• Solar Energy
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• v.15 no.3
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• pp.29-38
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• 1995

The heat-storage characteristics accompanied by exothermic reaction at the regeneration of $Ca(OH)_2$ in tile heat-storage mode of a chemical heat pump system using a $Ca(OH)_2/CaO$ reversible thermochemical reaction was examined in a lab-scale unit. In this heat-storage mode, the particle bed of CaO could be regenerated by heating the $Ca(OH)_2$ packed bed to the higher temperature at which the equilibrium pressure in the reactor is greater than the water vapor pressure in the condenser. The results are i) the dehydration, thermal decomposition, rate of $Ca(OH)_2$ was higher at the lower part of particle bed than at the upper part, ii) in the reactor, the dehydration was proceeded along radial and axial direction, from inner part to the outer part, which explains heat transfers from the center to wall and from the tenter to lower or upper part of reactor.

• Environmental Engineering Research
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• v.25 no.3
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• pp.309-315
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• 2020

Slaughterhouse wastewater (SWW) is characterized as one of the most harmful agriculture and food industrial wastewaters due to its high organic content. The emissions of SWW would cause eutrophication of surface water and pollution of groundwater. This study developed a pilot scale anaerobic-aerobic slaughterhouse wastewater treatment process (AASWWTP) to enhance the chemical oxygen demand (COD) and total nitrogen (TN) removal. The optimum supernatant reflux position and ratio for TN removal were investigated through the modified Box-Behnken design (BBD) experiments. Results showed that COD could be effectively reduced over the whole modified BBD study and the removal efficiency was all higher than 98%. The optimum reflux position and ratio were suggested to be 2 alure and 100%, respectively, where effluent TN concentration was satisfied with the forthcoming Chinese discharge standard of 25 mg/L. Anaerobic digestion and ammonia oxidation were considered as the main approaches for COD and TN removal in the AASWWTP. The results of inorganic nutrients (K⁺, Na⁺, Ca²⁺ and Mg²⁺) indicated that the SWW was suitable for biological treatment and the correspondingly processes such as AASWWTP should be widely researched and popularized. Therefore, AASWWTP is a promising technology for SWW treatment but more research is needed to further improve the operating efficiency.

• Journal of Electrochemical Science and Technology
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• v.7 no.4
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• pp.306-315
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• 2016

Amorphous vanadium titanates (aVTOs) are examined for use as a negative electrode in lithium-ion batteries. These amorphous mixed oxides are synthesized in nanosized particles (<100 nm) and flocculated to form secondary particles. The $V^{5+}$ ions in aVTO are found to occupy tetrahedral sites, whereas the $Ti^{4+}$ ions show fivefold coordination. Both are uniformly dispersed at the atomic scale in the amorphous oxide matrix, which has abundant structural defects. The first reversible capacity of an aVTO electrode ($295mAhg^{-1}$) is larger than that observed for a physically mixed electrode (1:2 $aV_2O_5$ | $aTiO_2$, $245mAhg^{-1}$). The discrepancy seems to be due to the unique four-coordinated $V^{5+}$ ions in aVTO, which either are more electron-accepting or generate more structural defects that serve as $Li^+$ storage sites. Coin-type Li/aVTO cells show a large irreversible capacity in the first cycle. When they are prepared under nitrogen (aVTO-N), the population of surface hydroxyl groups is greatly reduced. These groups irreversibly produce highly resistive inorganic compounds (LiOH and $Li_2O$), leading to increased irreversible capacity and electrode resistance. As a result, the material prepared under nitrogen shows higher Coulombic efficiency and rate capability.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.673-676
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• 2008

