• Title/Summary/Keyword: Initial Concentration

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The Explosion Characteristics of City Gas on the Change of Oxygen Concentration and Pressure (산소농도와 압력 변화에 따른 도시가스의 폭발특성)

  • Choi Jae-Wook;Lee In-Sik;Park Sung-tae
    • Journal of the Korean Institute of Gas
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    • v.9 no.1 s.26
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    • pp.38-43
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    • 2005
  • To examine the characteristics of the explosion of city gas, the concentration of oxygen was changed with the change of initial pressure. From the result of the experiment, as the concentration of oxygen was low, the explosion limit became narrow and the minimum concentration of oxygen for the explosion was $12\%$. Furthermore, As the increase of the initial pressure, explosion ranges were a little increased. And as the change of the initial pressure, the maximum explosion pressure were $6.3 kgf/cm^2{\cdot}g,\;12.7 kgf/cm^2{\cdot}g$ and the maximum pressure rising velocity were $245.63 kgf/cm^2/s,\;427.88 kgf/cm^2/s$.

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Investigation of Nickel Removal from Heavy Metal Containing Industrial Wastewater by Electrocoagulation Method

  • Baybars Ali, Fil;Cansu, Elgun;Sevim Alya, Cihan;Sermin, Gunaslan;Alper Erdem, Yilmaz
    • Journal of Electrochemical Science and Technology
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    • v.13 no.4
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    • pp.424-430
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    • 2022
  • In the study, Ni2+ (nickel) removal from synthetically prepared wastewater by electrocoagulation method, which is one of the electrochemical treatment processes, was investigated and parameters such as current density, pH, mixing speed, initial Ni2+ concentration, supporting electrolyte type and concentration were determined to determine Ni2+ removal efficiencies effects were studied. Experiment conditions during 30 minutes of electrolysis; the current density was determined as 0.95 mA/cm2, the initial pH of the wastewater was 6, the mixing speed was 150 rpm, and the initial nickel concentration was 250 mg/L. The Ni2+ removal efficiency was obtained as 75.99% under the determined experimental conditions, while the energy consumption was calculated as 3.15 kW-h/m3. In the experiments, it was observed that the type and concentration of the supporting electrolyte did not have a significant effect on the Ni2+ removal efficiency. In the trials where the effect of the support electrolyte concentration was examined, the Ni2+ removal efficiency was 75.99% in the wastewater environment without the supporting electrolyte, while the Ni2+ removal efficiency was 81.55% when 7.5 mmol/L NaCl was used after the 30-minute reaction, and the energy consumption was 2.15 kW-h/m3 obtained as. As a result of the studies, it was concluded that the electrocoagulation process can be applied in the treatment of wastewater containing Ni2+.

Assessment of Sorption Behavior on Slag Against Heavy Metals (카드뮴, 납, 구리에 대한 슬래그의 흡착특성평가)

  • Lee, Gwang-Hun;Choi, Sung-Dae;Chung, Jae-Shik;Park, Jun-Boum;Nam, Kyoung-Phile
    • Journal of the Korean Geotechnical Society
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    • v.24 no.6
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    • pp.17-25
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    • 2008
  • Permeable reactive barriers (PRBs) technology can be applied to contaminated groundwater remediation. It is necessary to select adequate reactive material according to contaminant characterization. In groundwater. In this research, the reaction between reactive material and heavy metal contaminants was estimated through batch test. Reactive material was slag, which has been produced in Gwangyang power plant, and heavy metal contaminants were cadmium, lead and copper. Batch test consisted of two testes: 1) sorption equilibrium test and 2) sorption kinetic test. Sorption equilibrium test was performed for estimating slag sorption capacity against contaminants. And sorption kinetic test was performed for slag sorption rate with contaminants species, contaminants initial concentration and sulfate. Sorption capacity and sorption rate were affected by contaminant species. Sorption rate increased with increasing initial concentration in lead and copper but decreased with increasing initial concentration in cadmium. Sorption rate increased in existing sulfate. In low concentration, film diffusion was domain mechanism, and in high concentration, particle diffusion was domain mechanism.

