• Title/Summary/Keyword: Inorganic materials

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Removal of Volatile Organic Compounds with Organic-Inorganic Hybrid Mesoporous Materials (유·무기 혼성 메조포러스 물질의 휘발성 유기화합물 제거능)

  • Jeong, Han Mo;La, Young Soo;An, Jin Hee;Jo, Ah Young;Choi, Mi Yeon;Kim, Suck Man;Moon, Nam Gu;Yoon, Young Ho
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.719-723
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    • 2005
  • Organic-inorganic hybrid mesoporous materials were prepared by co-condensation of organosilanes with tetraethyl orthosilicate (TEOS) or 1,2-bis(triethoxysilyl) ethane (BTSE). Their removal capability of volatile organic compounds (VOCs) in the air was evaluated and compared with that of inorganic hydrophilic mesoporous material, SBA-15 that was prepared with TEOS only. It was found that the increased hydrophobicity of mesoporous materials due to the presence of organic group, could enhance the VOCs removal by adsorption in the air. An organic-inorganic hybrid material prepared by the co-condensation of BTSE/phenyl triethoxysilane (90/10 by weight) was a typical example of superior adsorbent. It was also observed that these organic-inorganic hybrid materials can be utilized as absorbents for the removal of oil dispersed in water.

Gate dielectric based on organic-inorganic hybrid polymer in organic thin-film transistors

  • Lee, Seong-Hui;Jeong, Sun-Ho;Moon, Joo-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.727-729
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    • 2007
  • Inorganic-organic hybrid polymer provides various advantages including low-temperature process, high dielectric constant and direct photo-patterning. The hybrid dielectric was synthesized by the sol-gel process in which an acid-catalyzed solution of Si alkoxide and Zr alkoxide was used as a precursor. The electrical performance of transistors with hybrid dielectric was investigated.

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Liquid crystal effects on poling behaviour of NLO chromophore dispersed in organically modified sol-gel materials (유/무기 졸-겔 재료에 비선형광학 물질의 배향특성에 대한 액정효과)

  • Baek, In-Chan;Seok, Sang-Il;Jin, Moon-Young;Lee, Chang-Jin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.132-132
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    • 2003
  • Second-order nonlinear optical(NLO) materials have been extensively studied for applications in photonic devices, such as frequency doubling and electro-optical(EO) modulation, because of their large optical nonlinearity, excellent processibility, low dielectric constant, and high laser damage thresholds. The poling behaviour of NLO chromophore in organic/inorganic matrixes showed the randomization of poled NLO chromophore in the absence of poling Held. The liquid crystal molecules in a droplet showed a long-range orientational order along a director. Therefore, liquid crystal effects on poling behaviour of NLO chromophore dispersed in organically modified inorganic sol-gel materials were investigated. Using sol-gel process for the development of NLO material has received increasing attention, Organically modifked inorganic NLO sol-Eel materials are obtained via incorporation of the organic NLO active chromophore into an alkoxysilane based inorganic network. One of the most important thing in this works was that tetraethoxysilane(TEOS) and methyltrimathoxysilane(HTMS) were used as precursor followed by hydrolysis and condensation without using any acidic catalyst during the process. The NLO chromophores in the liquid crystal nanodomains were well mixed with I/O hybrid matrix, deposited on transparent ITO-coated glasses. The poling behaviour of liquid crystal effects of NLO chromophore dispersed in I/O hybrid matrix were investigated by UV-vis spectroscopy. Size distribution and morphology of the NLO chromophores doped in the liquid crystal nanodomains dispersed in I/O hybrid matrix were investigated by SEM.

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An Experimental Study on the Chloride Diffusion Properties in Concrete according to the Water-Cement Ratio and Coating Materials (물시멘트비 및 도장재 종류에 따른 콘크리트의 염소이온 확산특성에 관한 실험적 연구)

  • 이태희;김용로;김재환;강석표;권영진;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.679-684
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    • 2002
  • In this study we performed test to compare and analyze the chloride diffusion properties in concrete according to organic coating materials used at concrete structures widely and inorganic coating materials as eco-materials in recently. The results of study were shown as follow ; 1) Chloride diffusion coefficient was low as low as and that of organic and inorganic painted was lower than non-painting 2) In case of inorganic coating material applied in this study, it should be possible to evaluate the chloride diffusion properties by CTH method. Because presumption value by CTH method is similar with real estimate value by digestion experiment.

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