• Title/Summary/Keyword: Internal electrode

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Monitoring the water absorption in GFRE pipes via an electrical capacitance sensors

  • Altabey, Wael A.;Noori, Mohammad
    • Advances in aircraft and spacecraft science
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    • v.5 no.4
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    • pp.499-513
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    • 2018
  • One of the major problems in glass fiber reinforced epoxy (GFRE) composite pipes is the durability under water absorption. This condition is generally recognized to cause degradations in strength and mechanical properties. Therefore, there is a need for an intelligent system for detecting the absorption rate and computing the mass of water absorption (M%) as a function of absorption time (t). The present work represents a new non-destructive evaluation (NDE) technique for detecting the water absorption rate by evaluating the dielectric properties of glass fiber and epoxy resin composite pipes subjected to internal hydrostatic pressure at room temperature. The variation in the dielectric signatures is employed to design an electrical capacitance sensor (ECS) with high sensitivity to detect such defects. ECS consists of twelve electrodes mounted on the outer surface of the pipe. Radius-electrode ratio is defined as the ratio of inner and outer radius of pipe. A finite element (FE) simulation model is developed to measure the capacitance values and node potential distribution of ECS electrodes on the basis of water absorption rate in the pipe material as a function of absorption time. The arrangements for positioning12-electrode sensor parameters such as capacitance, capacitance change and change rate of capacitance are analyzed by ANSYS and MATLAB to plot the mass of water absorption curve against absorption time (t). An analytical model based on a Fickian diffusion model is conducted to predict the saturation level of water absorption ($M_S$) from the obtained mass of water absorption curve. The FE results are in excellent agreement with the analytical results and experimental results available in the literature, thus, validating the accuracy and reliability of the proposed expert system.

Performance characteristics of AGM lead acid battery with the content of positive plate incorporating nano-size additive material (나노 사이즈 입자가 포함된 양극 활물질 함량에 따른 차량용 AGM 연축전지 성능 특성)

  • Lim, Tae Seop;Kim, Sung Jun;Kim, Sang Dong;Yang, Seung Cheol;Jung, Yeon Gil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.4
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    • pp.123-130
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    • 2020
  • Nano seed incorporated in micro-sized 4BS (Tetrabasic lead Sulfate) seed was applied to the positive electrode active material and compared with Nano 4BS seed (NS). The dispersion of NS decreased due to the aggregation phenomenon, while the nano seed incorporated in micro-sized 4BS seed (INS) could confirm excellent dispersion. As the content of INS increased, the particle size of the active material became small and constant, which was confirmed through SEM and particle size analysis. The specific surface area for the reaction was increased and the high-rate discharge and lifetime characteristics were improved. In order to confirm the variation in particle size distribution in the plate manufacturing process, internal resistance and voltage were measured for 200 AGM lead-acid batteries, and it was confirmed that batteries quality variation decreased.

Fabrication of CO2 Sensor Membrane by Photolithographic Method (사진식각법을 이용한 CO2 센서 감지막의 제조)

  • Park, Lee Soon;Kim, Sang Tae;Koh, Kwang-Nak
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.6-12
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    • 1998
  • A FET(Field Effect Transistor) type dissolved $CO_2$ sensor based on Severinghaus type $CO_2$ sensor was fabricated by the photolithographic process. The sensor consists of Ag/AgCl reference electrode and membranes (hydrogel membrane and $CO_2$ gas permeable membrane) on the pH-ISFET base chip. Ag/AgCl reference electrode was fabricated as follows. Ag layer was thermally evaporated and then its upper surface was chemically chloridized into the AgCl. The hydrogel used as an internal electrolyte solution was fabricated by a photolithographic method using 2-hydroxyethyl methacrylate(HEMA) and acrylamide. $CO_2$ permeable membrane on the top of the hydrogel layer was formed by photolithographic process with UV-oligomer. The FET type $pCO_2$ sensor fabricated by photolithographic method showed good linearity within the concentration range of $10^{-3}{\sim}10^0mole/{\ell}$ of dissolved $CO_2$ in aqueous solution with high sensitivity.

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Improved Mesh Grounding Electrode Model by Changing Arrangements of Internal Conductors of the Mesh Grounding Electrode (메쉬접지극의 내부도체 배치에 따른 개선된 메쉬접지극 모델)

  • Shim, Yong-Sik;Choi, Hong-Kyoo;Kim, Tae-Hoon;Song, Young-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.6
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    • pp.60-66
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    • 2010
  • Mesh grounding electrodes in Korea and abroad are designed as lattice-shaped equidistance grounding grids. In case of a lattice-shaped grounding Grid, however, there is a problem of higher touch voltage at the corner of the grid relative to the center. To overcome this problem, we used oblique-shaped equidistance grounding grid to reduce the area of the corner where mesh voltage occurs. As a result the mesh voltage was reduced. Therefore, this paper suggests the use of oblique-shaped grounding grid instead of the existing lattice-shaped ones. It applied the same grounding design dimensions for both lattice-shaped and oblique-shaped grounding grids, compared and analyzed mesh voltage, GPR, ground resistance, total length of grounding conductor, verified that oblique-shaped grounding grid is superior to the lattice-shaped.