Effects of Initial Concentration of Ammonium Ion and Active Nitrifiers on Nitrification (암모늄 이온 및 질산화균의 초기 농도가 질산화에 미치는 영향)

  • Kim, Jung Hoon;Kim, Young Ju;Park, Hung Suck
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4B
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    • pp.421-426
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    • 2006
  • The effect of initial concentration of ammonium ion ($N_0$) and active nitrifiers ($X_0$) on nitrification was examined by continuous monitoring of the ammonium removal rate. The concentration of the active nitrifiers in the culture sludge, measured by the oxygen uptake rate (OUR), was found to be 42.8% of the culture sludge. Experiments were carried out under different ratios of $N_0/X_0$, viz., 0.025 to 0.493. The results from this study show that the oxidation rate was similar under the same $N_0/X_0$ ratio despite different initial concentration of ammonium ion ($N_0$) and active nitrifiers ($X_0$). Moreover, the Contois kinetic expression which includes biomass concentration, was found to describe the mechanism behind nitrification process. The ammonium oxidation rate ($q_{Nmax}$) and half saturation constant per unit activated nitrifiers ($K_N{^{\prime}}$) were theoretically determined using the Contois expression. These values were found to be 4.32 gN/gVSS/day and 0.013 gN/gVSS respectively.

Furfural Production From Xylose by Using Formic Acid and Sulfuric Acid (포름산 및 황산 촉매를 이용한 자일로스로부터 푸르푸랄 생산)

  • Lee Seungmin ;Kim Jun Seok
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.561-569
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    • 2023
  • Furfural is a platform chemical that is produced from xylose, one of the hemicellulose components of lignocellulosic biomass. Furfural can be used as an important feedstock for phenolic compounds or biofuels. In this study, we compared and optimized the conditions for producing furfural from xylose in a batch system using two types of catalysts: sulfuric acid, which is commonly used in the furfural production process, and formic acid, which is an environmentally friendly catalyst. We investigated the effects of xylose initial concentration (10 g/L~100 g/L), reaction temperature (140~200 ℃), sulfuric acid catalyst (1~3 wt%), formic acid catalyst (5~10 wt%), and reaction time on the furfural yield. The optimal conditions according to the type of catalyst were as follows. For sulfuric acid catalyst, 3 wt% of catalyst concentration, 50 g/L of xylose initial concentration, 180 ℃ of temperature, and 10min of reaction time resulted in a maximum furfural yield of 59.0%. For formic acid catalyst, 5 wt% of catalyst concentration, 50 g/L of xylose initial concentration, 180 ℃ of temperature, and 150 min of reaction time resulted in a furfural yield of 65.3%.

A Diffusion-based Model Theory of Passive-Targeted Drug Delivery in Solid Tumors (단단한 종양 안에 수동 조준된 약물의 전달에 관한 확산에 기초한 모델 이론)

  • Choi, Joon-Hyuck;Kang, Nam-Lyong;Choi, Sang-Don
    • Progress in Medical Physics
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    • v.18 no.3
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    • pp.161-166
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    • 2007
  • A model theory of passive-targeted drug delivery in sphere-shaped solid tumors is introduced on the basis of Fick's law of diffusion, with appropriate boundary and initial conditions. For a uniform initial concentration inside the tumor, the concentration is obtained as a function of time and radial position. The concentration is shown to approach the equilibrium distribution as the time elapses, as is expected by the Gedanken Experiment. The time-evolution rate is found to be determined by the diffusion coefficient of the drug in the tissue, the size of the tumor, the volume of the drug-injected region, and the concentration gradient at the boundary.

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Effects of Plant Age Inoculum Concentration and Inoculation Method on Root Gall Development of Clubroot Disease of Chinese Cabbage Caused by Planmodiophora brassicae (배추무사마병의 뿌리혹 형성에 미치는 묘령, 접종원 농도 및 접종방법의 영향)

  • 김충회
    • Plant Disease and Agriculture
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    • v.5 no.2
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    • pp.90-94
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    • 1999
  • Effect of inoculum concentration inoculation method and plant age on development of clubroot disease of Chinese cabbage seedling were examined in growth chambers. Root galls were developed at the concentration of 105 resting spore or above per ml of incoulum and as the inoculum concentration became higher rate of development of root galls was faster. In the plants with root gall development fresh weight of above ground parts was reduced to 30-44% of that of healthy plants but root weight increased by 4-10 times. Growth of diseased plants was greatly reduced as compared to healthy plants. Planting in the diseased soil as a inoculation method was most effective for disease development showing uniform infections but time of initial root gall development was delayed by root soaking inoculation. Some plants inoculated by soil drenching method did not develop root galls. However root gall enlargement after its initial formation did not differ greatly among inoculation methods. Nine-day-old seedlings showed poor development of root gall but 16-days-old seedlings was found to be most adequate for inoculation for gall development.

