• Journal of the Korean Society of Safety
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• v.30 no.1
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• pp.21-27
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• 2015

In this study, interfacial characteristics between SOFC and Ag paste as current collector was estimated in the high temperature environment. The Ag paste was used to connect the unit cell of SOFC strongly with interconnector and provide the electrical conductivity between them. To confirm electrical conductivity, Ag paste was treated in the furnace at $800^{\circ}C$ for 48 hours. The sheet resistance of Ag paste was measured to compare the resistance values before and after the heat treatment. Also, the four-point bending test was performed to measure the interfacial adhesion. The unit cell of SOFC and $SiO_2$ wafer were diced and then attached by Ag paste. The $SiO_2$ wafer had the center notch to initiate a crack from the tip of the notch. The modified stereomicroscope combined with the CCD camera and system for measuring the length was used to observe the fracture behavior. To compare the characteristics before heat treatment and after heat treatment, the specimen was exposed in the furnace at $800^{\circ}C$ for 48 hours and then the interfacial adhesion was evaluated. Finally, the interfacial adhesion energy quantitatively increases $1.78{\pm}0.07J/m^2$ to $4.9{\pm}0.87J/m^2$ between the cathode and Ag paste and also increase $2.9{\pm}0.47J/m^2$ to $5.12{\pm}1.01J/m^2$ between the anode and Ag paste through the high temperature. Therefore, it is expected that Ag paste as current collector was appropriate for improving the structural stability in the stacked SOFC system if the electrical conductivity was more increased.

• Journal of Adhesion and Interface
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• v.23 no.3
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• pp.59-69
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• 2022

In composite materials, the adhesion and interfacial properties were the most important factors to obtain high performance of mechanical properties. This review paper had been focused on the micromechanical evaluation methods for the interfacial property historically. The interfacial property of fiber-reinforced composites (FRC) could be evaluated using only a single fiber and matrix via various micromechanical testing methods. Self-sensing due to the fracture behavior of FRC could be determined and discussed more critically and clearly using electro-micromechanical evaluation. In this paper, the research trends for micro-mechanical evaluation of composites was summarized, and their practical applications would be suggested in the future.

• Journal of Mechanical Science and Technology
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• v.16 no.2
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• pp.165-174
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• 2002

In the present study, interfacial cracks between an isotropic and orthotropic material, subjected to static far field tensile loading are analyzed using the technique of photoelasticity. The fracture parameters are extracted from the full-field isochromatic data and the same are compared with that obtained using boundary collocation method. Dynamic photoelasticity combined with high-speed digital photography is employed for capturing the isochromatics in the case of propagating interfacial cracks. The normalized stress intensity factors for static cracks are greate. when ${\alpha}$: 90$^{\circ}$(fibers perpendicular to the interface) than when ${\alpha}$=0$^{\circ}$(fibers parallel to the interface), and those when ${\alpha}$=90$^{\circ}$are similar to ones of isotropic material. The dynamic stress intensity factors for interfacial propagating cracks are greater when ${\alpha}$=0$^{\circ}$ than ${\alpha}$=90$^{\circ}$. For the velocity ranges (0.1 < C/C$\sub$s1/<0.7) observed in this study, the complex dynamic stress intensity factor │K$\sub$D/│increases with crack speed c, however, the rate of increase of │K$\sub$D/│with crack speed is not as drastic as that reported for homogeneous materials.

• Advances in nano research
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• v.15 no.5
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• pp.467-484
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• 2023

