• Title/Summary/Keyword: Ion Size

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A Study on the Sheet Resistance Variation in Ion Implanted Poly-Si Thin Flim by CO2 Laser Annealing (CO2 레이저 열처리에 따른 이온 주입된 다결정 실리콘 박막의 판막저항 변화에 관한 연구)

  • Park, Pyeong-Whang;An, Chul
    • Proceedings of the KIEE Conference
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    • 1987.07a
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    • pp.539-541
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    • 1987
  • P+ ion implanted poly-Si flim with doses of 10E13-10E16 ions/$cm^2$ were annealed by CO2 laser and their sheet resistances were measured and compared with thoses of furnace annealed samples. In case of lightly doped samples, the measured sheet resistance of laser annealed samples were lower several orders of magnitude than those of furnace annealed samples. The origin of this reduction of sheet resistances is supposed to be the increase of the grain size to the extent of certain critical value.

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A Study on Low Temperature Phosphating for Cold Forming (냉간 가공용 인산염 피막처리의 저온화에 관한 연구)

  • 이만식;정충택;이광호;김준호;이근대;홍성수
    • Journal of Surface Science and Engineering
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    • v.36 no.1
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    • pp.59-68
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    • 2003
  • Zinc phosphating for cold forming of steel was studied with emphasis on decreasing phosphating temperature. To lower phosphating temperature, some techniques, such as adding Cu ion into bath, using activator in the form of pre-dip, and aeration in bath, instead of using conventional accelerator, namely oxidizing agent, have been tried. It was revealed that phosphating, leading to coatings of improved uniformity and fine crystal size, can be carried out using above techniques at lower temperature (55$^{\circ}C$) compared to conventional phosphating temperature ($80∼90^{\circ}C$). Under present condition, it was seen that optimum concentrations of Cu ion in phosphating bath and activator in pre-dip are 0.015 % (w/w) and 2.0 g/1, respectively. The coating weight was within the range of $\15∼20 g/m^2$. When lubricant was applied into phosphating coatings, the amount of lubricating component (total soap) was found to be$ 6∼10 g/\m^2$ and the lubricated panel revealed excellent lubricating properties.

Modularized Charge Equalization Converter for Hybrid Electric Vehicle Lithium-Ion Battery Stack

  • Park, Hong-Sun;Kim, Chong-Eun;Kim, Chol-Ho;Moon, Gun-Woo;Lee, Joong-Hui
    • Proceedings of the KIPE Conference
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    • 2007.07a
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    • pp.350-352
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    • 2007
  • Modularized charge equalization converter for HEV lithium-ion battery cells is proposed in this paper, in which intra-module and inter-module charge equalization can be achieved at the same time. For intra-module charge equalization, the conventional flyback DC/DC converters of low power and small size are employed, in which all of the primary sides are coupled in parallel for selective charge of the specific under charged cell within the module. For inter-module charge equalization, the flyback DC/DC converters are also added, in which all the secondary windings are electrically linked in parallel for automatic charge balancing among the modules. An engineering sample of forty cells hiring the proposed cell balancing scheme is implemented and its experimental result shows that the proposed modularized charge equalization circuit has good cell balancing performance.

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The Luminescence Property of Ba-Mg-Al-O:$Eu^2+$ Blue Phosphors (Ba-Mg-Al-O:$Eu^2+$ 청색형광체의 발광특성)

  • 김광복;천희곤;조동율;구경완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.157-161
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    • 2000
  • Blue phosphor of Ba-Mg-Al-O:Eu$^{2+}$ phase was fabricated by conventional firing techniques under reducing atmosphere and its photoluminescence properties are studied with varying Eu concentration and phost-annealing temperature under air atmosphere. This phosphors were well crystallized with particle size in the range of 3~5um and emitted a blue light at a dominent wavelength 450nm for 254nm UV irradiation. The concentration quenching wit Eu$^{2+}$ was that with increasing Eu concentration the energy transfer between the activator ions steadily improves, so that the excitation energy is transported over larger distances through the lattice before luminescence can occur. Thermal quenching also occurred in this phosphor means that in a host lattice with the $\beta$-alumina structure the bond of an Eu$^{2+}$ ion with the nearest-neighbour oxygen ion is much stronger than in a lattice with the magnetoplumbite structure.cture.

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Fabrication of Metallic Nano-filter Using UV-Imprinting Process (UV 임프린팅 공정을 이용한 금속막 필터제작)

  • Noh Cheol Yong;Lee Namseok;Lim Jiseok;Kim Seok-min;Kang Shinill
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.237-240
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    • 2005
  • The demand of micro electrical mechanical system (MEMS) bio/chemical sensor is rapidly increasing. To prevent the contamination of sensing area, a filtration system is required in on-chip total analyzing MEMS bio/chemical sensor. A nano-filter was mainly applied in some application detecting submicron feature size bio/chemical products such as bacteria, fungi and so on. We suggested a simple nano-filter fabrication process based on replication process. The mother pattern was fabricated by holographic lithography and reactive ion etching process, and the replication process was carried out using polymer mold and UV-imprinting process. Finally the nano-filter is obtained after removing the replicated part of metal deposited replica. In this study, as a practical example of the suggested process, a nano-dot array was replicated to fabricate nano-filter fur bacteria sensor application.

