• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.566-574
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• 2011

Coal gasifier is a key component for achieving high efficiency in integrated gasification combined cycle and indirect coal liquefaction. Although there have been several successful coal gasifiers that were commercially proven, many different design configurations are still possible for a simple and reliable gasifier operation. Four different gasifier design concepts of dry-feeding were compared in terms of residence time, exit syngas temperature and syngas composition. First, cold-flow simulation was applied to pre-select the configuration concepts, and the hot-flow simulation including chemical reactions was performed to compare the concepts at more actual gasifier operating conditions. There are many limitations in applying CFD method in gasifier design, particularly in estimating slag behavior and slag-tap design. However, the CFD analysis proved to be useful in comparing the widely different gasifier design concepts as a pre-selection tool.

• Journal of Ceramic Processing Research
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• v.19 no.5
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• pp.378-382
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• 2018

It is a known fact that the cement production is responsible for almost 5% of total worldwide $CO_2$ emission, the primary factor affecting global warming. Geopolymers are valuable as ordinary Portland cement (OPC) substitutes because geopolymers release 80% less $CO_2$ than OPC and have mechanical properties sufficiently similar to those of OPC. Therefore, geopolymers have proven attractive to eco-friendly construction industries. Geopolymers can be fabricated from aluminum silicate materials with alkali activators such as fly ash, blast furnace slag, and so on. Integrated gasification combined cycle (IGCC) slag has been used for fabricating geopolymers. In general, IGCC slag geopolymers are fabricated with finely ground and sieved (<128 mesh) IGCC slag. The grinding process of as-received IGCC slag is one of the main costs in geopolymer production. Therefore, the idea of using as-received IGCC slag (before grinding the IGCC slag) as aggregates in the geopolymer matrix was introduced to reduce production cost as well as to enhance compressive strength. As-received IGCC slag (0, 10, 20, 30, 40 wt%) was added in the geopolymer mixing process and the mixtures were compared. The compressive strength of geopolymers with an addition of 10 wt% as-received IGCC slag increased by 19.84% compared to that with no additional as-received IGCC slag and reached up to 41.20 MPa. The enhancement of compressive strength is caused by as-received IGCC slag acting as aggregates in the geopolymer matrix like aggregates in concrete. The density of geopolymers slightly increased to $2.1-2.2g/cm^3$ with increasing slag addition. Therefore, it is concluded that a small addition of as-received IGCC slag into the geopolymer can increase compressive strength and decrease the total cost of the product. Moreover, the direct use of as-received IGCC slag may contribute to environment protection by reducing process time and $CO_2$ emission.

• Journal of Energy Engineering
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• v.17 no.2
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• pp.54-66
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• 2008

After the Kyoto Protocol has been ratified in Feb. 16 2005, the developed countries which is involved in Annex-1 have tried to mitigate GHG to the reduction objective. To accomplish this objective, EU developed EU-ETS, CDM project, and so on. Korea has faced pressure to be a member of Annex-1, because Korea and Mexico are only non-Annex-1 countries in the OECD nations. In this study, we simulated power plant expansion plan and calculated $CO_2$ emission with changing Carbon Tax. Especially, we focused on the competitiveness of IGCC and carbon capture technology. In our result, even though carbon tax rise, nuclear power plant does not always increase, it increase up to minimum load. LNG combined cycle power plants substitute the coal fired power plants. If there are many alternatives like IGCC, these substitute a coal fired power plant and we can reduce more $CO_2$ and save mitigation cost.

• Journal of Energy Engineering
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• v.5 no.2
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• pp.160-169
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• 1996

Parametric studies are conducted for optimizing the integration design between gas turbine compressor and air separation unit (ASU) of integrated gasification combined cycle power plant. The present study adopts the ASU of double-distillation column process, from which integration conditions with compressor such as the heat exchanger condition between air and nitrogen, the amount and the pressure of extracted air are defined and mathematically formulated. The performance variations of the compressor integrated with ASU are analyzed by combining streamline curvature method and pressure loss models, and the predicted results are compared with the performance test results of actual compressors to verify the prediction accuracy. Using the present performance prediction method, the effects of pinch-point temperature difference (PTD) in the heat exchanger, the amount and the pressure of extracted air on compressor performances are quantitatively examined. As the extraction air amount or the PTD is increased, the pressure ratio and the power consumption of compressor are increased. The compressor efficiency deteriorates as the increase of the flow rate of air extracted at higher pressure level while improving at lower pressure air extraction. Furthermore, through the characteristic curve between generalized inlet condition and efficiency of compressor, optimal integration condition is presented to maximize the compressor efficiency.

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.592-602
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• 2014

In the Integrated Gasification Combined Cycle (IGCC), the stability of the gasifier has strong influences on the rest of the plant as it supplies the feed to the rest of the power generation system. In order to ensure a safe and stable operation of the entrained-flow gasifier and for protection of the gasifier wall from the high internal temperature, the solid slag layer thickness should be regulated tightly but its control is hampered by the lack of on-line measurement for it. In this study, a previously published dynamic simulation model of a Shell-type gasifier is reproduced and two different linear model predictive control strategies are simulated and compared for multivariable control of the entrained-flow gasifier. The first approach is to control a measured secondary variable as a surrogate to the unmeasured slag thickness. The control results of this approach depended strongly on the unmeasured disturbance type. In other words, the slag thickness could not be controlled tightly for a certain type of unmeasured disturbance. The second approach is to estimate the unmeasured slag thickness through the Kalman filter and to use the estimate to predict and control the slag thickness directly. Using the second approach, the slag thickness could be controlled well regardless of the type of unmeasured disturbances.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.30 no.1
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• pp.33-39
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• 2020

