• Title/Summary/Keyword: Iodine sorbents

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A method for properties evaluation of activated charcoal sorbents in iodine capture under dynamic conditions

  • Magomedbekov, Eldar P.;Obruchikov, Alexander V.
    • Nuclear Engineering and Technology
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    • v.51 no.2
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    • pp.641-645
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    • 2019
  • Experimental equipment for studying the sorption properties of iodine sorbents using radioactive methyliodide has been developed. The sorption capacity index ${\alpha}$ is proposed as a criterion parameter for assessing the quality of impregnated activated charcoals. It was found that this parameter does not depend on the dynamic conditions during the sorbent test. It was shown that values of the sorption capacity index allow to recommend iodine sorbents for industrial gas cleaning processes.

Removal of radioactive methyliodide from the gas stream with a composite sorbent based on polyurethane foam

  • Obruchikov, Alexander V.;Magomedbekov, Eldar P.;Merkushkin, Aleksei O.
    • Nuclear Engineering and Technology
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    • v.52 no.5
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    • pp.1093-1097
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    • 2020
  • A composite iodine sorbent was obtained in the form of porous polymer matrix with activated carbon particles impregnated with triethylenediamine deposited on its surface. A comparative assessment of the radioactive methyliodide capturing efficiency by the composite sorbent and a sample of industrial charcoal sorbent was conducted. It was shown that under the selected testing conditions, the hydraulic resistance of the composite sorbent is lower, and the sorption capacity is higher than that of the industrial charcoal sorbent. A method for comparing the effectiveness of iodine sorbents, based on the calculation of the ratio of the sorption capacity index to the minimum capacity index, needed for the required purification degree was proposed.

Radioiodine removal from air streams with impregnated UVIS® carbon fiber

  • Obruchikov, Alexander V.;Merkushkin, Aleksei O.;Magomedbekov, Eldar P.;Anurova, Olga M.
    • Nuclear Engineering and Technology
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    • v.53 no.5
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    • pp.1717-1722
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    • 2021
  • This study is devoted to the ability of carbon fiber material samples impregnated with various amounts of barium iodide and triethylenediamine to remove radioactive methyliodide from air streams. The main sorption characteristics of impregnated UVIS® carbon fiber were determined and the use of this material for purifying of technological gas flows at nuclear power plants was evaluated. The methyliodide trapping efficiency by samples impregnated with barium iodide, TEDA, and their mixture was 83.4 ± 0.8%; 93.1 ± 0.6% and 93.5 ± 0.7% respectively, under the same conditions. The study established a significantly higher capacity (8.3 ± 0.07 mg/cm2) of samples impregnated simultaneously with both chemical compounds toward methyliodide. Under the same test conditions, the values of this parameter for the samples impregnated separately with TEDA and BaI2 were 2.85 ± 0.05 mg/cm2 and 0.86 ± 0.04 mg/cm2, respectively.

Enhancement of Efficiency of Activated Carbon Impregnated Chitosan for Carbon Dioxide Adsorption

  • Patkool, Chaiwat;Chawakitchareon, Petchporn;Anuwattana, Rewadee
    • Environmental Engineering Research
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    • v.19 no.3
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    • pp.289-292
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    • 2014
  • The effect of carbon dioxide ($CO_2$) on global warming is serious problem. The adsorption with solid sorbents is one of the most appropriate options. In this study, the most interesting adsorbent is granular activated carbon (GAC). It is suitable material for $CO_2$ adsorption because of its simple availability, many specific surface area, and low-cost material. Afterwards, GAC was impregnated with chitosan solution as impregnated granular activated carbon (CGAC) in order to improve the adsorption capacity of GAC. This research aims to compare the physical and chemical characteristics of GAC and CGAC. The experiment was carried out to evaluate the efficiency of $CO_2$ adsorption between GAC and CGAC. The results indicated that the iodine number of GAC and CGAC was 137.17 and 120.30 mg/g, respectively. The Brunauer-Emmett-Teller results (BET) of both GAC and CGAC show that specific surface area was 301.9 and $531.3m^2/g$, respectively; total pore volume was 0.16 and $0.29cm^3/g$, respectively; and mean diameter of pore was 2.18 and 2.15 nm, respectively. Finally, the $CO_2$ adsorption results of both GAC and CGAC in single column how the maximum adsorption capacity was 0.17 and 0.25 mol/kg, respectively; how degeneration time was 49.6 and 80.0 min, respectively; and how the highest efficiency of $CO_2$ adsorption was 91.92% and 91.19%, respectively.