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3D Plasma simulation을 이용한 Cylindrical Rotating Magnetron Sputtering Cathode 개발

  • Cheon, Yong-Hwan;O, Ji-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.179.1-179.1
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    • 2013
  • Cylindrical Rotating Magnetron Sputtering Cathode (이하 Rotary Cathode)는 기존에 사용 되던 rectangular type 보다 Target 사용 효율이 높다는 큰 이점을 가지고 있다. 높은 Target 사용 효율은 비용 절감 효과와 직접적으로 관련 된다. 이번 연구는 3D Plasma simulation(PIC-MCC)을 통한 Target 사용 효율 80% 이상의 Rotary Cathode 개발을 목적으로 한다. Plasma simulation에 External Magnetic fields를 접목하여 Electron의 이동 궤적을 제어하였고, 생성된 Ion (Ar+)의 밀도 및 속도로 Plasma의 안정성과 Erosion 계산 구간을 선정 하였다. Target Erosion Profile은 Sputtering yield Data와 Target에 충돌한 Ion 정보를 사용하여 산출 하였으며, Sputtered Particles의 Deposition Profile은 계산된 Target Erosion Profile과 The cosine law of emission을 이용하여 계산 하였다. 실험 조건은 Plasma simulation의 초기조건 바탕으로 하여 2G size의 ITO Target을 대상으로 실험 하였다. 비 Erosion 영역 최소화하기 위해 Magnet Length를 변경하여 제작 적용 하였다. Simulation 계산 시간의 제약으로 인하여 simulation에서 생성된 최대 이온 밀도는 일반적으로 알려진 값 보다 적게 계산 되었지만, Simulation으로 예측한 Erosion Profile 및 Deposition Profile은 실험 값과 유사한 형태를 나타났으며, 실험 결과는 Target 사용 효율 80%이상의 결과를 보였다.

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TiN coatings by HCD plasma enhanced reactive ion plating method (HCD플라즈마를 이용한 반응성 이온플레이팅법에 의한 TiN 코팅)

  • 서용운;황기웅
    • Journal of Surface Science and Engineering
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    • v.25 no.3
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    • pp.133-143
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    • 1992
  • Titanium nitride(TiN) films have been prepared by HCD plasma enhanced reactive ion plating. Density and temperature of the plasma generated by the HCD were investigated. It was shown that parameters such as the substrate bias voltage(0 350V) and N2 flow rate(10 180SCCM) influenced the growth, the growth, the microstructure and the color tone of the film mostly. In order to study the interface region, surface analysis by AES combined with sputter depth profiling was performed. Microhardness of the coated TiN films were measured by micro Vickers hardness tester. Also, the effect of coating parameters on composition, coating surface and fracture morphology, grain size and growth rate were examined.

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A Study of the Ionic Association of the Substituted N-Methyl Pyridinium Iodide (II), 4,N-Dimethyl Pyridinium Iodide in Ethanol-Water Mixture

  • Kwun, Oh-Cheun;Jee, Jong-Gi
    • Bulletin of the Korean Chemical Society
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    • v.6 no.1
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    • pp.37-40
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    • 1985
  • The electrical conductance and UV absorbance of 4,N-dimethyl Pridinium Iodide (NDMPI) were measured in the ethanol volume percentage, 95, 90, 80 and 60 of an ethanol-water mixture at 15, 25, 35 and $45^{\circ}C$. Ionic association constants(K) of NDMPI were evaluated in accordance with a combined method of conductance UV absorbance. The ion size parameter (${\gamma}_{\pm}$) and dipole momemt (${\mu}_{A+D-}$) of NDMPI were obtained from the values of K and dielectric constant. The ${\mu}_{A+D-}$- values were in good agreement with the values of transition moment(${\mu}_{mn}$) which is calculated form the UV peak values. The large negative values of the electrical enthalpy (${\Delta}H_{el}^{\circ}$) and entropy (${\Delta}H_{el}^{\circ}$ ) have proved that NDMPI had a positive hydration. The positive values of entropy (${\Delta}S^{\circ}$) means the formation of NDMPI ion goes with dehydration.

The Effect of Alkali Metal Ions on Nucleophilic Substitution Reactions of Alkali Metal Ethoxides with S-p-nitrophenyl 2-thiofuroate and 2-Thiophenethiocarboxylate in Absolute Ethanol

  • 엄익환;이윤정;남정현;권동숙
    • Bulletin of the Korean Chemical Society
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    • v.18 no.7
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    • pp.749-754
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    • 1997
  • Rate constants have been measured spectrophotometrically for the reactions of alkali metal ethoxides (EtOM) with S-p-nitrophenyl 2-thiofuroate (1b) and 2-thiophenethiocarboxylate (2b) in absolute ethanol at 25.0±0.1 ℃. 1b is observed to be more reactive than 2b toward all the EtOM studied. The reactivity of EtOM is in the order EtOK > EtONa > EtO- > EtOLi for both substrates, indicating that K+ and Na+ behave as a catalyst while Li+ acts as an inhibitor in the present system. Equilibrium association constants of alkali metal ions with the transition state (KaTS) have been calculated from the known equilibrium association constants of alkali metal ion with ethoxide ion (Ka) and the rate constants for the reactions of EtOM with 1b and 2b. The catalytic effect (KaTS/Ka) is larger for the reaction of 1b than 2b, and decreases with decreasing the size of the alkali metal ions. Formation of 5-membered chelation at the transition state appears to be responsible for the catalytic effect.

Estimation of the neutron production of KSTAR based on empirical scaling law of the fast ion stored energy and ion density under NBI power and machine size upgrade

  • Kwak, Jong-Gu;Hong, S.C.
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.2334-2337
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    • 2022
  • Deuterium-tritium reaction is the most promising one in term of the highest nuclear fusion cross-section for the reactor. So it is one of urgent issues to develop materials and components that are simultaneously resistant to high heat flux and high energy neutron flux in realization of the fusion energy. 2.45 MeV neutron production was reported in D-D reaction in KSTAR and regarded as beam-target is the dominant process. The feasibility study of KSTAR to wide area neutron source facility is done in term of D-D and D-T reactions from the empirical scaling law from the mixed fast and thermal stored energy and its projection to cases of heating power upgrade and DT reaction is done.