• Title/Summary/Keyword: Intensity of bond

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A Study on the Trade Structure between Korea and RCEP Participating Countries (한국과 RCEP 참여국가와의 무역구조에 관한 연구)

  • Kim, Min-Soo
    • The Journal of Industrial Distribution & Business
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    • v.9 no.1
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    • pp.89-97
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    • 2018
  • Purpose - The Regional Comprehensive Economic Partnership (RCEP) among 16 countries including South Korea, the largest free trade agreement in the Asia-Pacific region, will be concluded next year. The participating countries decided to pursue a comprehensive and high -quality agreement, while ensuring flexibility considering development level of each country. In this study, trade structures between nations from 2005 through 2016 were examined to see the impact that this agreement will have on Korea and to come up with effective countermeasures. Research design, data, and methodology - The method of analysis includes the analysis of the trade matrix, which is useful for identifying the dependency of the individual countries on the market in the region and the reciprocal dependency of the member countries on the market, and the index of intensity of trade, which is useful for figuring out the share of trade between the parties in total trade. Results - The results showed that first, the international trade coefficients of Vietnam and Philippines are higher than those of China and Japan. Secondly, the international inducement coefficients between China and Japan were high, and that between Indonesia and Burma were low, indicating that Korea's exports did not have much effect on export increase of these countries. Third, as a result of analyzing Korea's trade intensity, it was found that export intensity and import intensity were greater than 1 in Vietnam and Philippines, which shows that there is a high degree of relational bond with these countries. India and Laos countries still have a low level of relational bond, which indicates that there is room for improvement in economic relations when the agreement is concluded. After the signing of the agreement in the future, more diverse industrial structures should be continuously studied. Conclusions - The analysis of trade matrix, trade structure, trade inducement coefficient and trade intensity between Korea and RCEP participating countries shows that the majority of the countries have the high level of economic relationship with Korea. Korea should drive a harder bargain when negotiating the terms of the RCEP, in comparison with the level of the existing FTA agreement excluding Japan.

Effect of RTA on Leakage Current of $Ta_2O_5$ Thin Films Deposited by PECVD (PECVD법으로 증착된 $Ta_2O_5$박막의 누설전류에 미치는 RTA의 영향)

  • Kim, Jin-Beom;Lee, Seung-Ho;So, Myeong-Gi
    • Korean Journal of Materials Research
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    • v.4 no.5
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    • pp.550-555
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    • 1994
  • The effects of RTA treatment on the leakage current have been studied for tantalum pentoxide( $Ta_2O_5$) films deposited by PECVD on P-type(100) Si substrate using $TaCl_5$(99.99%) and $N_2O$(99.99%) gaseous mixture. The refractive index increased with increasing the deposition temperature and the maximum deposition rate was obtained at $500^{\circ}C$. The Ta-0 bond peak intensity of as-deposited $Ta_2O_5$ increased with increasing the deposition temperature through FT-IR analysis and the leakage current value was decreased with increasing the deposition temperature. The small leakage current value obtained after RTA treatment of as-deposited $Ta_2O_5$ was found to be due to the reduction of 0-deficient structure in the film. The increases of the oxygen coacentration and the Ta-0 bond peak intensity in the film after RTA treatment were measured by AES and FT-IR analyses.

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A bond graph approach to energy efficiency analysis of a self-powered wireless pressure sensor

  • Cui, Yong;Gao, Robert X.;Yang, Dengfeng;Kazmer, David O.
    • Smart Structures and Systems
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    • v.3 no.1
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    • pp.1-22
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    • 2007
  • The energy efficiency of a self-powered wireless sensing system for pressure monitoring in injection molding is analyzed using Bond graph models. The sensing system, located within the mold cavity, consists of an energy converter, an energy modulator, and a ultrasonic signal transmitter. Pressure variation in the mold cavity is extracted by the energy converter and transmitted through the mold steel to a signal receiver located outside of the mold, in the form of ultrasound pulse trains. Through Bond graph models, the energy efficiency of the sensing system is characterized as a function of the configuration of a piezoceramic stack within the energy converter, the pulsing cycle of the energy modulator, and the thicknesses of the various layers that make up the ultrasonic signal transmitter. The obtained energy models are subsequently utilized to identify the minimum level of signal intensity required to ensure successful detection of the ultrasound pulse trains by the signal receiver. The Bond graph models established have shown to be useful in optimizing the design of the various constituent components within the sensing system to achieve high energy conversion efficiency under a compact size, which are critical to successful embedment within the mold structure.

