• Journal of the Korean Society for Marine Environment & Energy
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• v.2 no.2
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• pp.60-69
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• 1999

In this paper, we have obtained the initial and near-field dilution rates of wastewaters discharged from the ocean outfall of Masan-Changwon municipal wastewater treatment plant from both of field measurements and CORMIX model simulations. In the summer of 1998, water temperature and salinity profiles was measured at 16 stations in the vicinity of the Masan outfall and the dilution rates were analyzed by salinity deficit method. The transport of the wastefields and their initial dilution rates were calculated by CORMIX model using field data as model input. Both of observed and predicted results are shown In very low dilutions with the range of 32～48 from the field data analysis and 29～43 from the model prediction, respectively. This indicates that the water quality in the Masan outfall area can be worsening due to the low dilution rates of diswastewaters, especially, when the ambient currents are very weak in a neap tide and ambient water density is highly stratified in summer.

• Biotechnology and Bioprocess Engineering:BBE
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• v.6 no.6
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• pp.410-418
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• 2001

The effects of several variables on the refolding of hen egg white lysozyme have been studied, Lysozyme was denatured in both urea, and guanidine hydrochloride(GuHCl), and batch refolded by dilution (100 to 1000 fold) into 0.1 M Tris-HCI, pH 8.2 mM EDTA 3 mM reduced glutathione and 0.3 mM oxidised glutathions. Refolding was found to be sensitive to temperature, with the highest refolding yield obtained at 50$\^{C}$. The apparent activation energy for lysozyme re-folding wasf ound to be 56kJ/mol, Refolding by dilution results in low concentrations of both de-naturant and reducing agent species. It was found that the residual concentrations obtained dur-ing dilution(100-fold dilution:[GuHCI]=0.06 mM, [DTT]=0.15 mM) were significant and could inhibit lysozyme refolding. This study has also shown that the initial protein concentration (1-10mg/mL) that is refolded is an important parameter. In the presence of residual GuHCl and DTT higher refolding yields were obtained when starting from higher initial lysozyme concentra-tions. This trend was reversed when residual denaturant components were removed from the re-folding buffer.

• Microbiology and Biotechnology Letters
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• v.23 no.6
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• pp.717-722
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• 1995

Using a flocculating Saccharomyes cerevisiae CA-1, an air-lift reactor equipped with a modified settler was used for ethanol fermentation. The effects of conditions such as aeration rate, initial glucose concentration, and dilution rate were studied using the air-lift reactor. In batch fermentation, optimum aeration rate was 0.5 vvm. In continuous fermentation, aeration rate and initial pH were fixed 0.5 vvm and 4.5, substrate concentration and dillution rate were changed 10-15% and 0.1-1.3. The maximum ethanol productivity was shown to be 20.4 g/l$\cdot $h in 10% glucose and 0.7 h$^{-1}$ dilution rate., and optimum operation condition considering the ethanol productivity and glucose utilization ratio was 0.5 h$^{-1}$ dilution rate in 10% glucose concentration.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.1
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• pp.1-8
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• 2004

An study has been performed with axisymmetric coflow diffusion flames to investigate the influence of air-side fuel side dilution and initial preheated temperature on the soot formation in methan/air flames. Soot quantities are determined by using PLII(Planar Laser Induced Incandescence), such a $C_2$H$_2$ major species(CH$_4$, $O_2$, $N_2$) and temperature are simulated by chemkin code. The numerical analysis was performed with transport properties and detailed reaction mechanisms m axisymmetric coflow diffusion flames. The study of how flame temperature and $N_2$ dilution of air and fuel side influence the soot concentrations is focused. Soot concentrations results on PLII show that preheated temperature contributes to an increase in the soot volume fraction, and soot formation Is more productive to air side dilution than to fuel side dilution. $C_2$H$_2$ concentrations have a similar tendency to soot concentrations.

• Journal of Korea Water Resources Association
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• v.33 no.2
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• pp.207-217
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• 2000

A numerical model is applied to analyze the mixing characteristics of an axisymmetric turbulent buoyant jet discharged into flowing stratified ambients. The numerical model is a Gaussian-vortex model which incorporates the effects of the vortex pair known as the representative characteristics of far-field in flowing ambients. Six ocean outfalls that have field data for the initial dilution at the water surface are selected for testing the applicability of the developed numerical model. The comparisons of the observed initial dilutions and the simulated ones show that the developed numerical model could be used for the analyses of the initial mixings induced by the sewage diffuser discharged into the ocean.

• Journal of Radiation Protection and Research
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• v.23 no.1
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• pp.1-6
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• 1998

A diffusion model of radioactive liquid effluents is developed and applied for YGN NPP's site, based on the Gaussian plume type model. Due to the complexity of oceanic diffusion characteristics of YGN site, a simple and reliable statistical model based on Reg. Guide 1.113 is developed. Also, a computer code package to calculate dilution factors as a function of plant operation conditions and pathway of radioactive materials. A liquid effluents diffusion model is developed by dividing the diffusion range into two categories, i. e, a near field mixing region and a far field mixing region. In the near field, the initial mixing is affected by a buoyance force, a high initial turbulence and momentum which is characterized by a plant operation condition and environmental conditions. The far field mixing is similar to gaseous effluents diffusion. So, beyond the near field region, wellknown Gaussian plume model was adopted. A different area averages of Gaussian plume equation was taken for each radioactive exposure pathway. As a result, we can get different dilution factors for different pathways. Results shows that present dilution factors used for YGN ODCM is too much overestimated compared with dilution factors calculated with the developed model.