Research on the Power Drop of Photovoltaic Module’s Aging Through the Thermal Shock Test

  • Kang, MinSoo;Jeon, YuJae;Kim, DoSeok;Shin, YoungEui
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.5
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    • pp.268-273
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    • 2015
  • While analyzing the specimens before and after the thermal shock test, we found that the power drop rate of the bare cell was 5.08%, while the power drop rate of the ribboned cell was 16.49%. In comparative terms, the efficiency was lower at the ribboned cell than at the bare cell. While analyzing through EL (Electroluminescence) shots and cross sections, we tried to decipher the exact cause of the power drop. Although mere color change of the cell was observed at the surface of the bare cell, no abnormality could be found inside the cell. On the surface of the ribboned cell, the short circuit of gridfinger extended from the front part of the front electrode of the ribboned cells. Therefore, cracks occurred on the surface of the cell. Cracks also appeared inside the cell. While analyzing the I-V curve, we determined an increase in the leakage current and an increase of resistances in series in the bare cell. In the ribboned cell, the resistances in parallel reduced remarkably. An increase of resistances in series could also be verified. Conclusively, we deduced that the power drop rate in the bare cell is a life span of the cell itself; aging is the cause of power drop rate in cells. In case of ribboned cell, the power drop rate was directly influenced by internal cracks and an intermetallic compound layer joining the ribbon at the front electrode.

Development of Thin-Film Thermo-Electrochemical Cell for Harvesting Waste Thermal Energy (폐열 에너지 수집을 위한 박막형 열-전기화학전지 개발)

  • Im, Hyeongwook;Kang, Tae June;Kim, Dae Weon;Kim, Yong Hyup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.11
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    • pp.1010-1015
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    • 2012
  • In this study, a thin-film thermo-electrochemical cell that directly converts waste thermal energy into electrical energy was fabricated. Electrical conductivity of conducting carbon fiber, which was used as flexible electrode, was increased through coating of carbon nanotube, and resistance of the CNT-coated fiber electrode was not changed even after bending test with various curvatures. Maximum output power of the thermocell was increased quadratically with the temperature difference, and showed a value of about 2.5 mW/kg at temperature difference of $3.4^{\circ}C$. As a result of discharge test for 12 hours, it is confirmed that the cell can operates continuously. And thin-film thermocell wrapped around a pipe with hot liquid flowing within was demonstrated. Internal resistance of the cell was decreased with various curvature of heat pipe, and maximum output power was increased by 30 %. Therefore, the cell can be applied to various heat source.

The Effect of Current Flow on Active Layer by n-GaN Electrode Patterns in GaN-based Vertical Light-Emitting Diodes (수직형 구조 GaN 발광다이오드의 n-GaN 위 전극구조에 따른 활성층 영역에서의 전류분포 전산모사)

  • Lee, Byoung-Gyu;Shin, Young-Chul;Kim, Eun-Hong;Kim, Chul-Min;Lee, Wan-Ho;Kim, Tae-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.326-326
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    • 2008
  • 갈륨 질화물 (GaN) 기반의 발광다이오드(Light Emitting Diode, LED)는 최근 디스플레이, 교동신호등, 휴대폰용 키패드의 광원 등에 널리 사용되는 전자소자로, 차세대 조명용 광원으로도 각광받고 있다. 일반적인 수평 구조의 LED에 비해 수직형 구조 LED 는 발광면이 n-GaN 표면 전체이며, 전류 확산 특성이 매우 뛰어남으로 인해 차세대 구조라고 표현되어 진다. 이런 구조에서 활성층 영역에서의 균일한 전류 분포는 전류밀집 현상을 억제하여 결과적으로 광학적 특성을 향상시킨다. 따라서 현재까지도 전류확산에 따른 발광다이오드의 성능향상에 대한 연구가 다각도로 이루어지고 있다. 본 연구에서는 수직형 GaN LED 의 전극 패턴에 따른 활성층 영역에서의 전류밀도 분포에 대해 조사하였다. 전극 패턴의 크기 및 구조 변화에 따른 활성층 영역에서의 전류분포도를 삼차원 회로 모델을 이용하여 분석하였다. 또한 활성층 영역으로 주입되는 전류 밀도의 크기가 내부양자효율에 미치는 영향에 대하여 알아보았다. 활성층 영역에서의 균일한 전류밀도 분포를 갖는 전극구조를 설계하였으며, 각각의 전극구조를 적용한 수직형 GaN LED의 전기/광학적 특성에 대해 전산모사 하였다. 최종적으로, n-GaN 위 전극의 크기 및 구조 변화에 대한 시뮬레이션 결과를 토대로, 균일한 전류분포 및 내부 양자효율 향상을 위한 전극패턴 설계 방침을 제안한다.

