• Journal of Welding and Joining
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• 제14권2호
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• pp.46-56
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• 1996

HAZ impact toughness of Ti-oxide steel was investigated and compared to that of a conventional Ti-nitride steel. Toughness variations of each steel with weld peak temperatures and cooling rates were interpreted with microstructural transformation characteristics. In contrast to Ti-nitride steel showing continuous decrease in HAZ toughness with peak temperature, Ti-oxide steel showed increase in HAZ toughness above $1400^{\circ}C$ peak temperature. The HAZ microstructure of the Ti-oxide steel is characterized by the formation of intragranular ferrite plate, which was found to start from Ti-oxide particles dispersed in the matrix of the steel. Large austenite grain size above $1400^{\circ}C$ promoted intragranular ferrite plate formation in Ti-oxide steel while little intragranular ferrite plate was formed in Ti-nitride steel because of dissolution of Ti-nitrides. Ti-oxides in the Ti-oxide steel usually contain MnS and have crystal structures of TiO and/or $Ti_2O_3$.

• Journal of Welding and Joining
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• 제7권3호
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• pp.44-54
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• 1989

This study was undertaken to evaluate the allowable welding heat input range for high strength steels manufactured by various processes and to compare the weldability of TMCP steel for high heat input welding with that of conventional Ti-added normalized steel. The allowable welding heat input ranges for conventional 50kg/$mm^2$ steel to guarantee D or E grade of ship structural steel were below 150 and 80kJ/cm respectively. Such a limit in welding heat input was closely related with the formation of undesirable microstructures, such as grain boundary ferrite and ferrite side plate in the coarse grain HAZ. In case of 60 and 80kg/$mm^2$ quenched and tempered steels, for securing toughness in weldments over toughness requirements for base metal, each welding heat input had to be restricted below 60 and 40kJ/cm, that was mainly due to coarsened polygonal ferrite in weld metal and lower temperature transformation products in coarse grain HAZ. The TMCP steel could be appropriate as a grade E ship hull steel up to 200kJ/cm, but the Ti-added normalized steel could be applied only below 130kJ/cm under the same rule. This difference was partly owing to whether uniform and fine intragranular ferrite microstructure was well developed in HAZ or not.

• International Journal of Korean Welding Society
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• 제3권2호
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• pp.40-45
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• 2003

A series of experiments has been carried out to investigate the effect of titanium, boron and nitrogen on the microstructure and toughness of simulated heat affected zone (HAZ) in quenched and tempered (QT) type 490MPa yield strength steels. For acquiring the same strength level, the carbon content and carbon equivalent could be lowered remarkably with a small titanium and boron addition due to the hardenability effect of boron during quenching process. Following the thermal cycle of large heat input, the coarsened grain HAZ (CGHAZ) of conventional quenched and tempered (QT) type 490MPa yield strength steels exhibited a coarse bainitic or ferrite side plate structure with large prior austenite grains. While, titanium and boron bearing QT type 490MPa yield strength steels were characterized by the microstructure in the CGHAZ, consisting mainly of the fine intragranular ferrite microstructure. Toughness of the simulated HAZ was mainly controlled by the proper Ceq level, and the ratio of Ti/N rather than titanium and nitrogen contents themselves. In the titanium­boron added QT steels, the optimum Ti/N ratio for excellent HAZ toughness was around 2.0, which was much lower than the known Ti/N stoichiometric ratio, 3.4. With reducing Ti/N ratio from the stoichiometric ratio, austenite grain size in the coarse grained HAZ became finer, indicating that the effective fine precipitates could be sufficiently obtained even with lower Ti/N level by adding boron simultaneously. Along with typical titanium carbo­nitrides, various forms of complex titanium­ and boron­based precipitates, like TiN­MnS­BN, were often observed in the simulated CGHAZ, which may act as stable nuclei for ferrite during cooling of weld thermal cycles