• 제목/요약/키워드: Inorganic matters

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X-선 형광분광법을 이용한 대기부유분진중 중금속의 농도분포에 관한 연구 (Studies on the Distribution of Heavy Metal Concentrations in Ambient Suspended Particulate Matters Using the X-ray Fluorescence Spectroscopy)

  • 이태정;김동술
    • 한국대기환경학회지
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    • 제8권1호
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    • pp.20-28
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    • 1992
  • The x-ray fluorescence(XRF) is one of the most convenient and widely used techniques for analyzing trace elements in ambient particulate matters. The objects of the study were to estimate the optimum exposure time using the XRF, to investigate the distributions of heavy metal levels in particulate matters, and finally to study seasonal variation for the concentrations of total suspended particulate matters(TSP) and size fractionated particulate matters. The suspended particulate matters had been collected by a cascade impactor having 9 size fragnated stages for 3 years(Dec. 1988 to Nov. 1991) in Kyung Hee University-Suwon Campus. The particulate matters were then collected on each stage by membrane filters. The weight concentrations were determined by the XRF system. Thus, seasonal variations and relationship between concentration and particle size could be investigated. Resulting distribution was bimodal with the coarse and the fine particle groups minimum occurring around 2.1 to 3.3 $\mu$m as an aerodynamic diameter. To determine optimum exposure time of the XRF for various trace inorganic elements, membrane filters and the NIST standard filters were extensively studied. Using a statistical technique, optimum exposure time was estimated for each trace element and overall elements. The time was then determined as 20 seconds for the XRF system. The concentration of TSP was 123.9$\mum/m^3$ on an arithmatic average. The levels of each inorganic metal were Si 2420.0ng/$m^3$, Fe 977.1ng/$m^3$, and so on. The Pb. Zn, and Cu abounded in the fine mode group, while Ca, Fe, Si, Al, and K in the coarse group. Marked seasonal variation of TSP and metal concentrations was observed. The concentration of heavy metals in the fine mode was highest in winter : on the other hand, that in the coarse mode was highest in spring.

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매연저감장치 손상에 기인한 차량화재 사고사례 분석 (Analysis on Vehicle Fires Caused by Damage of Diesel Particulate Filter (DPF))

  • 송재용;사승훈;남정우;조영진;김진표;박남규
    • 한국화재소방학회논문지
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    • 제26권4호
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    • pp.70-76
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    • 2012
  • 본 논문에서는 디젤 승용차량에서 매연저감장치 손상에 기인한 차량화재에 대하여 기술하였다. 디젤 차량에서는 배출가스에 포함되는 입자상 물질을 저감하기 위하여 매연저감장치를 배기계통에 설치하고 있다. 매연저감장치는 입자상 물질의 과다 포집, 재상과정에서의 오류 및 흡기계통 불량 등에 의해 재생과정에서 파손에 이르게 되며, 매연저감장치가 파손되는 경우, 고온의 배출가스가 분출되고, 차량 하부 배기계통의 주변 가연물을 통해 화재로 진전된다. 매연저감장치 손상에 의해 화재가 발생되는 경우, 배기계통 배관 및 머플러 부분에 규산염계 무기화합물이 부착되는 특징을 나타내며, 이 규산염계 무기화합물은 매연저감장치 내부 필터 재료인 세라믹 부분이 손상되는 과정에서 발생된다. 따라서 화재가 발생된 디젤 차량의 경우, 머플러 주변에서 규산염계 무기화합물이 식별되는 경우, 매연저감장치 손상에 기인한 화재로 추정할 수 있다.

고온수열된 무기질단열재의 물성변화에 관한 실험적 연구 (An Experimental Study on the Property Transformation for High-Heated Inorganic Insulation)

  • 김봉주;김태용;오창희
    • 한국화재소방학회논문지
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    • 제5권1호
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    • pp.29-36
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    • 1991
  • The purpose of this study is to understand the variations of the properties of matters according to the heated temperature of inorganic insulation. As a result, form the variation of heat conductivity and maintaining from of insulation, the range of reusable heated temperature of inorganic insulation is as follows. Glass wool : $400^{\circ}C$, Rock wool : $600^{\circ}C$, Perlite : $800^{\circ}C$.

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RO막을 이용한 매립지 침출수 처리 및 붕소 제거 (Landfill Leachate Treatment and Boron Removal by Reverse Osmosis)

  • 정수정;나숙현;배상옥;임병진
    • 한국물환경학회지
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    • 제28권5호
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    • pp.657-662
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    • 2012
  • This study was carried out to evaluate the removal rate of organic and inorganic matters from landfill leachate using pre-treatment process as coagulation and limonite adsorption, and membrane process as RO (reverse osmosis) and NF(nanofiltration). By adding limonite adsorption as pre-treatment process, about 40% of organic matters in leachate was removed through pre-treatment process and 74.7% of boron was removed after RO process without pH adjustment. The rejection rate of boron in RO process mainly depends on the pH and increased at pH value of 10. RO process was performed as two stage system adjusting pH condtion to 7 and 10 in second RO stage for boron removal. Most (>90%) of TOC, Cl- and inorganic matters as Ca was rejected in first RO stage, the residue was rejected in second RO and the rejection rate was above 97%. Considering economic efficiency of operation cost, NF substituted for the first RO and total removal rate of TOC was above 90%. Through RO system toxicity to Daphnia in leachate was removed completely.

