• 한국주조공학회지
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• 제33권4호
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• pp.147-156
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• 2013

The effects of core materials on the microstructure and mechanical properties of Al casting products have been investigated. The Al casting samples and cylinder head were fabricated by using organic and inorganic binder core respectively, and their microstructure and mechanical properties were evaluated. The Al casting samples fabricated by using inorganic core showed the better mechanical properties such as tensile strength and elongation than those of the Al casting samples fabricated by using organic core. That's because the Al casting samples contained small amount of pore defects and had fine microstructure compared with the Al casting samples fabricated by using organic core. Also, the use of inorganic core effectively reduced harmful gas emission and pollution.

• 한국결정성장학회지
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• 제6권4호
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• pp.521-531
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• 1996

분무건조법을 이용하여 무기질막 microcapsule과 무기질/유기질막 microcapsule을 제조하였다. 무기질막 microcapsule은 core 물질로 $K_{4}SO$와 clay shell 물질로 colloidal silica를 사용하였고, 무기질/유기질막 microcapsule은 core 물질로 상기 제조된 무기질막 microcapsule을 shell 물질로는 ethyl cellulose를 사용하여 각각의 microcapsule를 제조하였다. 제조된 microcapsule이 기능성을 갖기 위하여는 구형의 균일한 표면과 세공용적이 매우 중요하다. 무기질막 microcapsule인 경우 core/shell의 체적비가 0.3/0.7인 경우 구형의 균일한 표면의 microcapsule이 제조되었으며, 무기질/유기질막 microcapsule인 경우, 무게비가 0.76/0.24일 때 균일한 표면을 갖는 microcapsule이 제조되었다. 무기질/유기질막 microcapsule인 경우, 무기질막 microcapsule보다 세공용적이 감소하였고, shell물질(ethyl cellulose)의 양이 증가할수록 피복이 균일하게 되며, 세공용적도 감소하였다.

• 한국재료학회지
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• 제32권12호
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• pp.538-544
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• 2022

In existing ceramic mold manufacturing processes, inorganic binder systems (Si-Na, two-component system) are applied to ensure the effective firing strength of the ceramic mold and core. These inorganic binder systems makes it possible to manufacture a ceramic mold and core with high dimensional stability and effective strength. However, as in general sand casting processes, when molten metal is injected at room temperature, there is a limit to the production of thin or complex castings due to reduced fluidity caused by the rapid cooling of the molten metal. In addition, because sodium silicate generated through the vitrification reaction of the inorganic binder is converted into a liquid phase at a temperature of 1,000 ℃. or higher, it is somewhat difficult to manufacture parts through high-temperature casting. Therefore, in this study, a high-strength ceramic mold and core test piece with effective strength at high temperature was produced by applying a Si-Na-Ti three-component inorganic binder. The starting particles were coated with binary and ternary inorganic binders and mixed with an organic binder to prepare a molded body, and then heat-treated at 1,000/1,350/1,500 ℃ to prepare a fired body. In the sample where the two-component inorganic binder was applied, the glass was liquefied at a temperature of 1,000 ℃ or higher, and the strength decreased. However, the firing strength of the ceramic mold sample containing the three-component inorganic binder was improved, and it was confirmed that it was possible to manufacture a ceramic mold and core via high temperature casting.

• 한국구조물진단유지관리공학회 논문집
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• 제21권1호
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• pp.74-82
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• 2017

본 연구에서는 시멘트 복합체의 균열을 자기치유 할 수 있는 자기치유 캡슐을 제조하기 위한 일환의 기초 연구로써 자기치유 캡슐용 코어재료에 무기계 기반 코어재료를 적용하기 위하여 액상형태의 무기 소재를 기반으로한 코어재료를 제조하였다. 제조된 무기계 기반 코어재료는 캡슐화를 진행하기 전에 무기계 기반 코어재료를 직접 시멘트 복합체에 적용하여 균열부의 균열수복 성능뿐만 아니라 시멘트 복합체의 성능에 미치는 영향을 검토하였다. 평가결과, 무기계 기반 코어재료는 압축 및 부착강도 향상효과가 있는 것을 확인하였으며, 부착, 내흡수, 내투수 및 동결융해 저항 성능을 가진 것으로 판단된다. 본 논문의 결과를 통하여 자기치유 캡슐용 무기계 기반 코어재료를 적용할 경우에 얻을 수 있는 시멘트 복합체의 성능 및 차후 진보화된 자기치유 캡슐기술의 기반 자료로써 활용하고자 한다.

