• Title/Summary/Keyword: Ion Transport

Search Result 471, Processing Time 0.03 seconds

Facilitated ion transport through cellulose triacetate-based polymer inclusion membranes: A promising method for treatment of nuclear wastewater

  • Samuel P.Kusumocahyo;Toshiyuki Kanamori;Kim, io-Sumaru;Toshio Shinbo;Hideto Matsuyama;Masaaki Teramoto
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 2004.05a
    • /
    • pp.43-46
    • /
    • 2004
  • The large quantity of liquid wastes from nuclear industries such as nuclear power plants would become a serious storage problem in view point of the environmental safety. The liquid wastes should be concentrated to a smallest possible volume before the storage. The use of supported liquid membranes (SLMs) for this purpose is very attractive [1,2], however loss of solvent and carrier in the surrounding solutions limits the stability of SLMs and hinders their commercial application in the industries.(omitted)

  • PDF

Effect of Polycarboxylate Type Superplasticizer on the Rheological Properties of Mortar (고성능AE감수제를 이용한 모르타르의 유동특성 평가에 관한 연구)

  • Jung, Youn-Sik;Lim, Chae-Yong;Yang, Seung-Kyu;Um, Tae-Sun;Lee, Jong-Ryul
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2006.11a
    • /
    • pp.801-804
    • /
    • 2006
  • Polycarboxylate type superplasticizers(PC) have got widely used for making not only high performance concrete but low grade concrete as well. It is known that fluidity of cement with PC is affected by the characteristics of cement especially sulphate ion concentration and hydration activity. But the characteristics of PC also affect the fluidity. The fluidity of cement mortar with various types of PC was measured and critical dosage(CD) and dispersing ability(DA) was calculated. CD and DA is strongly dependent on the type of PC. And the variation of fluidity on time was affected by the type of PC also. So, it is advisable to investigate the property of PC before production of concrete and adjust it to meet the requirements of concrete depending on the materials, the time of transport and so on.

  • PDF

Growth and optical properties of undoped and Co-doped CdS single crystals (CdS 및 $CdS:Co^{2+}$ 단결정의 성장과 광학적 특성)

  • Kim, N.O.;Bang, T.H.;Hyun, S.C.;Park, K.H.;Park, H.;Oh, S.K.
    • Proceedings of the KIEE Conference
    • /
    • 2002.06a
    • /
    • pp.94-97
    • /
    • 2002
  • CdS and $CdS:Co^{2+}$ single crystals were grown by CTR method using iodine as transport material. The grown single crystals have defect chalcopyrite structure with direct band gap. The optical energy band gap was decreased according to add of Co-impurity. We can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

  • PDF

Silicon Nitride Thin Film Deposition Using ECR Plasma (ECR 플라즈마를 이용한 실리콘화박막증착)

  • 송선규;장홍영
    • Journal of the Korean institute of surface engineering
    • /
    • v.23 no.4
    • /
    • pp.218-224
    • /
    • 1990
  • Silicon nitride thin(SiNx) is deposited onto 3 inch silicon wafor using ECR plasma apparatus. For the two different plasma extraction windows size, the thin films which were deposited by changing the SiH4/N2 gas fole at at 1.5mTorr without substrate heating are analyzed through the XPS and wlliposometer measurements. The very uniform and good quality silicon nitride thin film were obtained with the analyzed results of the deposited films, and particularly, ion temperature perpendicular to the magnetic filed was nearly same as the neutral gas temperature. The large amount of plasma loss in the transport process following magnetic field lines could be seen from the plasma emission intensity measurements.

  • PDF

Memristive Devices Based on RGO Nano-sheet Nanocomposites with an Embedded GQD Layer (저결함 그래핀 양자점 구조를 갖는 RGO 나노 복합체 기반의 저항성 메모리 특성)

  • Kim, Yongwoo;Hwang, Sung Won
    • Journal of the Semiconductor & Display Technology
    • /
    • v.20 no.1
    • /
    • pp.54-58
    • /
    • 2021
  • The RGO with controllable oxygen functional groups is a novel material as the active layer of resistive switching memory through a reduction process. We designed a nanoscale conductive channel induced by local oxygen ion diffusion in an Au / RGO+GQD / Al resistive switching memory structure. A strong electric field was locally generated around the Al metal channel generated in BIL, and the local formation of a direct conductive low-dimensional channel in the complex RGO graphene quantum dot region was confirmed. The resistive memory design of the complex RGO graphene quantum dot structure can be applied as an effective structure for charge transport, and it has been shown that the resistive switching mechanism based on the movement of oxygen and metal ions is a fundamental alternative to understanding and application of next-generation intelligent semiconductor systems.

