• 제목/요약/키워드: Interface reaction

검색결과 698건 처리시간 0.03초

Improved Method for Calculating Armature-Reaction Field of Surface-Mounted Permanent Magnet Machines Accounting for Opening Slots

  • Zhou, Yu;Li, Huaishu;Wang, Qingyu;Xue, Zhiqiang;Cao, Qing;Zhou, Shi
    • Journal of Electrical Engineering and Technology
    • /
    • 제10권4호
    • /
    • pp.1674-1681
    • /
    • 2015
  • This paper presented an improved analytical method for calculating armature-reaction field in the surface-mounted permanent magnet machines accounting for opening slots. The analytical model is divided into two types of subdomains. The current of the armature is centralized in the center of the slots. The field solution of each subdomain is obtained by applying the interface and boundary conditions of the model. Two 30-pole/36-slot prototype machines with different slot-opening width are used for validation. The FE (finite element) results confirm the validity of the analytical results with the proposed model. The investigation shows that the wider the slot-opening width is, the smaller the peak value of radial and circumferential components of flux density, and the analytical armature-reaction field produced by centralized current in the slots is similar with the armature-reaction field produced by distributed current in the slots in the FE.

LSGM계 고체산화물 연료전지의 전해질-음극 사이의 계면안정성 (Interfacial Stability Between Anode and Electrolyte of LSGM-Based SOFCs)

  • 김광년;문주호;손지원;김주선;이해원;이종호;김병국
    • 한국세라믹학회지
    • /
    • 제42권7호
    • /
    • pp.509-515
    • /
    • 2005
  • Interfacial reactions at LSGM electrolyte and NiO-GDC anode interfaces were thoroughly investigated with Environmental Scanning Electron Microscopy (ESEM-PHlLIPS XL-30) and Energy Dispersive X-ray (EDX-Link XL30). According to the analysis, serious reaction zone was observed at LSGM/NiO-GDC interface. It was found that the reaction layer was originated from the chemical reaction between NiO and LSGM. The reaction products were identified as La deficient form of LSGM based perovskite and Ni-La-O compounds such as LaSrGa$_{3}$O$_{7}$ and LaNiO$_{3}$ from the X-Ray Diffraction (XRD, Philips) analysis. According to the electrical characterization, interfacial layer was very electrically resistive which would be the cause of high internal resistance and low power generating characteristic of the unit cell.

Ag 함유량에 따른 Sn-Ag-Cu 솔더의 Solderability 및 반응 특성 변화 (Solderability Evaluation and Reaction Properties of Sn-Ag-Cu Solders with Different Ag Content)

  • 유아미;이종현;강남현;김정한;김목순
    • 대한용접접합학회:학술대회논문집
    • /
    • 대한용접접합학회 2006년 추계학술발표대회 개요집
    • /
    • pp.169-171
    • /
    • 2006
  • Solderability and reaction properties were investigated for four Pb-free alloys as a function of Ag contents; Sn-4.0Ag-0.5Cu, Sn-3.0Ag-0.5Cu, Sn-2.5Ag-0.5Cu, and Sn-1.0Ag-0.5Cu. The alloy of the lowest Ag content, i.e., Sn-1.0Ag-0.5Cu, showed poor wetting properties as the reaction temperature decreased to 230oC. Variation of Ag concentration in the Sn-xAg-0.5Cu alloy shifted exothermic peaks indicating the undercooling temperature in DSC curve. For the aging process at 170oC, the thickness of IMCs at the board-side solder/Cu interface increased with the Ag concentration.

  • PDF

Imaging the Enzymatic Reaction of Urease Using Liquid Crystal-Based pH Sensor

  • Hu, Qiong-Zheng;Jang, Chang-Hyun
    • Bulletin of the Korean Chemical Society
    • /
    • 제32권12호
    • /
    • pp.4377-4381
    • /
    • 2011
  • In this study, real-time and label-free methods for monitoring the enzymatic reaction of urease, which releases ammonia through the hydrolysis of urea in an aqueous solution, were developed using a liquid crystal (LC)-based pH sensor. Nematic liquid crystal 4-cyano-4'-pentylbiphenyl (5CB), doped with 4'-pentyl-biphenyl-4-carboxylic acid (PBA), exhibited a shift in optical appearance from bright to dark when it was in contact with ammonia generated from the enzymatic reaction between urease and urea. This optical change was attributed to the anchoring transitions of LCs caused by hydrophobic interactions between the tails of deprotonted PBA ($PBA^-$) molecules and the LCs at the aqueous/LC interface. This novel technique holds great promise for the sensitive detection of urease along with its substrates and inhibitors.

