• Title/Summary/Keyword: Inhomogeneous Materials

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Solution-based fabrication of germanium sulphide doped with or without Li ions for solid electrolyte applications

  • Jin, Byeong Kyou;Cho, Yun Gu;Shin, Dong Wook;Choi, Yong Gyu
    • Journal of Ceramic Processing Research
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    • v.13 no.spc1
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    • pp.110-113
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    • 2012
  • Ge-S and Li-Ge-S powders were synthesized via solution-based process in order to employ chalcogenide-based solid electrolyte for use in Li secondary batteries. GeCl4 and thioacetamide in combination result in Ge-S powders of which major crystalline phase becomes GeS2 where the tetragonal and orthorhombic phases coexist after heat treatment. A chemical treatment using NaOH brings about the reduction of chlorine in the powders obtained. However, the heat treatment at 300 ℃ is more effective in minimizing the chlorine content. When lithium chloride is used as the precursor of Li ions, the LiCl powders are agglomerated with an inhomogeneous distribution. When Li2S is used, the Li-Ge-S powders are distributed more uniformly and the orthorhombic GeS2 phase dominates in the powders.

Micromechanical Superplastic Model for the Analysis of Inhomogeneous Deformation in Heterogeneous Microstructure (비균일 조직에 따른 불균일 변형 해석을 위한 미시역학적 초소성 모텔)

  • Kim, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.12
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    • pp.1933-1943
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    • 2001
  • A micromechanical model is presented for superplasticity in which heterogeneous microstructures are coupled with deformation behavior. The effects of initial distributions of grain size, and their evolutions on the mechanical properties can be predicted by the model. Alternative stress rate models such as Jaumann rate and rotation incremental rate have been employed to analyze uniaxial loading and simple shear problems and the appropriate modeling was studied on the basis of hypoelasticity and elasto-viscoplasticity. The model has been implemented into finite element software so that full process simulation can be carried out. Tests have been conducted on Ti-6Al-4V alloy and the microstructural features such as grain size, distributions of grain size, and volume fraction of each phase were examined for the materials that were tested at different strain rates. The experimentally observed stress-strain behavior on a range of initial grain size distributions has been shown to be correctly predicted. In addition, the effect of volume fraction of the phases and concurrent grain growth were analyzed. The dependence of failure strain on strain rate has been explained in terms of the change in mechanism of grain growth that occurs with changing strain rate.

Elimination of the Fabry-Perot effect in a $4{\times}4$ matrix method ($4{\times}4$ 행렬 연사에서 Fabry-Perot 간섭효과의 제거방법)

  • 우성일;백흠일;박구현;박세민;이기동;윤태훈;김재창
    • Korean Journal of Optics and Photonics
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    • v.9 no.1
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    • pp.5-8
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    • 1998
  • In calculating the light propagation in inhomogeneous uniaxial materials by using a conventional $4{\times}4$ matrix method, Fabry-Perot effect is caused by inherent multiple internal reflections at interfaces for monochromatic light source. In this paper we propose an apodization method by which we can eliminate in negligible time the interference fringe in the $4{\times}4$ matrix optics. For a cell with k abrupt interfaces, the new apodization method can be implemented simply by, at maximum, (k+1) addtional $4{\times}4$ matrix multiplications in calculating the complete transfer matrix of the cell.

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The Evaluation of the dose calculation algorithm(AAA)'s Accuracy in Case of a Radiation Therapy on Inhomogeneous tissues using FFF beam (FFF빔을 사용한 불균질부 방사선치료 시 선량계산 알고리즘(AAA)의 정확성 평가)