수생태계에 미치는 석산개발의 영향 - 생물군집과 입지유형을 중심으로 (Environmental Impacts of Stone Quarry Exploitation - Aquatic Macroinvertebrate Community and Quarry Locality)

  • 이성진;김명철;김지영;노태호
    • 한국물환경학회지
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    • 제21권4호
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    • pp.368-378
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    • 2005
  • Inorganic matters originated from stone quarries and manufacturing plants could alter the ecological characteristics of adjacent aquatic systems, especially the structure and function of benthic macroinvertebrate community. In such situation, the locality of stone quarry and the quantity of inorganic matters would be important factors that determined the disturbing strength to the benthic macroinvertebrate community. Locality patterns of stone quarries were classified into 3 types in relation to the stream ecosystem; stream-proximity, upstream-inclusion and tributary-inclusion type. In the result of species:abundance analysis, stone quarry B (upstream-inclusion type) showed geometric distribution, while others showed broken-stick distribution pattern. The benthic macroinvertebrate communities closer to stone quarries showed smaller species numbers and standing crops among all types of stone quarries. However the values of species evenness index were not seriously different between controls and directly affected sites. These results indicated that the effect of inorganic disturbance would differ from those of organic pollution that induced the highly dominant state occupied by tolerant species. Number of occurred species, standing crops, community indices and biotic indices indicated that the community of upstream-inclusion type was the most seriously damaged from the inorganic disturbance, and the community would be very simple and unstable. Tributary-inclusion stone quarry heavily damaged to tributary system in biologically, but influence to the main stream seemed to be depended on the scale of main stream. Among 3 types of stone quarry localities, stream-proximity type induced the least damages to benthic macroinvertebrate community, though the degrees of damage were different along with distances between stream and stone quarry.

하계 완도 주변 육상 양식장 배출수 중 유기탄소 및 영양염의 분포 특성 (Distribution Characteristics of Organic Carbon and Nutrient in Effluent of Land-based Aquaculture Farms around Wando in Korea)

  • 김규리;최유정;김태훈
    • Ocean and Polar Research
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    • 제45권3호
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    • pp.103-111
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    • 2023
  • To evaluate the impact of effluents from land-based fish farms on the coastal ocean of Wando, Korea, we analyzed inorganic nutrients, particulate organic carbon (POC), dissolved organic carbon (DOC), and colored dissolved organic matter (CDOM) in the effluent and influent of land-based fish farms during the summer (July) of 2021. The average concentrations of nutrients (Dissolved inorganic nitrogen, phosphorus, and silicate; DIN, DIP, and DSi, respectively) in the effluents of this study area were 17±3.7 μM, 1.4±0.7 μM, and 14±1.6 μM, respectively. The average concentrations of POC and DOC were 37±22 μM and 81±13 μM, respectively, with POC accounting for about 30% for total organic carbon in effluents. The Reduced Dissolved Inorganic Nitrogen/Total Dissolved Inorganic Nitrogen ratio (0.7), potential short-period index, indicates that the discharge of nutrients excreted by the fish and unconsumed feed into coastal water results in such nutrients being deposited and accumulated in the sediment. Subsequently, this continuous accumulation triggers the release of ammonium ions during organic matter decomposition, and the ammonium-enriched waters that encroach on fish farms as influent seem to be due to the diffusion of high concentrations of ammonium from bottom sediment. Furthermore, we used fluorescence indices to examine the characteristics of organic matter sources, obtaining mean values of 1.54±0.19, 1.06±0.06, and 1.56±0.06 for the humification index, biological index, and fluorescence index, respectively, in the effluent. These results indicate that the organic matters had an autochthonous origin that resulted from microbial decomposition, and such organic matters were rapidly generated and removed by biological activity, likely supplied from the sediment. Our results suggest that the effluent from land-based fish farms could be a potential source of deoxygenation occurrence in coastal areas.