• 한국응용과학기술학회지
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• 제19권4호
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• pp.265-272
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• 2002

$CaCO_{3}$ absorbed sodium lauryl sulfate (SLS) surfactant was prepared, Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using styrene(St) as a shell monomer and potasium persulfate (KPS) as an initiator, We found that when $CaCO_{3}$; core prepared by adding 2,0 wt% SLS, $CaCO_{3}$ core/PSt shell polymerization was carried out on the surface of $CaCO_{3}$ particle without forming the new PSt particle during St shell polymerization in the inorganic/organic core-shell polymer preparation, The structure of core-shell polymer were investigated by measuring the degree of decomposition of $CaCO_{3}$ using HCl solution, thermal decomposition of polymer composite using thermogravimetric analyzer and morphology by scanning electron microscope.

• 한국안전학회지
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• 제19권1호
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• pp.81-87
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• 2004

Composite particles using inorganic and organic chemicals were synthesized and the results of those reaction were compared to variation of temperature and agitation speed in presence of $CaCO_3$ which was adsorbed SDBS. Also the synthesises were optimized according to conversion rate of composite particles. In inorganic/organic core-shell composite particle polymerization, $CaCO_3$ adsorbed by 0.5wt% surfactant SDBS was prepared initially and then core $CaCO_3$ was encapsulated by sequential emulsion polymerization using MMA at the addition of APS 3.16${\times}$$10^{-3}$mol/L to minimize the coagulated PMMA particle itself during MMA shell polymerization. Encapsulated PMMA on $CaCO_3$ as inorganic/organic core-shell particles was verified by FT-IR and DSC analysis. It was found that the $CaCO_3$ was very well encapsulated by PMMA as shell. The surfaces were distinctly found as spindle shape and broad particle distribution after capsulation.

• 방사선산업학회지
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• 제18권2호
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• pp.127-132
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• 2024

Large amounts of liquid radioactive waste or radioactive contaminated water could be produced during the treatment of radiation accidents or during the dismantling and decontamination process of nuclear power plants. Since most of the decontamination agents to date are difficult to recover after adsorption of radioactive isotopes, their use in open environments such as rivers, reservoirs, or oceans is limited. In this study, as a radioactive decontamination agent that can overcome the current limitations when used in an open environment, a paramagnetic core inorganic composite (PMCIC) decomposite agent with high selectivity to cesium ions was developed. PMCore was prepared by synthesizing paramagnetic iron oxide nanoparticles, and inorganic crystals such as metal-ferrocyanide were conjugated to the surface so that PMCore could be selective to cesium ions. The developed PMCIC could be easily recovered from the water by magnetism and could adsorb up to 94 μM of Cs atoms per 1 g of PMCIC.

• 한국응용과학기술학회지
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• 제26권2호
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• pp.199-204
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• 2009

Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S133D) surfactant was prepared. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 2.0 wt% EU-S133D, silicone dioxide/Acrylate core-shell polymerization was carried out on the surface of silicone dioxide particle without forming the new silicone dioxide particle during acrylate shell polymerization in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

• 한국응용과학기술학회지
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• 제27권1호
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• pp.56-60
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• 2010

Titanium dioxide particles are used as photocatalysts, sensors, adsorbents and catalyst. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 0.5~2.0 wt% EU-S133D, Titanium dioxide / Acrylate core-shell polymerization was carried out on the surface of Titanium dioxide particle without forming the new Titanium dioxide particle during acrylate shell polymerized in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

• 청정기술
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• 제27권2호
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• pp.115-123
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• 2021

본 연구는 무기 실리카 껍질(shell)과 유기 고분자 코어(core)로 구성된 매우 균일한 유-무기 복합체 입자 제조의 방법에 관한 것이다. 먼저, 미세유체 기술을 이용하여 균일한 크기를 지니는 유기 고분자 코어 입자를 제조하였다. 코어 입자의 제조 과정에서 코어 입자의 제조 과정에서 광 경화성 유기 물질이 포함된 분산상과 연속상의 유속을 독립적으로 제어함으로써 균일한 액적을 형성하였다. 액적이 형성됨과 동시에, 미세유체 채널의 말단에서 자외선 조사에 의해 액적이 광중합 되어 코어 입자로 형성된다. 더불어, 폴리알릴아민 하이드로클로라이드(polyallylamine hydrochloride, PAH)와 인산 이온(phosphate ion)으로 구성된 나노 복합체는 최적화된 pH 조건에서 수소결합과 정전기적 인력 같은 강력한 상호작용을 통해 코어 입자에 코팅된다. 폴리아민 나노 복합체에 존재하는 PAH 주쇄의 아민 그룹들은 규산(silicic acid)의 축합(condensation) 반응을 촉매하여, 코어 입자 표면의 실리카 나노입자 성장을 시킬 수 있었다. 따라서, 본 방법을 통해 유기 코어에 무기 실리카 나노입자로 코팅된 유-무기 복합체 입자를 제조할 수 있었다. 최종적으로, 본 연구에서 제시한 방법은 보다 온화하며 환경친화적인 조건 하에서 단시간 내에 유-무기 복합체 입자를 합성할 수 있으며, 다양한 모양과 크기를 갖는 코어 입자에 적용되어 넓게 활용될 수 있다.