An Experimental Study on the Bond Strength of the Metal Sprayed Coating According to the Shape and Size of the Attachment (어태치먼트의 형상 및 크기가 금속용사 방식피막의 부착강도에 미치는 영향에 관한 실험적 연구)

  • Park, Seungi-Gi;Park, Jin-Ho;Ryu, Hua-Sung;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.109-110
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    • 2016
  • The recent introduction of Metal spraying method apply to construction and civil steel structure is increasing. In applying the metal spraying lining process of construction and civil steel structure to secure the adhesion strength between the metal thermal spray coating and the steel structure and the highest priority requirements are required bond strength test reliable measurement accordingly. In this study, by calculating the deposition intensity and the standard deviation, coefficient of variation corresponding to the bonding area, unlike the shape of the attachment we compared the results.

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Etching Mechanism Of Bi4-xEuxTiO12 (BET) Thin films Using Ar/CF4 Inductively Coupled Plasma (Ar/CF4 유도결합 플라즈마를 이용한 BET 박막의 식각 메카니즘)

  • 임규태;김경태;김동표;김창일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.4
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    • pp.298-303
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    • 2003
  • Bi$_4$-$_{x}$EU$_{x}$Ti$_3$O$_{12}$ (BET) thin films were etched by inductively coupled CF$_4$/Ar plasma. We obtained the maximum etch rate of 78 nm/min at the gas mixing ratio of CF$_4$(10%)/Ar(90%). The variation of volume density for F and Ar atoms are measured by the optical emission spectroscopy. As CF$_4$increased in CF$_4$/Ar plasma, the emission intensities of F increase, but Ar atoms decrease, which confirms our suggestion that emission intensity is proportional to the volume density of atoms. From X-ray photoelectron spectroscopy, the intensities of the Bi-O, the Eu-O and the Ti-O peaks are changed. By pure Ar plasma, intensity peak of the oxygen-metal (O-M : TiO$_2$, Bi$_2$O$_3$, Eu$_2$O$_3$) bond was seemed to disappear while the intensity of pure oxygen peak showed an opposite tendency. After the BET thin films was etched by CF$_4$/Ar plasma, the peak intensity of O-M bond increase slowly, but more quickly than that of peak belonged to pure oxygen atoms due to the decrease of Ar ion bombardment. Scanning electron microscopy was used to investigate etching Profile. The Profile of etched BET thin film was over 85$^{\circ}$./TEX>.

Quantum Mechanical Investigation for the Structure and Vibrational Frequencies of Dimethyldioxirane (Dimethyldioxirane의 분자구조와 Vibrational Frequencies에 대한 양자역학적 고찰)

  • Kang, Chang Duk;Kim, Seung Joon
    • Journal of the Korean Chemical Society
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    • v.42 no.1
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    • pp.9-15
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    • 1998
  • The geometrical parameters, vibrational frequencies, and IR intensities of dimethyldioxirane had been investigated using high level ab initio quantum mechanical methods with various basis sets. The polarization function decreases C-O and C-C bond distances significantly and the electron correlation effect increases those bond lengths slightly, while other bond lengths and bond angles are relatively stable for basis set size and correlation effect. The experimental and other theoretical vibrational frequencies and IR intensities of dimethyldioxirane will be compared and discussed with our high level theoretical predictions.

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Study on the Properties of $B_2O_3$-$SiO_2$and $Al_2O_3$-$SiO_2$Coating Films by the Sol-Gel Method (Sol-Gel법으로 제조한 $B_2O_3$-$SiO_2$$Al_2O_3$-$SiO_2$ 박막의 특성에 관한 연구)

  • 황규석;김병훈;최석진
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.583-588
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    • 1990
  • Glass films in the binary system B2O3-SiO2 and Al2O3-SiO2 were prepared on soda-lime-silica slide glass by the dip-coating technique from TEOS and boric acid or aluminum nitrate. Thickness of the films varying with viscosity and withdrawal speed were measured and effect of composition and firing temperature on the properties such as transmittance and refractive index were investigated. nM2O3.(100-n)SiO2(M=B or Al) films containing up to 20mol% B2O3 and 40mol% Al2O3 were transparent. Maximum transmittance at visible range were obtained for the sample containing 15mol% Ba2O3 and 32.5mol% Al2O3 and heat-treated at 50$0^{\circ}C$, respectively. Refractive index of the film containing 15mol% B2O3 was mininum in the B2O3-SiO2 binary system and minimal refractive index was appeared at the film containing 32.5mol% Al2O3. In IP spectra, addition of B2O3 were increased absorption peak intensity of B-O and Si-O-B bond and addition of Al2O3 were decreased absorption peak intensity of Si-O bond, respectively.

