator and sensor in a hybrid structure. To use the IPMC as an actuator producing large force, a first order transfer function was obtained using results from a block force for DC excitation that applied to two IPMCs of 20mm-width, 50mm-length, and 2.4mm thickness together. After which the validation of 200gf control with anti-windup PI controller was confirmed. A 5mm-width, 50mm-length, 0.6mm-thickness of IPMC was also modeled as a sensor for tip displacement. As a result, the IPMC sensor could been utilized as a trigger role for the actuator. Finally, an IPMC sensor and actuator were installed on the joint of a single DOF exoskeleton in the hybrid structure, and test for the control of 40gf of block force and predefined sequence of motion was performed.

Fabrication of Electro-active Polymer Actuator Based on Transparent Graphene Electrode

  • Park, Yunjae;Choi, Hyonkwang;Im, Kihong;Kim, Seonpil;Jeon, Minhyon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.386.1-386.1
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    • 2014
  • The ionic polymer-metal composite (IPMC), a type of electro-active polymer material, has received enormous interest in various fields such as robotics, medical sensors, artificial muscles because it has many advantages of flexibility, light weight, high displacement, and low voltage activation, compare to traditional mechanical actuators. Mostly noble metal materials such as gold or platinum were used to form the electrode of an IPMC by using electroless plating process. Furthermore, carbon-based materials, which are carbon nanotube (CNT) and reduced graphene-CNT composite, were used to alter the electrode of IPMC. To form the electrode of IPMC, we employ the synthesized graphene on copper foil by chemical vapor deposition method and use the transfer process by using a support of PET/silicone film. The properties of graphene were evaluated by Raman spectroscopy, UV/Vis spectroscopy, and 4-point probe. The structure and surface of IPMC were analyzed via field emission scanning electron microscope. The fabricated IPMC performance such as displacement and operating frequency was measured in underwater.

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Improvement of Mechanical Properties of IPMC through Developing a Degree of Dispersion of SWCNT/Nafion Composite (SWCNT/Nafion 복합체의 분산능 향상을 통한 IPMC의 기계적 특성 향상)

  • Kwon, Hui-June;Kim, Ha-Na;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.5
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    • pp.131-136
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    • 2011
  • Many researchers are recently studying about Electroactive polymer(EAP). But it has a physical limitation, because of property of material. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. This study focuses on the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. To come up with mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we dispersed Single-walled carbon nanotubes(SWCNTs). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. We fabricated a disperse SWCNT/Nafion composite uniformly. Through the use of the E-beam evaporator to form an uniform electrode layer, we consummated the IPMC actuator. This result shows improving 1.5 times mechanical properties about driving force in IPMC.

Electrochemical Response of Polymer Actuators using Finite Element Formulation and ANSYS/Emag

  • Kang, Sung-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.3
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    • pp.369-375
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    • 2010
  • The two-dimensional finite element formulation for the basic field equations governing electrochemical responses of ionic conducting polymer-metal composite(IPMC) actuators is proposed in the present study. Biaxial deformation of a platinum plated Nafion actuator having 4 electrodes is dominated by electro-osmosis of hydrated ions and self-diffusion of free water molecules. Some numerical studies for IPMC actuators with electric field are carried out in order to show the validity of the proposed formulation and electric field analysis for the initial condition of total charge distribution are conducted using commercial code ANSYS/Emag.

SDRE controller considering Multi Observer applied to nonlinear IPMC model

  • Bernat, Jakub;Kolota, Jakub;Stepien, Slawomir
    • Smart Structures and Systems
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    • v.20 no.1
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    • pp.1-10
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    • 2017
  • Ionic Polymer Metal Composite (IPMC) is an electroactive polymer (EAP) and a promising candidate actuator for various potential applications mainly due to its flexible, low voltage/power requirements, small and compact design, and lack of moving parts. Although widely used in industry, this material requires accurate numerical models and knowledge of optimal control methods. This paper presents State-Dependent Riccati Equation (SDRE) approach as one of rapidly emerging methodologies for designing nonlinear controllers. Additionally, the present paper describes a novel method of Multi HGO Observer design. In the proposed design, the calculated position of the IPMC strip accurately tracks the target position, which is illustrated by the experiments. Numerical results and comparison with experimental data are presented and the effectiveness of the proposed control strategy is verified in experiments.

Modeling of IPMC Actuator for the Endoscopic Microcapsule (캡슐형 내시경 로봇의 IPMC 액추에이터 모델링)

  • Oh, Sin-Jong;Kim, Hun-Mo;Choi, Hyouk-Ryeol;Jeon, Jae-Wook;Nam, Jae-Do
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.660-666
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    • 2001
  • The Ionic Polymer Metal Composite (IPMC) is one of the electroactive polymer (EAP) have potential application as micro actuators. In this study, IPMC is used as actuator to control of the direction for the endscopic microcapsule. Because it bends in water and wet conditions by applying a low voltage $(1\sim3\;V)$ to its surfaces. The basic characteristics and the static modeling of IPMC are discussed. Also the dynamic modeling is performed using the Lagrange' equation. Computer simulation results show that the performed modeling guarantee similarity of actual system.

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Biomimetic Design of IPMC Actuator having Webfoot Form (생체모방 물갈퀴형 IPMC 구동기 설계)

  • Kim, Seon-Gi;Kim, On-Ah;Lee, Seung-Yop
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1558-1562
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    • 2008
  • Ionic polymer metal composite (IPMC), one of Electro- Active Polymer (EAP) actuators, has great attention due to the low-voltage driven, large deformation and its potential for artificial muscles. In this paper, we firstly review fish swimming modes using various propulsion mechanisms. Based on study on the swimming mechanisms, we develop an underwater robot actuator which mimics fanning motion of webfoot form. It consists of four actuators fabricated by using IPMC and PDMS which mimics Bio-inspired motion Experiments using a prototype show that the webfooted IPMC actuator generates large deformation and propulsion.

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Development of Fuzzy control and Modeling of IPMC Actuator for the Endoscopic Microcapsule (캡슐형 내시경 로봇의 IPMC 액추에이터 모델링 및 퍼지 제어 알고리듬 개발에 대한 연구)

  • 오신종;김훈모;최혁렬;전재욱;남재도
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.4
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    • pp.39-48
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    • 2003
  • The Ionic Polymer Metal Composite (IPMC) is one of the electroactive polymer (EAP) have potential application as micro actuators. In this study, IPMC is used as actuator to control of the direction for the endscopic microcapsule. Because it bends in water and wet conditions by applying a low voltage (1∼3 V) to its surfaces. The basic characteristics and the static modeling of IPMC are discussed. Also the dynamic modeling is performed using the Lagrange' equation. Computer simulation results show that the performed modeling guarantee similarity of actual system.