• Title/Summary/Keyword: Ion Size

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The Effect of Micro Nano Multi-Scale Structures on the Surface Wettability (초소수성 표면 개질에 미치는 마이크로 나노 복합구조의 영향)

  • Lee, Sang-Min;Jung, Im-Deok;Ko, Jong-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.5
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    • pp.424-429
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    • 2008
  • Surface wettability in terms of the size of the micro nano structures has been examined. To evaluate the influence of the nano structures on the contact angles, we fabricated two different kinds of structures: squarepillar-type microstructure with nano-protrusions and without nano-protrusions. Microstructure and nanostructure arrays were fabricated by deep reactive ion etching (DRIE) and reactive ion etching (RIE) processes, respectively. And plasma polymerized fluorocarbon (PPFC) was finally deposited onto the fabricated structures. Average value of the measured contact angles from microstructures with nanoprotrusions was $6.37^{\circ}$ higher than that from microstructures without nano-protrusions. This result indicates that the nano-protrusions give a crucial effect to increase the contact angle.

A Study on Low Temperature Phosphating for Cold Forming (냉간 가공용 인산염 피막처리의 저온화에 관한 연구)

  • 이만식;정충택;이광호;김준호;이근대;홍성수
    • Journal of Surface Science and Engineering
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    • v.35 no.5
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    • pp.279-288
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    • 2002
  • Zinc phosphating for cold forming of steel was studied with emphasis on decreasing phosphating temperature. To lower phosphating temperature, some techniques, such as adding Cu ion into bath, using activator in the form of pre-dip, and aeration in bath, instead of using conventional accelerator, namely oxidizing agent, have been tried. It was revealed that phosphating, leading to coatings of Improved uniformity and fine crystal size, can be carried out using above techniques at lower temperature ($55^{\circ}C$) compared to conventional phosphating temperature ($80 ~ 90^{\circ}C$ ). Under present condition, it was seen that optimum concentrations of Cu ion in phosphating bath and activator in pre-dip are 0.015% (w/w) and 2.0 g/1, respectively. The coating weight was within the range of 15 ~ 20 g/$\m^2$. When lubricant was applied into phosphating coatings, the amount of lubricating component (total soap) was found to be 6 ~ 10 g/$\m^2$ and the lubricated panel revealed excellent lubricating properties.

Enhancement of Performance of Dye-Sensitized Solar Cell by Reducing the Interface Resistance (계면저항 감소를 통한 염료감응형 태양전지 성능 향상)

  • Kim, Hwi-Dong;Kim, Ki-Hoon;Ahn, Ji-Young;Kim, Soo-Hyung
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.360-363
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    • 2009
  • In order to improve the overall power conversion efficiency, it is very important to reduce the interface resistance of dye-sensitized solar cells (DSSCs). In this approach, tiny $TiO_2$ nanoparticles with the primary size of 10~20nm were synthesized and deposited between FTO glass and preformed $TiO_2$ layer by $TiOCl_2$ treatment, and also Pt catalysts were deposited on the counter electrode by both ion-sputter and thermal deposition to reduce the electrolyte-counter electrode interface resistance. The influence of these processes on the performace of DSSCs were discussed in terms of fill factor, short circuit current, and conversion efficiency.

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Effect of Solution Compositions on Properties of Ni-Fe Nano Thin Film and Wire Made by Electrodeposition Method (Electrodeposition법으로 제조한 Ni-Fe 나노박막 및 나노선의 특성에 미치는 용액 조성의 영향)

  • Koo, Bon-Keup
    • Journal of Surface Science and Engineering
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    • v.43 no.5
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    • pp.243-247
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    • 2010
  • The micro Vickers hardness and internal stress of Ni-Fe metal thin film synthesized by electrodeposition method at $25^{\circ}C$ were studied as a function of bath composition, and surface microstructure and atomic compositions of thin films were investigated by SEM and EDS. And the shape change of $200\;{\AA}$ Ni-Fe nanowires made using anodic aluminum oxide(AAO) templates by electrodeposition method were observed by SEM as a function of ultrasonic treatment time and bath composition. The Fe deposition contents on the substrate non-linearly increased with Fe ion concentration over total metal ion concentration. In case of low Fe contents film, the grain size is smaller and denser than high Fe contents deposited films, and the micro Vickers hardness increased with Fe contents of electrodeposited films. These results affected the shape change of nanowire after ultrasonic treatments.

