• Title/Summary/Keyword: Inorganic film

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A Study on the Anti-corrosion Properties of Organic and Inorganic Inhibitor by Electrochemical Evaluation Method in Saturated Aqueous Solution of Calcium Hydroxide (포화 수산화칼슘 수용액 내에서의 무기계 및 유기계 방청제의 전기화학적 방식 특성평가)

  • Kim, Soo-Young;Ryu, Hwa-Sung;Kim, Sung-Kil;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.4
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    • pp.66-74
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    • 2013
  • In this study, corrosion potential ($E_{corr}$), corrosion rate, and polarization resistance were measured aimed at inorganic inhibitors (passive film type) and organic inhibitors (absorption type). The experiment was conducted using potentiostat for the variable molar ratio and chloride ion concentration of the components of inhibitors in an aqueous solution of saturated calcium hydroxide targeting corrosion. As a result, it was possible to ensure an anticorrosive performance of at least a 1.2 molar ratio of inorganic inhibitors. Also, the organic inhibitors ensured the prevention of the anticorrosive performance of at least about a 0.3 molar ratio. It also showed the tendency that between polarization resistance and corrosion rate, Ecorr and corrosion rate is inversely proportional to the linear. Conversely, the tendency between polarization resistance and Ecorr is proportional to the linear. Also, a distinct difference in organic and inorganic inhibitors' relationship to Ecorr, corrosion rate, and polarization resistance was not shown.

A Study on Manufacturing and Characteristics of solid Lubricant Oilless Bearin (고체윤활 베어링의 제조방법 및 특성연구)

  • Kim, Chang-Uk;Ryu, Su-Hyeon
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.991-996
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    • 2001
  • This study is the manufacture of solid lubricant oilless bearing using sintered parts. PTFE was as organic solid lubricant and $MoS_2$ as inorganic solid lubricant, and its characteristics were studied. Thickness of lubricant was suited 25~$100\mu\textrm{m}$ for lubricant characteristics. Curring temperature of MoS_2$ film was 12$0^{\circ}C$, 2 hours and that of PTFE film was $260^{\circ}C$, 20 minutes. The solid weight and solid volume of $MoS_2$ film was 51.7% and 27.4%, and that of PTFE was 44.9% and 24.3%. Chemical resistant of PTFE solid lubricant oilless bearing was excellent as salt test was 520hours, and usable temperature range was $-200~+280 ^{\circ}C$. Conduction of electricity can be increase by addition of graphite or $$\alpha$- PbO_2$. The electric conductivity was 100~180$\Omega$.

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Effect of Surface Finishing Materials on the Moisture Conditions in Concrete: Vapor and Water Permeability of Finishing Materials Under Changing Environmental Conditions

  • Ryu, Dong-Woo
    • International Journal of Concrete Structures and Materials
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    • v.2 no.2
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    • pp.83-90
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    • 2008
  • Permeability to vapor and water among other performances required for finishing materials is dealt with in this study. The relative moisture content of concrete coated/covered with a finishing material was experimentally investigated while changing the environmental conditions including temperature, relative humidity, and rainfall. An organic paint (water-based urethane), organic synthetic resin emulsion-type film coating (film coating E), and inorganic porcelain tiles were selected as the finishing materials. When compared from the aspect of vapor and water permeability, the vapor permeability and water permeability of water-based urethane were high and low, respectively; those of film coating E were high and high, respectively; and those of porcelain tiles were low and low, respectively. This means that the moisture state of concrete structures is governed not only by the environmental conditions but also by the performance of finishing materials. It is therefore of paramount importance to appropriately select a finishing material to address the specific deteriorative factors involved in the concrete structure to be finished.