Recent trends show an increased usage of 'colored concrete', a inorganic pigmented concrete mix, especially in small to large scale buildings. However, due to lack of regulations, current usage of colored concrete indicates a lack of consideration for safety factors and aesthetic aspects. Sometimes color pigmentation used in paints are inappropriately used in concrete, and in many cases the addition of coloring material is done without proper research into how structural characteristics of resulting concrete may have been affected. To resolve these issues, some construction sites apply ASTM or ACI regulations. However, such regulations incorporate elements that cannot be applied in Korea, which makes their domestic application impractical. In this paper, the primary aim is to determine to what extent the basic material characteristics of concrete is affected by the variety and quantity of different color pigments, and in so doing establish a foundation for future reference in case of construction projects involving the use of colored concrete.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.726-731
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• 2011

The technology enabling the large-scale production of catalysts by extrusion is very important for the commercialization of the Fischer-Tropsch process. In this study, the influence of the binder on the extrudate of Fe-based catalyst well known as FT catalysts has been studied. Inorganic binders such as kaolin, bentonite, alumina sol and silica sol and organic binders were added during extrudate preparation. The extrudates have been prepared with various compositions, and the physicochemical properties of the extrudates have been examined by XRD, BET, PSD, TPR and UTM. The optimum binder composition of extrudate was established by comparing the FT reaction activity.

• Hwankyungkyoyuk
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• v.15 no.1
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• pp.137-147
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• 2002

The progress of environmental science and technology in the developed countries has been rapid in recent years. Particularly remarkable has been the advancement of various pollutant control measures, which have brought the pollution of inorganic factors such as air and water under control. In contrast, diversity of the ecosphere, of which man is a part, is being steadily Impoverished and the biological community is getting unvaryingly uniform. These phenomena were brought about by the expansion of artificial environment such as new industrial complexes, transportation facilities and urban development. Man has constructed uniform and artificial environment, believing in the premise of confrontation with nature, to such a scale that the natural environment and biological community have lost their balance. This will increasingly endanger the soundness of the biotic environment of nature, which constitutes the potential foundation both for the survival environment of man as biological entity and for the development of human civilization. In order to guarantee the soundness of man's body, intelligence and sensitivity as wholesome gene Pool on the earth and for the future of man, primarily important environmental education is the understanding of how man can everlasting exist in and with the survival environment. In view of this reality, it is vitally important to create ecologically diverse and well-balanced environment with living materials, i.e., vegetation in order to secure lasting survival environment for man. This task is urgently required in highly artificial environment where non-biological materials have forced the impoverishment of the biological community. Therefore, environmental education for the future should not be totally oriented to technology as that in the past nor it is limited to the medical aspect where well-being of human is the sole object of concern. That is to say, environmental education for the future should be one that provides knowledge that human can understand his place based on the ecological concept and thereby make him to have ethical consciousness that he can control his behavior within the reasonable level for ecological niche who he is located.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.5
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• pp.549-555
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• 2015

Objective of this study was to investigate the effect of carbonized biomass from crop residues on chemical properties of soil and soil carbon pools during soybean cultivation. The carbonized biomass was made by field scale mobile pyrolyzer. A pot experiment with soybean in sandy loam soil was conducted for 133 days in a greenhouse, by a completely randomized design with three replications. The treatments consisted of four levels including the control without input and three levels of carbonized biomass inputs of $9.75Mg\;ha^{-1}$, C-1 ; $19.5Mg\;ha^{-1}$, C-2 ; $39Mg\;ha^{-1}$, C-3. Soil samples were collected and analyzed pH, EC, TC, TN, inorganic-N, available phosphorus and exchangeable cations of the soils. Soil pH, Total-N and available phosphorus contents correspondingly increased with increasing the carbonized material input. The contents of soil carbon pools were $19.04Mg\;C\;ha^{-1}$ for C-1, $26.19Mg\;C\;ha^{-1}$ for C-2, $33.62Mg\;C\;ha^{-1}$ for C-3 and $12.01Mg\;C\;ha^{-1}$ for the control at the end of experiment, respectively. Increased contents of soil carbon pools relative to the control were estimated at $7.03Mg\;C\;ha^{-1}$ for C-1, $14.18Mg\;C\;ha^{-1}$ for C-2 and $21.62Mg\;C\;ha^{-1}$ for C-3 at the end of experiment, respectively, indicating that the soil carbon pools were increased with increasing the input rate of the carbonized biomass. Consequently, it seems that the carbonized biomass derived from the agricultural byproducts such as crop residues could increase the soil carbon pools and that the experimental results will be applied to the future study of soil carbon sequestration.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.37 no.3
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• pp.209-219
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• 2019