차량 시물레이터의 운전석 시스템 개발 (Development of a Driving Operation System for Vehicle Simulator)

  • 유성의;박민규;유기성;이민철
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 제어로봇시스템학회 2000년도 제15차 학술회의논문집
    • /
    • pp.291-291
    • /
    • 2000
  • A vehicle driving simulator is a virtual reality device which a human being feels as if the one drives a vehicle actually. Driving Operation System acts as an interface between a driver and a driving simulator. This paper suggests the driving operation system for a driving simulator. This system consists of a controller, DC geared motor, MR brake, rotary encoders, steeping motor and bevel gear box. Reaction force and torque on the steering system were made by DC_Motor and MR_Brake. Reaction force and torque on the steering system were compare between real car and a driving simulator. The controller based on the 80C196KC micro processor that manage and transfer signal.

  • PDF

Investigation of Interface Reaction between TiAl Alloys and Mold Materials

  • 김명균;김영직
    • 소성∙가공
    • /
    • 제8권3호
    • /
    • pp.289-289
    • /
    • 1999
  • This paper describes the investment casting of TiAl alloys. The effects of mold material and mold preheating temperature for the investment casting of TiAl on metal-mold interfacial reaction were investigated by means of optical micrography, hardness profiles and an electron probe microanalyzer. The mold materials examined were colloidal silica bonded ZrO₂, ZrSiO₄, A1₂O₃and CaO stabilized ZrO₂. When compared with conventional titanium a1loy, the high aluminum concentration of TiAl alloys helps to lower their reactivity in the molten state. The A1₂O₃mold is a promising mold material for the investment casting of TiAl in terms of the thermal stability, formability and cost. Special attention need to be paid to thermal stability and mold preheating when developing the investment calling of TiAl alloys.

SiC/Co 반응의 계면화학 (Interface chemistry of SiC/Co reaction)

  • 임창성
    • 한국결정성장학회지
    • /
    • 제5권2호
    • /
    • pp.109-121
    • /
    • 1995
  • SiC/Co 반응커플을 Ar/4 vol% $H_2$분위기하에서 $950^{\circ}C$에서 $1250^{\circ}C$ 범위에서 4시간에서 100시간까지 열처리하였다. $950^{\circ}C$ 이상의 온도에서의 고상반응으로 여러 가지 규소화물과 탄소석출이 형성되었다. 이 반응 zone에 있어서의 전형적인 반응층의 순서는 $SiC/CoSi + C/Co_2Si + C/Co_2Si/Co_2Si + C/{\cdots\cdots}/Co_2Si/Co$이었다. 그리고 탄소 석출거동을 동반한 주기적인 띠구조의 형성기구가 반응운동학과 열역학적인 고찰을 통하여 조사되어졌고 논하여졌다. 이 반응의 zone의 서장은 시간의 함수관계를 가지며 이러한 반응운동학이 반응상수의 측정을 통하여 제시되어진다. 또한 microhardness 측정을 통하여 반응 zone의 기계적인 물성이 조사되어졌다.

  • PDF

INFLUENCE OF INVESTMENT/CERAMIC INTERACTION LAYER ON INTERFACIAL TOUGHNESS OF BODY CERAMIC BONDED TO LITHIA-BASED CERAMIC

  • Park, Ju-Mi
    • 대한치과보철학회지
    • /
    • 제44권6호
    • /
    • pp.683-689
    • /
    • 2006
  • Statement of problem. Interfacial toughness is important in the mechanical property of layered dental ceramics such as core-veneered all-ceramic dental materials. The interfaces between adjacent layers must be strongly bonded to prevent delamination, however the weak interface makes delamination by the growth of lateral cracks along the interface. Purpose. The purpose of this study was to determine the effect of the reaction layer on the interfacial fracture toughness of the core/veneer structure according to the five different divesting. Materials and methods. Thirty five heat-pressed Lithia-based ceramic core bars (IPS Empress 2), $20mm{\times}3mm{\times}2mm$ were made following the five different surface divesting conditions. G1 was no dissolution or sandblasting of the interaction layer. G2 and G3 were dissolved layer with 0.2% HF in an ultrasonic unit for 15min and 30 min. G4 and G5 were dissolved layer for 15min and 30min and then same sandblasting for 60s each. We veneered bilayered ceramic bars, $20mm{\times}2.8mm{\times}3.8mm$(2mm core and 1.8mm veneer), according to the manufacturer's instruction. After polishing the specimens through $1{\mu}m$ alumina, we induced five cracks for each of five groups within the veneer close to interface under an applied indenter load of 19.6N with a Vickers microhardness indenter. Results. The results from Vickers hardness were the percentage of delamination G1:55%, G2:50%, G3:35%, G4:0% and G5:0%. SEM examination showed that the mean thickness of the reaction layer were G1 $93.5{\pm}20.6{\mu}m$, G2 $69.9{\pm}14.3{\mu}m$, G3 $59.2{\pm}20.2{\mu}m$, G4 $0.61{\pm}1.44{\mu}m$ G5 $0{\pm}0{\mu}m$. The mean interfacial delamination crack lengths were G1 $131{\pm}54.5{\mu}m$, G2 $85.2{\pm}51.3{\mu}m$, and G3 $94.9{\pm}81.8{\mu}m$. One-way ANOVA showed that there was no statistically significant difference in interfacial crack length among G1, G2 and G3(p> 0.05). Conclusion. The investment reaction layer played important role at the interfacial toughness of body ceramic bonded to Lithia-based ceramic.