Solute Carrier SLC41A1 'A MINI REVIEW'

  • Basnet Hom Bahadur
    • Environmental Mutagens and Carcinogens
    • /
    • v.25 no.2
    • /
    • pp.60-65
    • /
    • 2005
  • The human solute carrier, SLC41Al, is a $Mg^{2}+$ transporter that is regulated by extracellular magnesium. Although intracellular magnesium plays a fundamental role in cellular metabolism, little is known about how $Mg^{2}+$ is taken up and controlled by cells. Magnesium plays a fundamental role in cellular metabolism so that its control within the body is critical. Magnesium homeostasis is principally a balance between intestinal absorption of dietary magnesium and renal excretion of urinary magnesium. The kidney, mainly the distal convoluted tubule, controls magnesium reabsorption. Although renal reabsorption is under the influence of many hormones, selective regulation of magnesium transport is due to intrinsic control involving transcriptional processes and synthesis of transport proteins. Using microarray analysis, identification of the genetic elements involved with this transcriptional control has been begun. SLC41A1(GenBank Accession No. AJ514402), comprises 10 putative transmembrane domains, two of which are highly homologous to the integral membrane part of the prokaryote transports $Mg^{2}+$ and other divalent cations $Sr^2+,\;Zn^2+,\;Cu^2+,\;Fe^2+,\;Co^2+,\;Ba^2+,\;and\;Cd^2+,\;but\;not\;Ca^2+,\;Mn^2+,\;and\;Ni^2+.$ Transport of $Mg^{2}+$ by SLC41Al is rheogenic, voltage dependent, and not coupled to Na or Cl. Expressed SLC41Al transports a range of other divalent cations: $Mg^{2+},\;Sr^{2+},\;Zn^{2+},\;Cu^{2+},\;Fe^{2+},\;Co^{2+},\;Ba^{2+},\;and\;Cd^{2+}$. The divalent cations $Ca^{2+},\;Mn^{2+},\;and\;Ni^{2+}$and the trivalent ion $Gd^{3+}$ did not induce currents nor did they inhibit $Mg^{2+}$ transport. The nonselective cation $La^{3+}$ abolishes $Mg^{2+}$ uptake. Computer analysis of the SLC41Al protein structure reveals that it belongs to MgtE protein family & suggested that the human solute carrier, SLC41Al, might be a eukaryotic $Mg^{2+}$ transporter closely related $(60-70\%)$ protein encoded by SLC41A2 is a $Mg^{2}+$ transporter that might be involved in magnesium homeostasis in epithelial cells also transports a range of other divalent cations: $Ba^2,\;Ni^2,\;CO^2,\;Fe^2,\;or\;Mn^2,\;but\;not\;Ca^2,\;Zn^2,\;or\;Cu^{2+}$ that may have related functional properties.

  • PDF

Effect of Electrode Design on Electrochemical Performance of Highly Loaded LiCoO2 Positive Electrode in Lithium-ion Batteries (리튬이온 이차전지용 고로딩 LiCoO2 양극의 전극설계에 따른 전기화학적 성능연구)

  • Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
    • /
    • v.23 no.2
    • /
    • pp.47-55
    • /
    • 2020
  • Highly loaded LiCoO2 positive electrodes are prepared to construct high-energy density lithium-ion batteries, their electrochemical performances are evaluated. For the standard electrode, a loading of about 2.2 mAh/㎠ is used, and for a high-loading electrode, an electrode is manufactured with a loading level of about 4.4 mAh/㎠. The content of carbon black as electronic conducting additive, and the porosity of the electrode are configured differently to compare the effects of electron conduction and ionic conduction in the highly loaded LiCoO2 electrode. It is expected that the electrochemical performance is improved as the amount of the carbon black increases, but the specific capacity of the LiCoO2 electrode containing 7.5 weight% carbon black is rather reduced. When the conductive material is excessively provided, an increase of electrode thickness by the low content of the LiCoO2 active material in the same loading level of the electrode is predicted as a cause of polarization growth. When the electrode porosity increases, the path of ionic transport can be extended, but the electron conduction within the electrode is disadvantageous because the contact between the active material and the carbon black particles decreases. As the electrode porosity is lowered through the sufficient calendaring of the electrode, the electrochemical performance is improved because of the better contact between particles in the electrode and the reduced electrode thickness. In the electrode design for the high-loading, it is very important to construct the path of electron conduction as well as the ion transfer and to reduce the electrode thickness.