Lightweight geopolymers were fabricated by using fused slag from integrated gasification combined cycle as a law material and Si sludge from silicon wafer process as a bloating material for the purpose of replacing autoclaved lightweight concrete (ALC). Density and compressive strength of geopolymers were measured and compared with the properties of ALC according to the variation of mol concentration of alkaline activator, W/S ratio, addition of fibers, and addition of polystyrene and the possibility of replacing ALC panel was estimated through the comparisons. Although the geopolymer satisfying the standard of ALC panel was not made by controlling mol concentration and W/S ratio, addition of inserts such as fibers and polystyrene insert was tried to overcome the obstacle of enhancing properties. Geopolymers cannot satisfying the standard of ALC panel by adding carbon or glass fibers; however, adding fibers can be suggested as one of the methods enhancing compressive strength because the compressive strength of the specimen containing 0.3 wt.% glass fibers was increased by 3 times. The maximum addition of polystyrene insert was turned out to be 50 vol.% and the properties of geopolymers varied by the method of insertion. When using single polystyrene insert, compressive strength was 17.8 MPa and density was 0.996 g/㎤ which were similar values to the standard of ALC panel. If the difficulties of reproductivity of production and insertion method of inserts were overcome through the future research, the geopolymers containing polystyrene inserts could possibly replace ALC panel.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.8
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• pp.632-638
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• 2013

This paper describes on the flame stability and combustion instability of coal derived synthetic gas especially for gases of Buggenum IGCC in Netherlands and Taean IGCC in Korea. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Flame stability map is plotted according to the flame structure by dividing all regimes into six, and only regime I and II are identified to be stable. Both syngases of Taean and Buggenum with nitrogen integration corresponds to regime II in which syngas burnt stably and flame coupled with outer recirculation flow. Stable regime of Buggenum is larger than that of Taean when considering only $H_2$/CO ratio due to higher content of hydrogen. However, when considering nitrogen dilution, syngas of Taean is burnt more stably than that of Buggenum since more nitrogen in Buggenum has negative effect on the stability of flame.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.8
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• pp.639-648
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• 2013

This paper describes on the NOx/CO emission characteristics, temperature characteristics and flame structures when firing coal derived synthetic gas especially for gases of Buggenum and Taean IGCC. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Nitrogen addition caused decrement in adiabatic flame temperature, thus resulting in the NOx reduction. At low heat input condition, nitrogen dilution raised the CO emission dramatically due to incomplete combustion. These NOx reduction and CO arising phenomena were observed at certain flame temperature of $1500^{\circ}C$ and $1250^{\circ}C$, respectively. As increasing nitrogen dilution, adiabatic flame temperature and combustor liner temperature were decreased and singular points were detected due to change in flame structure such as flame lifting. From the results, the effect of nitrogen dilution on the NOx/CO and flame structure was examined, and the test data will be utilized as a reference to achieve optimal operating condition of the Taean IGCC demonstration plant.

• Journal of Energy Engineering
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• v.6 no.2
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• pp.176-187
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• 1997

As a way to evaluate the performance of IGCC (Integrated Gasification Combined Cycle) processes, heating values of coal gas as well as plant efficiency were compared for different rank coals and coal feeding methods by employing the static process simulation technique. Performance of the process was compared with coal rank that was varied by three assorted bituminous coals and also by three subbituminous coals, in addition to the two types of feeding techniques, i.e., dry-feeding and slurry-feeding, that are utilized in entrained-bed coal gasifiers. For the verification of the simulation technique, simulated results were compared first with the actual pilot plant data published from Shell and Texaco. The simulation technique was, then, applied to other coals. Result from tests varying coal rank exhibits the trend of improving both heating content of the product gas and plant efficiency with increasing carbon content in coal. The effect of coal rank is more sensitive in slurry-feeding cases compared to the dry-feeding cases. In particular, considering notably lower values in gas heating value and plant efficiency calculated in the slurry-feeding case that uses a subbituminous coal, limited utilization of the slurry-feeding method for subbituminous coals can be expected. From the plant efficiency point of view, dry-feeding method resulted in higher simulated efficiency values by maximum 3% for subbituminous coals and ca. l% for bituminous coals.

• Clean Technology
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• v.13 no.4
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• pp.266-273
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• 2007

The adsorption properties of the activated carbon-based adsorbents were studied to remove COS emitted from $SO_2$ catalytic reduction process on the integrated gasification combined cycle (IGCC) system in this work. Transition metal supported catalysts and mixed metal oxide catalysts were used for the $SO_2$ catalytic reduction. The mechanism of COS produced from the $SO_2$ reduction and the COS concentration s according to the reaction temperature were investigated. In this study, an activated carbon and a modified activated carbon doped with KOH were used to remove the very low concentration of COS effectively. The adsorption rate and the breakthrough time of COS were measured by a thermo gravity analyzer (TGA, Cahn Balance) and a fixed bed flow reactor equipped with GC-pulsed flammable photometric detector (PFPD), respectively. It was confirmed that the COS breakthrough time of the activated carbon doped with KOH was longer than that of an activated carbon. In conclusion, the modified-activated carbon having a high surface area showed a high adsorption rate of COS produced from the $SO_2$ reduction.