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Effect of Interfacial Reaction Layer on the Electrochemical Performance of LSGM-Based SOFCs (LSGM계 고체산화물 연료전지의 전기화학적 성능에 미치는 계면반응층의 영향)

  • Kim, Kwang-Nyeon;Moon, Jooho;Kim, Hyoungchul;Son, Ji-Won;Kim, Joosun;Lee, Hae-Weon;Lee, Jong-Ho;Kim, Byung-Kook
    • Journal of the Korean Ceramic Society
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    • v.42 no.10 s.281
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    • pp.665-671
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    • 2005
  • LSGM is known to show very serious interfacial reaction with other unit cell components, such as electrode, electrode functional or buffering layers. Especially, the formation of very resistive LaSr$Ga_{3}$$O_{7}$ phase at the interface of an anode and an electrolyte is the most problematic one in LSGM-based SOFCs. In this study, we investigated the interfacial reactions in LSGM-based SOFCs under different unit cell configurations. According to the microstructural analysis on the interfacial layer between an electrolyte and its neighboring component, serious interfacial reaction zone was observed. From the electrical and electrochemical characterization of the cell, we found such an interfacial reaction zone not only increased the internal ohmic resistance but also decreased the OCV(Open Cell Voltage) of the unit cell, and thus consequently deteriorated the unit cell performance.

Characterization of the LSGM-Based Electrolyte-Supported SOFCs (LSGM계 전해질 지지형 고체산화물 연료전지의 특성평가)

  • Song, Eun-Hwa;Kim, Kwang-Nyeon;Chung, Tai-Joo;Son, Ji-Won;Kim, Joo-Sun;Lee, Hae-Weon;Kim, Byung-Kook;Lee, Jong-Ho
    • Journal of the Korean Ceramic Society
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    • v.43 no.5 s.288
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    • pp.270-276
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    • 2006
  • LSGM(($La_xSr_{1-x})(Ga_yMg_{1-y})O_3$) electrolyte is known to show very serious interfacial reaction with other unit cell components, especially with an anode. Such an interfacial reaction induced the phase instability of constituent component and deterioration of the unit cell performance, which become the most challenging issues in LSGM-based SOFCs. In this study, we fabricated LSGM($La_{0.8}Sr_{0.2}Ga_{0.83}Mg_{0.17}O_x$) electrolyte supported-type cell in order to avoid such interfacial problem by lowering the heat-treatment temperature of the electrode fabrication. According to the microstructural and phase analysis, there was no serious interfacial reaction at both electrolyte/anode and electrolyte/cathode interfaces. Moreover, from the electrochemical characterization of the unit cell performance, there was no distinct deterioration of the open cell voltage as well as an internal cell resistance. These results demonstrate the most critical point to be concerned in LSGM-based SOFC is either to find a proper electrode material which will not give any interfacial reaction with LSGM electrolyte or to properly adjust the processing variables for unit cell fabrication, to reduce the interfacial reaction.

Low-Firing Pb(Zr,Ti)O3-Based Multilayer Ceramic Actuators Using Ag Inner Electrode

  • Han, Hyoung-Su;Park, Eon-Cheol;Lee, Jae-Shin;Yoon, Jong-Il;Ahn, Kyoung-Kwan
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.6
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    • pp.249-252
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    • 2011
  • We investigated the low firing of $Li_2CO_3$ added $0.2Pb(Mg_{1/3}Nb_{2/3})O_3$ - 0.3Pb($Fe_{1/2}Nb_{1/2}$) - $0.5Pb(Zr_{0.475}Ti_{0.525})O_3$ (PMN-PFN-PZT) ceramics and multilayer actuators (MLAs) using Ag inner electrodes. It was found that 0.1 wt% $Li_2CO_3$ was quite effective in lowering the sintering temperature of PMN-PFN-PZT ceramics from $1,100^{\circ}C$ down to $900^{\circ}C$ without deteriorating their piezoelectric ceramics ($d_{33}$ = 425 pC/N and $k_p$ = 61.9%). However, excess $Li_2CO_3$ up to 0.3 wt% brings about unwanted problems such as the formation of a $LiPbO_2$ secondary phase and subsequent degradation in the piezoelectric properties. Using 0.1 wt% $Li_2CO_3$ added PMN-PFN-PZT ceramics, MLAs with Ag inner electrodes were successfully fabricated, resulting in a normalized strain of 580 pm/V at an electric field of 1.5 kV/mm.