Satellite imagery occurs geometric and radiometric errors due to external environmental factors at the acquired time, which in turn causes false-alarm in change detection. These errors should be eliminated by geometric and radiometric corrections. In this study, we propose a methodology that automatically and simultaneously performs geometric and radiometric corrections by using the SURF (Speeded-Up Robust Feature) algorithm and the mask filter. The MPs (Matching Points), which show invariant properties between multi-temporal imagery, extracted through the SURF algorithm are used for automatic geometric correction. Using the properties of the extracted MPs, PIFs (Pseudo Invariant Features) used for relative radiometric correction are selected. Subsequently, secondary PIFs are extracted by generated mask filters around the selected PIFs. After performing automatic using the extracted MPs, we could confirm that geometric and radiometric errors are eliminated as the result of performing the relative radiometric correction using PIFs in geo-rectified images.

• Journal of Environmental Science International
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• v.30 no.3
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• pp.195-206
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• 2021

Contaminated marine sediment is a secondary pollution source in the coastal areas, which can result in increased nutrients concentrations in the overlying water. We analyzed the nutrients release characteristics into overlying water from sediments and the interaction among benthic circulation of nitrogen, phosphorus, iron, and sulfur were investigated in a preset sediment/water column. Profiles of pH, ORP, sulfur, iron, nitrogen, phosphorus pools were determined in the sediment and three different layers of overlying water. Variety types of sulfur in the sediments plays a significant role on nutrients transfer into overlying water. Dissimilatory nitrate reduction and various sulfur species interaction are predominantly embodied by the enhancing effects of sulfide on nitrogen reduction. Contaminant sediment take on high organic matter, which is decomposed by bacteria, as a result promote bacterial sulfate reduction and generate sulfide in the sediment. The sulfur and iron interactions had also influence on phosphorus cycling and released from sediment into overlying water may ensue over the dissolution of ferric iron intercede by iron-reducing bacteria. The nutrients release rate was calculated followed by release rate equation. The results showed that the sediments released large-scale quantity of ammonium nitrogen and phosphate, which are main inner source of overlying water pollution. A mechanical migration of key nutrients such as ammonia and inorganic phosphate was depicted numerically with Fick's diffusion law, which showed a fair agreement to most of the experimental data.

• Journal of the Korean Institute of Rural Architecture
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• v.23 no.1
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• pp.1-8
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• 2021

In this study, a real-sized experimental equipment (pilot plant) was built at the site based on the preliminary research data to develop a movable separator for the mixed construction waste that can be implemented in agricultural areas to review its feasibility through the evaluation of its separation efficiency by waste types. The final construction of the movable separator and experimental results of the separation efficiency are summarized as follows. 1) The separation performance according to the blade type was the best for the combustible wastes either with 26 numbers of L-type blades and 32 numbers of pin type blades. As far as combination of blade types, when the L-type and pin-type were combined, the best separation efficiency was achieved. 2) The separation efficiency for waste wood by the conveyor type and angle of inclination (slope) of the trommel was the best when the conveyor had ribs of seagull shape with the angle of inclination 45°. 3) The separation efficiencies by process showed that 65.9% was separated as inorganic demolition wastes, 18.2% as waste woods, and 16.0% as combustible wastes at conveyor speed of 2-3 rpm, and the error rate was the least from the waste types generated in the dismantle site.