잣나무엽(葉)의 초기(初期) 분해과정(分解過程)에 있어서 무기태(無機態) 질소(窒素) 및 CO2 방출속도(放出速度)의 변화(變化) (Changes of Inorganic Nitrogen and CO2 Evolution Rate on the Decomposition Process of Korean White Pine Needles)

  • 이명종;한상섭;김정제
    • 한국산림과학회지
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    • 제69권1호
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    • pp.13-18
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    • 1985
  • 잣나무의 녹엽(綠葉), 낙엽(落葉), F층(層)의 엽(葉)과 떡갈 및 굴참나무의 녹엽(綠葉)을 각각 토양(土壤)에 혼합(混合)하여 53일간 $30^{\circ}C({\pm}1)$로 항온배양(恒温培養)하는 동안 토양중(土壤中)의 무기태(無機態) 질소(窒素) 및 $CO_2$ 방출속도(放出速度)의 변화(變化)를 측정(測定)하여 다음의 결과(結果)를 얻었다. 1) 배양초기(培養初期)에는 무기태(無機態) 질소(窒素)의 유기화(有機化)로 무기태(無機態) 질소량(窒素量)의 감소(減少)가 강(強)하게 일어났고, 시간(時間)의 경과(經過)에 따라 점차 증가(增加) 하였다. 2) 혼합(混合)한 엽중(葉中)의 유기태(有機態) 질소(窒素)의 유기화속도(有機化速度)는 잣나무의 엽중(葉中) 녹엽(綠葉)에서 가장 컸으나, 굴참 및 떡갈나무의 녹엽(綠葉)보다는 작았다. 3) $CO_2$ 방출속도(放出速度)의 크기는 굴참나무녹엽(綠葉), 떡갈나무녹엽(綠葉), 잣나무녹엽(綠葉), 잣나무 낙엽(落葉), F층(層)의 잣나무엽(葉)을 혼합(混合)한 토양(土壤)의 순(順)이었고, 시간의 경과(經過)에 따라 점차 감소했다. 4) 질산태(窒酸態) 질소량(窒素量)은 점차 증가(增加)하여 배양(培養) 53일 후에, 암모니아태(態應) 질소량(窒素量)을 상회(上迴)하였다.

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수원지역 대기 중 $PM_{2.5}$$PM_{10}$의 환경거동에 관한 연구 (Studies on the Environmental Behaviors of Ambient $PM_{2.5}$ and $PM_{10}$ in Suwon Area)

  • 김동술
    • 한국대기환경학회지
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    • 제16권2호
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    • pp.89-102
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    • 2000
  • A total of 318 particulate sample sets consisting of both fine PM(FPM : dp$\leq$2.5 ${\mu}{\textrm}{m}$) and coarse PM(CPM : 2.5${\mu}{\textrm}{m}$${\mu}{\textrm}{m}$) was collected by a dichotomous sampler in Suwon area from December 1996 to November 1997. The concentration of seven inorganic elements such as pb. Cr, Cd, Cu, Zn Fe and Na were determined from each sample using an AAS. The purpose of the study was to extensively investigate environmental behaviors of particulate matters and to provide air quality management schemes applying various statistical approaches. The mean concentrations of PM10 Results of correlation analyses indicated the existence of strong correlations among inorganic elements PM10 FPM CPM and various meterological variables. Our study also examined the degree of uncertainties whether the particular elements can be assorted into the accumulation mode or the coarse mode in their size distribution. Furthermore the analysis of the pollution rose showed graphically the direction of potential sources of particulate matters. According to statistical analyses of our data quantitative differences appeared in the pollution patterns between weekdays and weekends.

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민자주방망이버섯 (Lepista nuda) 서식지의 토양인자 분석 (Soil Properties of the Habitat of Lepista nuda)

  • 이양숙;주은영;김종봉;김남우
    • The Korean Journal of Ecology
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    • 제28권1호
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    • pp.25-29
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    • 2005
  • 민자주방망이버섯(Lepista nuda)의 생태적 특성에 대한 연구의 일환으로 민자주방망이버섯 서식지의 수분, 유기물, 전질소, 토양 산성도, 무기물 함량 등의 토양인자에 대하여 분석하였다. 수분 및 유기물 함량은 평균 29.65%, 32.14%로 나타났으며, 전질소 함량은 평균 0.74%, pH는 평균 4.57의 산성 토양으로 조사되었다. 무기물의 함량은 Fe가 평균 1,024 ppm으로 가장 높았고, K : 183 ppm, Mn : 21.88 ppm, Ca : 2.02 ppm, Zn : 1.46 ppm 그리고 Mg : 0.51 ppm의 순으로 나타났다.

칠러(Chiller) 냉각장치 침전물에 미치는 마그네슘의 영향에 관한 환경 광물학적 연구 (Environmental Mineralogy on the Mg Effects of Chiller Precipitates)

  • 김윤영;장세정;장윤득;김정진
    • 한국광물학회지
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    • 제18권2호
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    • pp.117-125
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    • 2005
  • 산업체에서 사용하고 있는 칠러 냉각 장치에는 침전물이나 부유물이 많이 발생한다. 칠러 냉각장치에 마그네슘을 적용시켰을 때 나타나는 냉각수와 침전물 및 부유물의 변화를 연구하기 위하여 ICP-AES, IC, XRD, SEM 분석을 실시하였다. 칠러 냉각장치에 Mg를 적용할 경우 대부분의 용해 성분이 감소하는 경향을 보여주고 있어 냉각수의 수질이 상당히 개선되었다. 또한 유기물 형태로 존재하던 부유물이나 침전물이 거의 생성되지 않아 유기물 생성을 억제시키는 효과도 있는 것으로 판단된다.