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Nocardia orientalis 변이주에 의한 고농도 혼합당을 이용한 반코마이신 생산

  • 김창호;고영환;고중환
    • Microbiology and Biotechnology Letters
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    • v.24 no.4
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    • pp.404-407
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    • 1996
  • The effects of carbon sources on vancomycin production were investigated using Nocardia orientalis CSVC 3300. Among carbon sources tested, glucose, maltose and fructose were effective for the production of vancomycin. Glucose was favored for growth, but decrease the production of vancomycin at the concentration above 7.5%. In comparison, maltose did not decrease the production of vancomycin up to the concentration of 20%. When the mixture of glucose and maltose was used in the ratio 1:3 to 1:4, the highest production of vancomycin was achieved. When glucose concentration was set at 3.0%, catabolite repression could not be observed up to total sugar concentration of 16.0%. Fermentation was carried out using commercial hydrolyzed starch composed of glucose, maltose, maltotriose and maltotetraose, The initial glucose concentration was set at 3.0% and subsequent oligosaccharide consumption was monitored by checking their supernatant with HPLC. During initial cultivation for 38 hour, glucose was the sole carbon source leading to rapid growth. After cell growth stopped, the maltose and glucose concentrations increased due to degradation of maltotriose and maltotetraose, but glucose level was maintained at around 3.0%. After 70 hour fermentation, maltose slowly converted to glucose, and vancomycin production continued during the period.

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Photocatalytic Degradation of Gaseous Acetaldehyde through TiO2-Coated Fly Ash Composites (TiO2 코팅 석탄회 복합체의 기상 Acetaldehyde 광분해 특성)

  • Shin, Dae-Yong;Kim, Kyung-Nam
    • Journal of the Korean Ceramic Society
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    • v.45 no.1
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    • pp.43-47
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    • 2008
  • The photocatalyst of $TiO_2$ coated on a fly ash composites (TCF) was prepared from precipitant dropping method to remove the acetaldehyde by photocatalytic reaction. The TCF were characterized by crystal aize, crystal structure and specific surface area. The photodegradation of acetaldehyde has been investigated using a UV-illuminated fixed photocatalytic reactor with TCF catalyst and P-25 catalyst in gas phase. The effect of photodegradation reaction conditions, such as initial concentration of acetaldehyde, concentration of oxidant in mixed gas and the light intensity on the photodegradation of acetaldehyde were investigated. P-25 catalyst showed the highest photodegradation of acetaldehyde and anatase $TiO_2$ coated TCF showed higher decomposition rate than rutile coated TCF. The photodegradation rate of acetaldehyde increased with the decrease of flow rate, initial concentration of acetaldehyde ($C_i$) and water vapor, however, it was increased with the increas of UV light intensity. The optimum conditions were weight of TCF=10 g, flow rate=50 ml/min $C_i$=100 ppm, concentration of oxygen=20%, concentration of water vapor=100 ppm.

Biological production of $H_2$ from glucose by the chemoheterotropic facultative bacterium, Rhodopseudomonas palustris P4

  • Seol, Eun-Hee;Oh, You-Kwan;Noh, Min-Hyun;Park, Sung-Hoon
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.594-597
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    • 2001
  • RhodopseudolllOllas palustris P4 was studied for $H_2$ production from glucose in batch culture. Important conditions studied include phosphate concentration, initial pH, temperature, glucose concentration, and gas-phase replacement. Optimal $H_2$ production was observed at 60 - 300 mM of phosphate and 7.8 - 8.6 of initial pH. The effect of culture temperature was negligible When glucose concentration increased from 0.1 to 5% (w/v), $H_2$ production increased up to 2% and remained constant thereafter. Intermittent purging of the reaction botlle with Ar gas stimulated the Hl production by alleviating the inhibition by $H_2$. The maximum productivity was 111.1 ml $H_2$/h-1.

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