Despite the significant features of fiber-reinforced cementitious composites (FRCCs), including better mechanical, fractural, and durability performance, their high content of cement has restricted their use in the construction industry. Although ground granulated blast furnace slag (GGBFS) is considered the main supplementary cementitious material, its slow pozzolanic reaction stands against its application. The addition of nano-sized mineral modifiers, including nano-silica (NS), is an alternative to address the drawbacks of using GGBFS. The main object of this empirical and numerical research is to examine the effect of NS on the strain-hardening behavior of cementitious composites; ten mixes were designed, and five levels of NS were considered. This study proposes a new method, using a four-point bending test to assess the use of nano-silica (NS) on the flexural behavior, first cracking strength, fracture energy, and micromechanical parameters including interfacial friction bond strength and maximum bridging stress. Digital image correlation (DIC) was used for monitoring the initiation and propagation of the cracks. In addition, to attain a deep comprehension of fiber/matrix interaction, scanning electron microscope (SEM) analysis was used. It was discovered that using nano-silica (NS) in cementitious materials results in an enhancement in the matrix toughness, which prevents multiple cracking and, therefore, strain-hardening. In addition, adding NS enhanced the interfacial transition zone between matrix and fiber, leading to a higher interfacial friction bond strength, which helps multiple cracking in the composite due to the hydrophobic nature of polypropylene (PP) fibers. The findings of this research provide insight into finding the optimum percent of NS in which both ductility and high tensile strength of the composites would be satisfied. As a concluding remark, a new criterion is proposed, showing that the optimum value of nano-silica is 2%. The findings and proposed method of this study can facilitate the design and utilization of green cementitious composites in structures.

• Composites Research
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• v.30 no.4
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• pp.241-246
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• 2017

The brittle nature in most FRP composites is accompanying other forms of energy absorption mechanisms such as fibre-matrix interface debonding and ply delamination. It could play an important role on the energy absorption capability of composite structures. To solve the brittle nature, the adhesion between pines and composites was studied. Thermal treated pines were attached on carbon fiber reinforced polymer (CFRP) by epoxy adhesives. To find the optimum condition of thermal treatment for pine, two different thermal treatments at 160 and $200^{\circ}C$ were compared to the neat case. To evaluate mechanical and interfacial properties of pines and pine/CFRP composites, tensile, lap shear and Izod test were carried out. The bonding force of pine grains was measured by tensile test at transverse direction and the elastic wave from fracture of pines was analyzed. The mechanical, interfacial properties and bonding force at $160^{\circ}C$ treated pine were highest due to the reinforced effect of pine. However, excessive thermal treatment resulted in the degradation of hemicellulose and leads to the deterioration in mechanical and interfacial properties.

• Steel and Composite Structures
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• v.20 no.6
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• pp.1275-1303
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• 2016

Steel plates and carbon-fiber-reinforced polymer (CFRP) laminates or plates bonded to concrete substrates have been widely used for concrete strengthening. However, this technique cause plate debonding, which makes the strengthening system inefficient. The main objective of this study is to enhance the bond strength of externally bonded steel plates and CFRP laminates to the concrete surface by proposing new embedded adhesive and steel connectors. The effects of these new embedded connectors were investigated through the tests on 36 prism specimens. Parameters such as interfacial shear stress, fracture energy and the maximum strains in plates were also determined in this study and compared with the maximum value of debonding stresses using a relevant failure criterion by means of pullout test. The study indicates that the interfacial bond strength between the externally bonded plates and concrete can be increased remarkably by using these connectors. The investigation verifies that steel connectors increase the shear bond strength by 48% compared to 38% for the adhesive connectors. Thus, steel connectors are more effective than adhesive connectors in increasing shear bond strength. Results also show that the use of double connectors significantly increases interfacial shear stress and decrease debonding failure. Finally, a new proposed formula is modified to predict the maximum bond strength of steel plates and CFRP laminates adhesively glued to concrete in the presence of the embedded connectors.

• Journal of the Korean Society of Safety
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• v.28 no.4
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• pp.14-18
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• 2013