• Journal of the Korean Society for Marine Environment & Energy
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• v.3 no.1
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• pp.35-44
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• 2000

The winter case of the near-field dilution at the Masan outfalls has been studied by field measurements and CORMIX model simulations. Dilution rates of the wastewater discharge in winter were obtained by a salinity deficit method using the field data observed in the neap tidal period of February, 1999. The observed dilution rates in winter season were found to be very high in the range of 90～130 due to the isopycnal mixing of ambient density compared with the summer range of 30～40 under weak neap tidal currents. The results of CORMIX model simulations also show that the winter dilution rates under a weak ambient current(Ua=6.0ms/s) were increased by 3-fold of the summer dilution rates. However, the difference between two seasons becomes small by 30% under a strong current(Ua=15.5cm/s). This result indicates that the dilution and hydrodynamic mixing process of the effluents are more influenced by ambient crossflow condition than by ambient density stratification at the outfalls site.

• Journal of the Speleological Society of Korea
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• no.71
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• pp.5-11
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• 2006

A theoretical investigation of the solid phase mechanochemical synthesis of nano sized target product on the basis of dilution of the initial powdered reagent mixture by another product of an exchange reaction is presented. On the basis of the proposed 3 mode particle size distribution in mechanically activated mixture, optimal molar ratios of the components in mixture are calculated, providing the occurrence of impact friction contacts of reagent particles and excluding aggregation of the nanosized particles of the target reaction product. Derivation of kinetic equations for mechanochemical synthesis of nanoscale particles by the final product dilution method in the systems of exchange reactions is submitted. On the basis of obtained equations the necessary times of mechanical activation for complete course of mechanochemical reactions are designed. Kinetics of solid phase mechanosynthesis of nano TlCl by dilution of initial (2NaCl+$Tl_2SO_4$) mixture with the exchange reaction product (diluent,$zNa_2SO_4$, z=z*=11.25) was studied experimentally. Some peculiar features of the reaction mechanism were found. Parameters of the kinetic curve of nano TlCl obtained experimentally were compared with those for the model reaction KBr+TlCl+zKCl=(z+1) KCl+TlBr (z=z1*=13.5), and for the first time the value of mass transfer coefficient in a mechanochemical reactor with mobile milling balls was evaluated. Dynamics of the size change was followed for nanoparticle reaction product as a function of mechanical activation time.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.405-406
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• 2005

A theoretical investigation of the solid-phase mechanochemical synthesis of nano-sized target product on the basis of dilution of the initial powdered reagent mixture by another product of an exchange reaction is presented. On the basis of the proposed 3-mode particle size distribution in mechanically activated mixture, optimal molar ratios of the components in mixture are calculated, providing the occurrence of impact-friction contacts of reagent particles and excluding aggregation of the nanosized particles of the target reaction product. Derivation of kinetic equations for mechanochemical synthesis of nanoscale particles by the final product dilution method in the systems of exchange reactions is submitted. On the basis of obtained equations the necessary times of mechanical activation for complete course of mechanochemical reactions are designed. Kinetics of solid phase mechanosynthesis of nano-TlCl by dilution of initial (2NaCl + $Tl_2SO_4$) mixture with the exchange reaction product (diluent, $zNa_2SO_4$, $z=z^*=11.25$) was studied experimentally. Some peculiar features of the reaction mechanism were found. Parameters of the kinetic curve of nano-TlCl obtained experimentally were compared with those for the model reaction KBr + TlCl + zKCl = (z + 1) KCl + TlBr ($z=z_l^*=13.5$), and for the first time the value of mass transfer coefficient in a mechanochemical reactor with mobile milling balls was evaluated. Dynamics of the size change was followed for nanoparticle reaction product as a function of mechanical activation time.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.9
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• pp.1209-1219
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• 2003

The dynamic behaviors of the single vortex interacting with $CH_4-Air$ jet diffusion flame are investigated numerically. The numerical method is based on a predict-corrector scheme for a low Mach number flow. A two-step global reaction mechanism is adopted as a combustion model. Studies are conducted in fixed initial velocities for the three cases according as where $CO_2$ is added; (1) without dilution, (2) dilution in fuel stream and (3) dilution in oxidizer stream. A single vortex is generated by an axisymmetric jet, which is made by an impulse of a cold fuel when a flame is developed entirely in a computational domain. The simulation shows that $CO_2$ dilution in fuel stream results in somewhat larger vortex radius, and greater amount of entrainment of surrounding fluid than in other cases. Thus, the dilution of $CO_2$ in fuel stream enhances the mixing in single vortex and increases the stretching of the flame surface. The budgets of the vorticity transport equation are examined to reveal the mechanism of vortex formation when $CO_2$ is added. It is found that, in the case of $CO_2$ dilution in fuel stream, the vortex destruction due to volumetric expansion and the vortex production due to baroclinic torque are more dominant than in other cases.