Characteristics of insulators for inorganic electroluminescent display with high stability (안정성이 확보된 무기 전계발광 표시소자용 절연막의 특성)

  • Lim, Jung-Wook;Yun, Sun-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.111-114
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    • 2003
  • Compared to a conventional atomic layer deposition (ALD) grown Al203 film, Plasma enhanced ALD (PEALD) grown AION film was revealed to possess a large breakdown field, which is necessary for stable operation of thin film electroluminescent (TFEL) device. Also, AION is more stable than Al203 films grown by PEALD or by ALD after post-annealing process, which is inevitably required to improve luminance property of phosphor. Furthermore, AION films were applied to insulators of ZnS:Tb TFEL device. Resultant1y, they show better stability than ALD grown insulators under high electric field.

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Fabrication of polymer thick film resistor and study on resistance variation regarding curing temperature (폴리머 후막 저항체의 제작 및 경화 온도에 따른 저항 값 변화에 대한 연구)

  • Yoo, Myong-Jae;Lee, Sang-Myong;Park, Seong-Dae;Kang, Nam-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.212-213
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    • 2006
  • Polymer thick film resistor paste was fabricated using various materials. Inorganic materials of carbon black and graphite were selected as fillers and epoxy resin was selected as organic material. Solvent with high boiling temperature was applied to adjust viscosity. A designed test coupon pattern was used to evaluate fabricated resistors. Aspect ratio of 1 was selected for evaluating resistor values. Electrical properties of fabricated resistors were measured and their values analyzed in relation to paste composition. PTF fabricated using carbon black as fillers achieved resistor value of $530{\Omega}/sq$.

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Electro-Optical Performances of In plane Switching(IPS) Cell on the Inorganic Thin Film by DuoPIGatron Ion Source (NDLC박막에 DuoPIGatron 이온소스를 사용한 IPS cell의 전기광학특성)

  • Kim, Sang-Hoon;Kim, Jong-Hwan;Kang, Dong-Hoon;Kim, Young-Hwan;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.453-454
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    • 2006
  • We studied the nematic liquid crystal (NLC) alignment capability by the IB(Ion bean) alignment method on a NDLC(Nitrogen Diamond Like Carbon) as a-C:H thin film. and investigated electro-optical performances of the IBaligned IPS(In plane switching)cell with NDLC surface. A good LC alignment by IB exposure on a NDLC surface was achieved. Monodomain alignment of the IB aligned IPS cell can be observed. The goodelectro-optical (EO) characteristics of the IB aligned IPS cell was observed with oblique IBexposure on the NDLC as a-C:H thin film for 1 min.

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An Experimental Study on the Anti-corrosion and Anti-wear Characteristics of MoS$_2$ Bonded Films for Automotive Wheel Joints (방청 및 내마모 특성이 향상된 자동차 휠 조인트용 $MoS_2$계 고체 피막 윤활제)

  • 한흥구;공호성;윤의성;권오관
    • Tribology and Lubricants
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    • v.16 no.3
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    • pp.173-181
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    • 2000
  • Friction, wear and corrosion characteristics of various MoS$_2$ bonded film lubricants were investigated to apply them to automotive wheel joints. MoS$_2$ bonded film lubricants were formulated by combinations of several additives and binders, and they were coated onto the pre-treated surfaces of specimens. Friction and wear characteristics were evaluated with Falex pin & vee-block test and LFW-1 block-on-ring test. For the corrosion resistant characteristics of the films, salt solution spray corrosion tests were performed. Results showed that MoS$_2$ bonded films containing both inorganic and organic corrosion-resistant additives yielded a synergy effect on anti-corrosion resistance. Also, binders having the better water-proof and thermal stability showed the lower friction and higher corrosion resistance.