Particle Simulation on the Effect of Grid Cathode Geometry in SCBF Device (SCBF 장치에서 그리드 음극 구조의 영향에 대한 입자 시뮬레이션)

  • Ju, Heung-Jin;Park, Jeong-Ho;Ko, Kwang-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.8
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    • pp.742-747
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    • 2007
  • In 2-dimensional SCBF (Spherically Convergent Beam Fusion) device, the effect on neutron production rate of the grid cathode geometry was simulated. The motion of Particles was tracked using Monte Carlo Method including the atomic and molecular collision processes and potential distribution was calculated by Finite Element Method, Main processes of the discharge were the ionization of $D_2$ by fast $D_2^+\;ion$. As the number of cathode rings was small and the size of grid cathode decreased, the ion current increased and neutron production rate will also increase. The star mode discharge which is a very important characteristic in SCBF device, was confirmed by the ionization position.

Effect of pH on the Preparation of Spherical Fine Zirconia Powders Using Gas-Liquid Phase Reaction (기액반응법을 이용한 구형 지르코니아 미분체 제조시 pH의 영향)

  • 김창현;이대희;이창섭;이병교
    • Journal of the Korean Ceramic Society
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    • v.34 no.10
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    • pp.1009-1014
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    • 1997
  • Ammonia gas was blown into the solution of zirconium ion to induce precipitation of supersaturated zirconium ion at gas-liquid interface with increase in pH. The influence of pH on the phase and particle size of precipitate and calcined powders has been investigated. At pH 4.5 of zirconium solution, maximum yield of 98.7% was obtained. Above pH 4.5, there was no more increase of yield. Above pH 5.5, large aggregates consisting of primary particles were observed in precipitate and calcined powders. At pH 4.5, almost aggregate-free fine spherical zirconia powders were obtained.

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A Study for Parallel Computing Efficiency Comparing Numerical Solutions of Battery Pack (배터리 팩 수치해석 해의 비교를 통한 병렬연산 효율성 연구)

  • Kim, Kwang Sun;Jang, Kyung Min
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.2
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    • pp.20-25
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    • 2016
  • The parallel computer cluster system has been known as the powerful tool to solve a complex physical phenomenon numerically. The numerical analysis of large size of Li-ion battery pack, which has a complex physical phenomenon, requires a large amount of computing time. In this study, the numerical analyses were conducted for comparing the computing efficiency between the single workstation and the parallel cluster system both with multicore CPUs'. The result shows that the parallel cluster system took the time 80 times faster than the single work station for the same battery pack model. The performance of cluster system was increased linearly with more CPU cores being increased.

Effects of Reaction Parameters on the Preparation of LiMn2O4 for Lithium-Ion Batteries by SHS (리튬이온전지용 LiMn2O4분말의 자전연소합성시 반응변수의 영향)

  • Jang, Chang-Hyun;Nersisyan Hayk;Won, Chang-Whan;Kwon, Hyuk-Sang
    • Journal of the Korean Ceramic Society
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    • v.43 no.9 s.292
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    • pp.588-593
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    • 2006
  • Spinel phase $LiMn_2O_4$ is of great interest as cathode materials for lithium-ion batteries. In this study, SHS (Self propagating High-temperature Synthesis) method to synthesize spinel $LiMn_2O_4$ directly from lithium nitrate, manganese oxide, manganese and sodium chloride were investigated. The influence of Li/Mn ratio, the heat-treated condition of product have been explored. The resultant $LiMn_2O_4$ synthesized under the optimum synthesis conditions shows perfect spinel structure, uniform particle size and excellent electrochemical performances.

Synthesis of Large Bumpy Silver Nanostructures with Controlled Sizes and Shapes for Catalytic Applications

  • Oh, Ju-Hwan;Kim, Do Yeon;Lee, Jae-Seung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1001-1004
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    • 2014
  • We have synthesized disc-like large silver nanomaterials that have nanostructured bumps on the surface using smaller nanoplate seeds. The size and shape of the bumpy nanostructures are rationally controlled by changing the concentrations of nanoplate seeds, silver ion, reductant, and citrate ion. Importantly, the synthetic mechanism of these bumpy nanostructures is remarkably similar to that of the conventional seed-mediated growth based on tiny seeds. We have further investigated the catalytic properties of the bumpy nanostructures for the reduction of 4-nitrophenol, which is associated with a concomitant color change from yellow to colorless.

Preparation of Ruthenium Incorporated Heterogeneous Catalysts Using Hydroxyapatite as Catalytic Supports for Aerobic Oxidation of Alcohols

  • Kim, Sohee;Jung, Jong-Hwa;Kim, Dong-Hee;Woo, Dong Kyun;Park, Joon B.;Choi, Myong Yong;Kwon, Ki-Young
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.221-224
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    • 2013
  • Three different kinds of hydroxyapatites (HAPs) having different sizes and compositions are prepared by hydrothermal and molten salt syntheses. Using the ion exchange reactions, ruthenium ions are incorporated on the surface of HAPs. The crystallinity, morphology and ruthenium contents are investigated by XRD, SEM, TEM and ICP. We found that smaller size of HAP having large amounts of ruthenium under ion exchange reaction shows higher catalytic activity for aerobic oxidation of alcohols.