Si 웨이퍼의 UBM층 도금두께에 따른 무플럭스 플라즈마 솔더링 (Fluxless Plasma Soldering with Different Thickness of UBM Layers on Si-Wafer)

  • 문준권;강경인;이재식;정재필;주운홍
    • 한국표면공학회지
    • /
    • 제36권5호
    • /
    • pp.373-378
    • /
    • 2003
  • With increasing environmental concerns, application of lead-free solder and fluxless soldering process have been taken attention from the electronic packaging industry. Plasma treatment is one of the soldering methods for the fluxless soldering, and it can prevent environmental pollution cased by flux. On this study fluxless soldering process under $Ar-H_2$plasma using lead free solders such as Sn-3.5 wt%Ag, Sn-3.5 wt%Ag-0.7 wt%Cu and Sn-37%Pb for a reference was investigated. As the plasma reflow has higher soldering temperature than normal air reflow, the effects of UBM(Under Bump Metallization) thickness on the interfacial reaction and bonding strength can be critical. Experimental results showed in case of the thin UBM, Au(20 nm)/Cu(0.3 $\mu\textrm{m}$)/Ni(0.4 $\mu\textrm{m}$)/Al(0.4 $\mu\textrm{m}$), shear strength of the soldered joint was relatively low as 19-27㎫, and it's caused by the crack observed along the bonded interface. The crack was believed to be produced by the exhaustion of the thin UBM-layer due to the excessive reaction with solder under plasma. However, in case of thick UBM, Au(20 nm)/Cu(4 $\mu\textrm{m}$)/Ni(4 $\mu\textrm{m}$)/Al(0.4 $\mu\textrm{m}$), the bonded interface was sound without any crack and shear strength gives 32∼42㎫. Thus, by increasing UBM thickness in this study the shear strength can be improved to 50∼70%. Fluxed reflow soldering under hot air was also carried out for a reference, and the shear strength was 48∼52㎫. Consequently the fluxless soldering with plasma showed around 65∼80% as those of fluxed air reflow, and the possibility of the $Ar-H_2$ plasma reflow was evaluated.

단일 성분 고분자 나노 계면의 도입을 통한 블락 고분자 박막의 나노 구조 배향 조절 (Orientational Control of Nano Structures from Block Copolymer Using Homo-Polymer Nano Interface)

  • 인인식
    • 접착 및 계면
    • /
    • 제9권4호
    • /
    • pp.30-33
    • /
    • 2008
  • 블락 고분자 박막과 기판 사이의 계면에 1 nm 두께의 얇은 단일 성분 고분자 나노 계면을 도입함으로써 블락 고분자 나노 구조의 배향을 조절하는 연구가 수행되었다. Polystyrene-block-poly (methyl methacrylate) (PS-b-PMMA) 블락 고분자 박막의 나노 구조를 조절하기 위하여 블락 고분자의 각각의 고분자들의 평균 조성을 가지며 한쪽 끝에 히드록시 기를 가지는 단일 성분 고분자인 폴리(4-아세톡시스티렌) (OH-PAS)과 폴리(4-메톡시스티렌) (OH-PMS)를 나이트록사이드를 이용한 라디칼 중합법(nitroxide-mediated radical polymerization, NMP)을 사용하여 성공적으로 합성하였다. 실리콘 웨이퍼 표면과 저압 탈수 반응을 통하여 OH-PAS와 OH-PMS 두 개의 고분자를 성공적으로 표면에 공유결합 하였으며 생성된 두 고분자가 결합된 1 nm 두께의 계면 위에 PS-b-PMMA 블락 고분자 박막을 도포하여 그 나노 구조의 배향을 분석하였다. OH-PMS를 사용하여 제작된 계면의 경우 블락 고분자에 대하여 약 30%의 수직 배향을 보여주었고 OH-PAS를 사용하여 제작된 계면의 경우 수직 배향을 전혀 보여주지 않았고 오직 수평 배향만을 보여주었다. 결과적으로 계면의 화학적 조성을 정밀하게 조절하는 것이 블락 고분자 박막의 나노 구조 배향을 조절하는 데 가장 중요한 요소라고 고려된다.

  • PDF