• Title/Summary/Keyword: Inorganic crystal

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$TiO_2$ Doped Sapphire Single Crystal Growth by Verneuil Method and Study for Defects (Verneuil법에 의한 $TiO_2$를 첨가한 Sapphire 단결정 성장과 결함에 관한 연구)

  • Cho, H.;Choi, J.K.;Chun, B.S.;Orr, K.H.;Park, H.S.
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1423-1428
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    • 1994
  • TiO2 doped sapphire single crystals were grown by Verneuil method. The doping amount of TiO2 to Al2O3 were varied 0.1, 0.2, 0.3 wt% respectively. The grown crystals have reddish color and somewhat transparent. Optimum growth condition was established by changing growth rate and gas flow ratio. Growth condition are as follows; The flow rate range of oxygen ws 5.0~7.3 ι/min and that of hydrogen was 16~25ι/min and average growth rate was 6~8mm/hr. The basic cause of color appearence and defects in crystal were studied.

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Astudy of internal defects and their effects in $CaF_2$ single crystals (형석단결정의 내부결함 및 그 영향에 관한 연구)

  • Seo, Soo-Hyung;Joo, Kyoung;Auh, Keun-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.3
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    • pp.419-423
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    • 1998
  • The internal defects in $(CaF_2)$ single crystal were characterized by the observation of optical microscopy, the element analysis and the transmittance analysis. In bubble and negative crystal which are composed to crystal plane of (100) and (111), the spread negative crystal in $(CaF_2)$ crystal gave an effect of low transmittance. The precipitates formed in bubble as internal cavities were analyzed by using WDX. Violet colored-crystal had higher a dislocation density than non-colored crystal, and the atomic ratio between Ca and F changed by poor F ion. In this result, we could determine indirectly that violet color was occurred by poor F ion.

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Synthesis and crystallization of solder glass for electronic package (전자 Package 봉착유리의 합성과 결정화)

  • Kyung Nam Choi;Byoung Chan Kim;Byoung Woo Kim;Hyung Suk Kim;Hee Chan Park;Myung Mo Son;Heon Soo Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.6
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    • pp.407-411
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    • 2000
  • Low-temperature solder glass for use in electronic package was experimentally prepared and its crystallization behavior was investigated using differential thermal analysis (DTA) under nonisothermal condition. The composition of the solder glass was determined from PbO-ZnO-$B_2$$O_3$-$TiO_2$ glasses containing small amounts of CaO, $SiO_2$$A1_2$$O_3$ and $P_2$$O_5$. The crystallization exotherm corresponding to the formation of lead titanate (PbTiO$_3$) was observed. The crystallization of $PbTiO_3$was a three-dimensional process with the average activation energy of 223$\pm$3 kJ/mol for the crystallization from the glass matrix.

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1D-Coordination Polymer Formed by Structural Conversion of an Oxazolidine Ligand in Reaction with the Copper(II) Halides

  • Mardani, Zahra;Golsanamlou, Vali;Jabbarzadeh, Zahra;Moeini, Keyvan;Carpenter-Warren, Cameron;Slawin, Alexandra M.Z.;Woollins, J. Derek
    • Journal of the Korean Chemical Society
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    • v.62 no.5
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    • pp.372-376
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    • 2018
  • A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$ $\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

Synthesis of CuO from organic-inorganic hybrid (유기-무기 복합소재로부터 CuO합성)

  • Huh Young-Duk;Kweon Seok-Soon;Kuk Won-Kwen
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.5
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    • pp.193-197
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    • 2005
  • CuO has been synthesized using the layered organic-inorganic hybrids, $Cu_2(OH)_3(CH_3COO){\cdot}H_2O$ as precursor. The simple thermal decomposition of $Cu_2(OH)_3(CH_3COO){\cdot}H_2O$ is used without any external organic templates. This method provides large-scale production at a low cost of the single-crystalline CuO particles. The morphology of CuO aggregated particles is strongly dependent on structure of the precursor.

Titanium oxide nanoparticle hybridized liquid crystal display in vertical alignment

  • Lee, Won-Gyu;O, Byeong-Yun;Im, Ji-Hun;Park, Hong-Gyu;Kim, Byeong-Yong;Na, Hyeon-Jae;Seo, Dae-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.160-160
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    • 2009
  • In recent years, the merging of nanomaterials and nano-technology into electro-optic (EO) device technology such as liquid crystal displays (LCDs) has attracted much attention because of their unique electro- and magneto-optic properties and novel display applications. One example of hybrid LC-inorganic systems is semiconductor nanorods added to LC for their strong reorientation effect and tunable refractive index. Doping of nanoparticles in LC or polymers can lead to changes in performance characteristics such as electro-optical, dielectric, memory effect, phase behavior, etc. Due to the tunability of LCDs with mixed inorganic materials, low voltage operation of a LC system can also be achieved using the significant electro-optical effect achieved through suspension of ferroelectric nanoparticles in NLC.

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Effect of heat-treatment on the structural and electrical properties of ZnO thin films by the sol-gel method

  • Lee, Seung-Yup;Park, Byung-Ok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.2
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    • pp.72-75
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    • 2008
  • Zinc oxide (ZnO) thin films were prepared by a sol-gel method. The structural and electrical properties were investigated by varying drying and annealing temperatures. The thin films were coated (250 nm) by spin-coating method on glass substrates. The optimum drying temperature of ZnO thin films was 300$^{\circ}C$ where the resistivity was the lowest and the preferred c-axis orientation was the highest. The annealing was carried out in air and inert atmospheric conditions. The degree of the preferred c-axis orientation was estimated. The highest preferred c-axis orientation was recorded at 600$^{\circ}C$. The preferred c-axis orientation and grain growth resulted in the mobility enhancement of the ZnO thin films, and the lowest resistivity was 0.62${\Omega}{\cdot}cm$ at 600$^{\circ}C$.

Studies on Inorganic Chinese Drugs in Korea (V) Study on Yung-Sa (Vermillion) (광물성한약에 관한 연구 (V) 영사에 관한 연구)

  • 이은옥
    • YAKHAK HOEJI
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    • v.13 no.2_3
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    • pp.93-96
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    • 1969
  • X-ray diffraction analysis of Yung-Sa, an inorganic chinese drug in Korea, revealed the following: 1. "Yung-Sa" is red mercuric sulfide crystal (Vormillion) which is cinnabar type of hexagonal system. 2. It is accurate to call "Yung-Sa" synthetic red mercuric sulfide. 3. "Chung-Sa-Du" is mixture of crystals of cinnabar and meta-cinnabar types.

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