Concentration Characteristics of Atmospheric PM2.5, PM10 and TSP during the Asian Dust Storm in Iksan Area (익산지역에서 황사발생시 PM2.5, PM10 TSP의 농도 특성)

  • Kang, Gong-Unn;Kim, Nam-Song;Kim, Kyung-Suk;Kim, Mi-Kyung;Lee, Hyun-Ju
    • Journal of Environmental Health Sciences
    • /
    • v.33 no.5
    • /
    • pp.408-421
    • /
    • 2007
  • The concentration characteristics of atmospheric particle matters (PM) including $PM_{2.5},\;PM_{10}$, and TSP were evaluated through the measurement data of PM_{2.5}$ (fine particulate), PM_{10-2.5}$ (coarse particulate), and PM_{over-10}$ collected using a MCI (multi-nozzle cascade impactor) sampler of a three-stage filter pack in spring of 2006 in Iksan area. During the sampling period of 10-15 March and 24 days from 8 April to 2 May, 32 samples for PM of each size fractions were collected, and then measured for PM mass concentrations and water-soluble inorganic ion species. Average concentrations of $PM_{2.5},\;PM_{10}$, TSP were $57.9{\pm}44.1mg/m^3$, $96.6{\pm}89.1mg/m^3$, and $114.8{\pm}99.7mg/m^3$, respectively. Water-soluble inorganic ion fractions to PM mass were found to be 36.5%, 18.0%, and 11.1% for $PM_{2.5}$, $PM_{10-2.5}$ and $PM_{over-10}$, respectively. By showing the high concentrations of PM samples during Asian dust events, those three fractions of PM were distinguished between the samples of Asian dust event and the samples of no event. However, the increase of PM concentrations observed during Asian dust events showed a different pattern for some Asian dust events. The differences of those three fractions in the size distribution may depend on differences on place of occurrence of Asian dust storm and course of transport from China continent to Iksan area in Korea. However, the extent of PM mass contribution during Asian dust events was generally dominated by the coarse particles rather than the fine fraction of PM. The variations of water-soluble inorganic ion species concentration in those three PM fractions between the samples of Asian dust event and the samples of no event were also discussed in this study.

The Study on the Separation Characteristics of ion with ion Exchange Membrane - I.The Characteristics of ion Exchange Membrane with the Separator of All-Vanadium Redox Flow Battery - (이온교환막을 이용한 이온의 분리특성에 관한 연구 - I. 전바나듐계 레독스-흐름 전지의 격막용 이온 교환막의 특성 -)

  • Kang, An-Soo
    • Applied Chemistry for Engineering
    • /
    • v.4 no.2
    • /
    • pp.393-402
    • /
    • 1993
  • Redox flow secondary battery have been studied actively as one of the most promising electrochemical energy storage devices for a wide range of applications, such as electric vehicles, photovoltaic arrays, and excess power generated by electric power plants. In all-vanadium redox flow battery using solution of vanadium-sulfuric acid as a active material, the difficulty in developing an efficient ion selective membrane can still be identified. The asymmetric cation exchange membrane(M-30) as a separator of all-vanadium redox flow battery which were obtained by the reaction of chlorosulfonation for 30 minutes under the irradiation of UV, showed its superiority in the transport number of 0.94 and electrical resistivity of $0.5{\Omega}{\cdot}cm^2$. The base membrane were prepared by lamination a low density polyethlene film of $10{\mu}m$ thickness on polyolefin membrane(HIPORE 120). The electrical resistivity of M-30 membrane in real solution of vanadium-sulfuric acid was $3.79{\Omega}{\cdot}cm^2$ and it was similar to that of Nafion 117 membrane. Also the cell resistivity was $6.6{\Omega}{\cdot}cm^2$and lower than that of Nafion 117. In considertion of electrochemical properties and costs of membranes, M-30 membrane was better than that of Nafion 117 and CMV of Asahi glass Co. as a separator of all-vanadium redox flow battery.

  • PDF

Effects of Silver lon Exchanged Water Treatment Agent upon E. Coli RB 797 and Bacillus sp. (수처리제 은이온이 E. Coli RB 797과 Bacillus sp. 에 미치는 영향)

  • 신혜자;신춘환
    • Journal of Life Science
    • /
    • v.7 no.4
    • /
    • pp.316-321
    • /
    • 1997
  • The effects of the silver ion-exchanged water treatment agent (Ag-Os) upon E. coli RB 797 and Bacillus sp. have been discussed in this study. Silver ion causes a number of toxic effects with no known biological function. Silver ion-exchanged water treatment agent (Ag-Os) using oyster shell here showed antimicrobial activities. the soluble form of silver ion in water is more toxic to the growth of Bacillus sp. than that of E. Coli RB 797. The minium amount of Ag-Os needed for growth inhibition is 0.2 mg/ml for E. Coli RB 797 and 0.02 mg/ml for Bacillus sp., which is consistant with the data of the survival cell fraction. Binding studies suggested that binding of silver to the cell surface was a rapid, metabolic-independent process and different from active transport. Bacillus sp. showed more binding than E. Coli RB 797. Reducing substances of the cell cultures in the presence of Ag-Os was detected using Methylen blue as an indicator. From these results, we suggest that Ag-Os is effective as an antimicrobial agent on E. Coli RB 797 and Bacillus sp. and silver binds to the cells through rapid, metabolic-independent process and might complex to sulfur group in the cells for its toxicity.

  • PDF