• Bulletin of the Korean Chemical Society
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• v.18 no.9
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• pp.976-981
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• 1997

The magnetic susceptibilities of molybdenum ions with 4d1 electronic configuration in the octahedral crystal field were calculated on the basis of ligand field theory. The experimental magnetic susceptibilities for molybdenum ions, which are stabilized at the octahedral site in the perovskite lattice of Ba2ScMoⅤO6 and Sr2YMoⅤO6, were compared with the theoretical ones. We have tried to fit their temperature dependence of magnetic susceptibility with ligand field parameters, spin-orbit coupling constant ζSO, and orbital reduction parameter κ according to intermediate field coupling and strong field theory. Strong field coupling theory could not explain experimental curves without unrealistically large axial ligand field, since it ignores the mixing up between different state via spin-orbit interaction and ligand field. On the other hand, the intermediate field coupling theory could successfully reproduce experimental data in octahedral and trigonal ligand field. The fitting result demonstrates not only the fact that spin-orbit interaction is primarily responsible for the variation of magnetic behavior but also the fact that effective orbital overlap, enhanced by cubic crystal structure, reduces significantly orbital angular momentum as indicated by κ parameter.

• Rubber Technology
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• v.5 no.2
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• pp.94-103
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• 2004

The present work describes modification of dual phase filler by electron beam irradiation in presence of multifunctional acrylates like trimethylol propane triacrylate (TMPTA) or silane coupling agent like bis (3-triethoxysilylpropyltetrasulphide) and in-fluence of the modified fillers on the physical properties of styrene-butadiene rubber (SBR) vulcanizates. Modulus at 300 % elongation increases whereas the tensile strength decreases with increase in radiation dose for the dual phase filler loaded styrene-butadiene rubber vulcanizates (SBR). However, modulus and tensile strength significantly increase, which is more, pronounced at higher filler loadings for TMPTA modified dual phase filler loaded SBR. These changes in properties are explained by the equilibrium swelling data and Kraus plot interpreting the polymer-filler interaction. Electron beam modification of the filler results in a reduction of tan ${\delta}$ at $70^{\circ}C$, a parameter for rolling resistance and increase in tan ${\delta}$ at $0^{\circ}C$, a parameter for wet skid resistance of the SBR vulcanizates. Finally, the influence of modified fillers on the properties like abrasion resistance, tear strength and fatigue failure and the improvement in the properties have been explained in terms of polymer-filler interaction.

• Structural Engineering and Mechanics
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• v.91 no.4
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• pp.403-416
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• 2024

The single-column pier girder bridge, due to its low engineering cost, small footprint, and aesthetic appearance, is extensively employed in urban viaducts and interchange ramps. However, its structural design makes it susceptible to eccentric loads, flexural-torsional coupling effects, and centrifugal forces, among others. To evaluate its anti-overturning performance reasonably, it is crucial to determine the reaction force of the support for the single-column pier girder bridge. However, due to the interaction between vehicle and bridge and the complexity of vibration modes, it poses a significant challenge to analyze the theory or finite element method of single-column pier girder bridges. The unit load bearing reaction coefficient method is proposed in this study to facilitate the static analysis. Numerous parameter analyses have been conducted to account for the dynamic amplification effect. The results of these analyses reveal that the dynamic amplification factor is independent of road surface roughness but is influenced by factors such as the position of the support. Based on parameter analysis, the formula of the dynamic amplification factor is derived by fitting.

• Resources Recycling
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• v.20 no.6
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• pp.56-62
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• 2011

Zirconium is used in nuclear reactors as a structural material due to its excellent corrosion resistance and to low neutron crosssection. Variation in the distribution and solubility of Zr(IV) with solution pH was obtained. Distribution of Zr(IV) containing species in HCl and $HNO_3$ solution was analyzed by considering the complex formation of Zr(IV) species with the anion of the inorganic acid. Bromley interaction parameter between $ZrO^{2+}$ and nitrate ion was estimated by using the reported data on the solvent extraction of Zr(IV) by Cyanex272 from $HNO_3$ solution. This Bromley parameter can be utilized in calculating extraction isotherm of Zr(IV) and in predicting the separation factor between Zr(IV) and Hf(IV).