Blades of horizontal axis are nowadays made of composite materials. Generally, composite materials satisfy design provides lower weight and good stiffness, while laminate composites have often damages as like the delamination and cracks at the interface of laminates. The box spar and tail parts of a blade are composed of the CFRP/GFRP hybrid laminate composites. However, delamination and the interfacial crack often occur in the interface of CFRP/GFRP hybrid laminate composites under the mixed mode fracture condition, especially mode I and mode II. Therefore, there is a need for the evaluation of the mixed mode fracture behavior during the delamination of CFRP/GFRP hybrid laminates. This study shows the experimental results for the delamination fracture toughness in CFRP/GFRP hybrid laminate composites. Fracture toughness experiments and estimation are performed by using DMMB(Dissimilar mixed mode bending) specimen. The materials used in the test are a commercial woven type CFRP(Carbon fiber reinforced plastic) prepreg(CF3327) and UD type GFRP(Glass fiber reinforced plastic) prepreg(HD224A). A CFRP/GFRP hybrid laminate composite is composed by the 10 plies CFRP and GFRP prepreg for DMMB. A thickness of CFRP and GFRP layer is 2.5mm and 3.0mm, respectively. Also the fulcrum location which is a loading parameter is changed from 80 to 100mm on the specimen of length 120mm because it defines the ratio of mode I to mode II. In this study, the effects of the fulcrum location are evaluated in the viewpoint of energy release rate in mode I and mode II contribution. The results show that the delamination crack initiates at higher displacement and lower load according to the increase of the fulcrum location ratio. And the variation of the energy release rate for mode I and II contributions for the mode mixity are shown.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.102-105
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• 2000

Recently, applications of integrated large composite structures have been attempted to many structures of vehicles. To improve the cost performance and reliability of the integrated composite structures, it is necessary to judge structural integrity of the composite structures. For the judgement, we need fracture simulation techniques for composite structures. Many researches oil the fracture simulation method using FEM have been reported by now. Most of the researches carried out simulations considering only matrix cracking and fiber breaking as fracture modes, and did not consider delamination. Several papers have reported the delamination simulation, but all these reports require three-dimensional elements or quasi three- dimensional elements for FEM analysis. Among fracture mechanisms of composite laminates, delamination is the most important factor because it causes stiffness degradation in composite structures. It is known that onset and propagation of delamination are dominated by the strain energy release rate and interfacial moment. In this study, laminated composite has been described by using 3 dimensional finite elements. Then impact behavior of the laminated composite is simulated using FEM(ABAQUS/Explicit) with progressive failure mechanism. These results are compared with experimental results.

• Journal of the Korean Ceramic Society
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• v.41 no.6
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• pp.430-434
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• 2004

The values of fracture energy and mechanical flexural strength of Fiber Reinforced Cement (FRC) with polypropylene (PP) fiber modified by Ion Assisted Reaction (JAR), by which functional groups were grafted on the surface of PP fiber, was improved about 2 times as those of fracture energy and flexural strength of cement reinforced by untreated PP fiber. PP fiber was irradiated in O$_2$ environment by Ar$\^$+/ ion. The contact angle of PP treated by IAR decreased largely when compared with untreated PP. From this result, we expected that surface energy and interfacial adhesion force of treated PP fiber increased. The strain hardening occurred in the strain-stress curve of FRC including PP treated by IAR when compared with that of FRC with untreated PP. These enhanced mechanical properties might be due to strong interaction between hydrophilic group on modified PP fiber and hydroxyl group in cement matrix. This hydrophilic group on surface modified PP fiber was confirmed by XPS analysis. We clearly observed hydration products that were fixed at modified PP fiber due to the strong adhesion force of interface in cement reinforced modified PP by SEM (Scanning Electron Microscopy) study.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1993.10a
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• pp.656-659
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• 1993

The failure phenomenon of Dual Basalt Fibers Reinforced Epoxy Composites(DFC) under tensile load was studied using acoustic emission(AE) technique. AE amplitude and AE energy were mainly associated with the internal microscopic failure mechanism of DFC specimen, such as fiber fracture, matrix cracking, and fiber/matrix debonding. Fiber failures in the DFC specimens were distinguishable by showing the highest AE energy amplitude. They were dependant on the fiber diameters. Matrix cracking was determined from the relatively lower AE amplitude and AE energy, whereas fiber/matrix debonding could not be successfully isolated. AE method, however, can be applicable to the fragmentation method for interfacial strength(IFSS) in DFC specimens with adjusting the threshold to isolate fiber breaks from matrix crack and debonding.