Preparation and Characterization of Sol-Gel Derived $SiO_2-TiO_2$ -PDMS Composite Films

  • Hwang, Jin Myeong;Yeo, Chang Seon;Kim, Yu Hang
    • Bulletin of the Korean Chemical Society
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    • v.22 no.12
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    • pp.1366-1370
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    • 2001
  • Thin films of the SiO2-TiO2-PDMS composite material have been prepared by the sol-gel dip coating method. Acid catalyzed solutions of tetraethoxy silane (TEOS) and polydimethyl siloxane (PDMS) mixed with titanium isopropoxide Ti(OiPr) were used as precursors. The optical and structural properties of the organically modified 70SiO2-30TiO2 composite films have been investigated with Fourier Transform Infrared Spectroscopy (FT-IR), UV-Visible Spectroscopy (UV-Vis), Differential Thermal Analysis (DTA) and prism coupling technique. The films coated on the soda-lime-silicate glass exhibit 450-750 nm thickness, 1.56-1.68 refractive index and 88-94% transmittance depending on the experimental parameters such as amount of PDMS, thermal treatment and heating rate. The optical loss of prepared composite film was measured to be about 0.34 dB/cm.

Studies on the Anodic Oxidation Behavior of Methanol and L-Ascorbic Acid by Using Glassy Carbon Electrodes Modified with Inorganic-Metal Polymeric Films (무기 금속 고분자 막을 도포시킨 유리질 탄소전극을 이용한 메탄올과 L-ascorbic acid의 양극 산화 거동에 관한 연구)

  • Yoo, Kwang-Sik;Woo, Sang-Beom
    • Analytical Science and Technology
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    • v.11 no.5
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    • pp.347-352
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    • 1998
  • A study was carried out on the elelctrochemical characteristics of chemically modified electrodes (CMEs) by cyclic voltammetry. Fabrication of CMEs was made by coating with mixed valence (mv) inorganic-metal polymeric films on the glassy carbon electrode surface by potential cycling. Anodic oxidation behavior of methanol and L-ascorbic acid was studied by using CMEs working electrode. Deposition of films such as mv ruthenium oxo/ruthenium cyanide film (mv Ru-O/CN-Ru), mv ruthenium oxo/ferrocyanide film (mv Ru-O/$Fe(CN)_6$), and mv ruthenium oxo/ruthenium cyanide/Rhodium film (mv Ru-O/CN-Ru/Rh) was obtained to coat by scan rate of 50 mV/sec within the specified potential range (-0.5V ~ +1.2V). Film thickness was controlled by the repeat of the potential cycling. Anodic oxidation behavior of methanol was as follow. Calibration graph by using mv Ru-O/CN-Ru film showed linearly from 10 mM to 80 mM MeOH with slope factor of $-7.552{\mu}A/cm^2$. Although slope factor by using mv Ru-O/$Fe(CN)_6$ film was $-5.13{\mu}A/cm^2$, yet linear range of calibration graph could be extended from 10 mM to 100 mM MeOH. Anodic oxidation behavior of L-ascorbic acid was studied by mv Ru-O/CN-Ru film on the glassy carbon electrode and the glassy carbon electrode with Rh film, Glassy carbon electrode modified with Ru polymeric film was showed better sensitivity than the Rh-glassy carbon modified electrode (mv Ru-O/CN-Ru/Rh). Calibration graph was linear from 0.1 mM to 5 mM L-ascorbic acid by using glassy carbon electrode modified with Ru polymeric film. Solpe factor and relative coefficient are $-84.78{\mu}A/mM$ and 0.998, respectively.

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Electro-Optical Characteristics of the Ion-Beam-Aligned FFS-LCD on a Diamond-like-Carbon Thin Film

  • Hwang, J.Y.;Park, C.J.;Seo, D.S.;Jeong, Y.H.;Kim, K.C.;Ahn, H.J.;Baik, H.K.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1132-1136
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    • 2004
  • In this paper, we intend to make FFS mode cell with LC alignment used non-rubbing method, ion beam alignment method on the a-C:H thin film, to analyze electro-optical characteristics in this cell. We studied on the suitable inorganic thin film for FFS-LCD and the aligning capabilities of nematic liquid crystal (NLC) using the new alignment material of a-C:H thin film as working gas at rf bias condition. A high pretilt angle of about 5$^{\circ}$ by ion beam(IB) exposure on the a-C:H thin film surface was measured. An excellent voltage-transmittance (V-T) and response time curve of the ion-beam-aligned FFS-LCD was observed with oblique ion beam exposure on the DLC thin films.

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