• Structural Engineering and Mechanics
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• v.75 no.1
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• pp.109-122
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• 2020

An asymptotic local plane strain elasticity theory is reformulated for the static analysis of a simply-supported, multiple graphene sheet system (MGSS) in cylindrical bending and resting on an elastic medium. The dimension of the MGSS in the y direction is considered to be much greater than those in the x and z directions, such that all the field variables are considered to be independent of the y coordinate. Eringen's nonlocal constitutive relations are used to account for the small length scale effects in the formulation examining the static behavior of the MGSS. The interaction between the MGSS and its surrounding foundation is modelled as a Winkler foundation with the parameter k_w, and the interaction between adjacent graphene sheets (GSs) is considered using another Winkler model with the parameter c_w. A parametric study with regard to some effects on the static behavior of the MGSS resting on an elastic medium is undertaken, such as the aspect ratio, the number of the GSs, the stiffness of the medium between the adjacent layers and that of the surrounding medium of the MGSS, and the nonlocal parameter.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.71-74
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• 2007

Large Eddy Simulation(LES) has been conducted to insight interaction effects of turbulent flow and chemical reaction of a lean-Premixed swirl combustor. The unsteady turbulent flame is carefully simulated so that the motion of flow and flame can be characterized in detail. Fuel lumps escaping from the primary combustion zone move downstream and consequently produce local hot spots conveying large vortical structures in the azimuthal direction. The correlation between pressure oscillation and unsteady heat release is examined by the spatial and temporal Rayleigh parameter.

• Advances in nano research
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• v.10 no.3
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• pp.263-270
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• 2021

The present manuscript focuses the effects of suction on the flow of the dusty fluid along permeable exponentially stretching cylinder. Derived PDEs for this work are changed into ODEs by adopting right transformations. Numerical procedure is carried out for the obtained resultant equations by Shooting Technique in accordance with Runge-Kutta (RK-6) technique. Obtained results for the parameters namely, particle interaction parameter, suction parameter and Reynold number parameters are probed thoroughly. Some salient points are: (a) Fluid velocity decreases and the dust phase velocity rises for the higher values of particle interaction parameter; (b) more suction produces retarding velocities for both the phases; (c) high Reynold number slows down the fluid velocity while the speed of dust phase and (d) skin friction coefficient goes high for all these parameters.

• Journal of the Korean Society for Railway
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• v.15 no.2
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• pp.162-171
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• 2012

In this study, a new dynamic interaction analysis method for tilting trains and curved track is presented. Three dimensional lumped parameter vehicle elements are used to model tilting train, and the proposed analysis technique can simulate driving direction change of vehicle, the effect of track cant, wheel-rail contact angle, and tilting angle of tilting trains, etc. The proposed method passed several basic verification tests, and it is expected that the suggested method is applicable for practical problems.

• Speech Sciences
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• v.10 no.1
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• pp.95-105
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• 2003

This paper describes a new parameter for voice activity detection which serves as a front-end part for automatic speech recognition systems. The new parameter called run-ratio is derived from the runs test statistic which is used in the statistical test for randomness of a given sequence. The run-ratio parameter has the property that the values of the parameter for the random sequence are about 1. To apply the run-ratio parameter into the voice activity detection method, it is assumed that the samples of an inputted audio signal should be converted to binary sequences of positive and negative values. Then, the silence region in the audio signal can be regarded as random sequences so that their values of the run-ratio would be about 1. The run-ratio for the voiced region has far lower values than 1 and for fricative sounds higher values than 1. Therefore, the parameter can discriminate speech signals from the background sounds by using the newly derived run-ratio parameter. The proposed voice activity detector outperformed the conventional energy-based detector in the sense of error mean and variance, small deviation from true speech boundaries, and low chance of missing real utterances

• Journal of the Society of Naval Architects of Korea
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• v.38 no.4
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• pp.11-22
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• 2001

The interaction between forward mounted propeller and wing in ground effect, and its aerodynamic performance are analyzed by potential flow approximation. A Vortex Lattice Method(VLM) for the propeller analysis and a potential based panel method for the WIG are used together with an image method by assuming the free surface as a rigid wall. The interaction of propeller and wing in the proximity of the ground is taken into account by an iterative procedure where the boundary conditions are satisfied with the given convergence criteria. The program developed is first checked by comparing its numerical results with the experimental data and other numerical results for the propeller MP101-rudder MR21 system. Then, the propeller-WIG interaction and its performance versus ground clearance are investigated by changing parameters such as propeller position, diameter and speed of revolution. It is shown that the forward mounted propeller increases the lift forces of the wing and also enhances the height stability, depending on the design parameter. Therefore, the appropriate selection of the design parameter such as propeller diameter, revolution, the longitudinal and vertical position of propeller is necessary.