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Preliminary Study of Rapeseed Flour-based Wood Adhesives for Making Wood Flooring

  • Yang, In;Ahn, Sye-Hee;Choi, In-Gyu;Han, Gyu-Seong;Oh, Sei-Chang
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.5
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    • pp.451-458
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    • 2011
  • Adhesives derived from renewable resources allow wood panel producers to make lower cost alternatives to formaldehyde-based adhesive resins. Among them, adhesive components extracted from industrial by-products or wastes are the most important research fields in the efficient utilization of waste and cost reduction. In our study, the rapeseed flour, which is a by product from the production of biodiesel extracted from rapeseed, was introduced to develop alternative adhesives for the production of wood flooring. The rapeseed flour was hydrolyzed with 1% sodium hydroxide solution and PF prepolymers were prepared with 3-molar ratios, 1.8, 2.1 and 2.4. The linear fracture mechanics was introduced to evaluate the glue bond quality in wood flooring composed of fancy-veneered and plywood, and the formaldehyde emission and adhesive penetration were also investigated. The formaldehyde emissions of wood flooring met the requirement of the standard of $SE_0$ specified in the KS standard. The rapeseed flour adhesive penetrated sufficiently into the vessel elements and lumens in fancy veneer and plywood and gave strong bond quality to the wood flooring. The fracture mechanics was introduced to evaluate the adhesive joint between fancy veneer and plywood. The critical stress intensity factor ($K_{IC}$) of boliva overlayed wood flooring was increased with increasing molar ratio and this was the same tendency in oak overlayed wood flooring. From the results, the formulated adhesives were efficiently used to bond fancy veneer onto the plywood to make wood flooring and showed a potential to be used as a component of environmentally friendly adhesive resin systems for production of flooring.

FTIR Spectroscopic Analysis of Structural Changes of Cellulosic Fibres During Papermaking Process

  • Kim, Hyoung-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.2
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    • pp.51-58
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    • 1998
  • Structural changes of cellulosic fibres during the papermaking process were studied by analysis of FTIR spectra collected by the transmission method. The spectra were obtained from a carefully prepared handsheet, using a special infra-red (IR) cell suitable for evacuating the sample. The deconvolution technique was also applied for sharpening the FTIR spectra in the frequency range of the OH and CH stretching bands, which gave detailed information on the structural changes of cellulose. The intensity of some bands was decreased by predrying the sample as a result of the removal of adsorbed moisture. An increase in intensity of some bands in the frequency range of 3700 to $3200cm^{-1}$ was shown at a higher beating level. This increase in intensity was caused by changes in the crystal domain of cellulose resulting from the exposure of the crystalline area on the fibre surface.

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Theoretical Studies on the Photochemical Reactions of 5,7-Dimethoxycoumarin with Adenosine. The Electronic States of 5,7-Dimethoxycoumarin and their Photoadducts

  • Kim, Ja-Hong;Han, Goang-Lae;Song, Young-Chil;Sohn, Sung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.10 no.3
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    • pp.223-226
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    • 1989
  • The chemical reactivity of 5,7-dimethoxycoumarine with adenosine has been calculated by the frontier electron and PPP-Cl MO methods. Results suggest that the major reactivity of the 5,7-dimethoxycoumarin is highest at the carbon-4 (position 4), whereas the electrophilic reactivity is generally spread all over the 5,7-dimethoxycoumarin molecule. These results are consistent with the experimental photoaddition reaction products. The small change of bond orders on excitation does not give enough reactivity to triplet states or the efficient intersystem crossing from $T_1\;to\;S_0$ inhibits photoaddition of 5,7-dimethoxycoumarine to adenosine. Although the relative intensity of the singlet band appears to be considerably higher than the triplet band intensity, its integrated intensity, i.e. oscillator strength, is comparable to that of the 5,7-dimethoxycoumarin and adenosine bands.