  • Kim, In Woo;Chae, Seung Hoon;Kim, Min Jung;Kim, Bo Gyoum;Kim, Chan Yong;Park, So Yeon;Yoo, Suk Hyun
    • The Journal of Korean Society for Radiation Therapy
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    • v.26 no.2
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    • pp.321-327
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    • 2014
  • Purpose : To verify the accuracy of the Ecilpse's dose calculation algorithm(AAA:Analytic anisotropic algorithm) in case of a radiation treatment on Inhomogeneous tissues using FFF beam comparing dose distribution at TPS with actual distribution. Materials and Methods : After acquiring CT images for radiation treatment by the location of tumors and sizes using the solid water phantoms, cork and chest tumor phantom made of paraffin, we established the treatment plan for 6MV photon therapy using our radiation treatment planning system for chest SABR, Ecilpse's AAA(Analytic anisotropic algorithm). According to the completed plan, using our TrueBeam STx(Varian medical system, Palo Alto, CA), we irradiated radiation on the chest tumor phantom on which EBT2 films are inserted and evaluated the dose value of the treatment plan and that of the actual phantom on Inhomogeneous tissue. Results : The difference of the dose value between TPS and measurement at the medial target is 1.28~2.7%, and, at the side of target including inhomogeneous tissues, the difference is 2.02%~7.40% at Ant, 4.46%~14.84% at Post, 0.98%~7.12% at Rt, 1.36%~4.08% at Lt, 2.38%~4.98% at Sup, and 0.94%~3.54% at Inf. Conclusion : In this study, we discovered the possibility of dose calculation's errors caused by FFF beam's characteristics and the inhomogeneous tissues when we do SBRT for inhomogeneous tissues. SBRT which is most popular therapy method needs high accuracy because it irradiates high dose radiation in small fraction. So, it is supposed that ideal treatment is possible if we minimize the errors when planning for treatment through more study about organ's characteristics like Inhomogeneous tissues and FFF beam's characteristics.

Mechanisms of Tensile and Creep Deformation at Elevated Temperatures in a Ni-Base Superalloy Alloy 263 (니켈기 초내열합금 Alloy 263의 고온인장 및 크리프 변형기구)

  • Kim, In Soo;Choi, Baig Gyu;Hong, Hyun Uk;Jo, Chang Yong
    • Korean Journal of Metals and Materials
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    • v.49 no.7
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    • pp.535-540
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    • 2011
  • The tensile and creep behaviors of Alloy 263, which is a wrought Ni-base superalloy used for gas turbine combustion systems, was studied. Anomalous increase of yield strength and abrupt decrease of elongation with increasing temperature were observed after tensile testing at an intermediate temperature. Elongation of the superalloy decreased as the temperature increased to and above 540$^{\circ}C$, and it reached a minimum value at 760$^{\circ}C$. It was found that creep strain was also very low at the same temperature. Inhomogeneous deformation with intensive slip bands was observed in the specimens tested at low temperature. A thermally-assisted dislocation climb process was regularly conducted at high temperature. Twinning was found to be an important mechanism of both tensile and creep deformations of the superalloy at an intermediate temperature where ductility minimum was observed.

Influence of a soft FGM interlayer on contact stresses under a beam on an elastic foundation

  • Aizikovich, Sergey M.;Mitrin, Boris I.;Seleznev, Nikolai M.;Wang, Yun-Che;Volkov, Sergey S.
    • Structural Engineering and Mechanics
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    • v.58 no.4
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    • pp.613-625
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    • 2016
  • Contact interaction of a beam (flexible element) with an elastic half-plane is considered, when a soft inhomogeneous (functionally graded) interlayer is present between them. The beam is bent under the action of a distributed load applied to the surface and a reaction of the elastic interlayer and the half-space. Solution of the contact problem is obtained for different values of thickness and parameters of inhomogeneity of the layer. The interlayer is assumed to be significantly softer than the underlying half-plane; case of 100 times difference in Young's moduli is considered as an example. The influence of the interlayer thickness and gradient of elastic properties on the distribution of the contact stresses under the beam is studied.

Investigation of Initiation of Electroless Ni-P and Ni-Cu-P deposition on pure iron

  • Yiyong, W-U;Kim, M.;S.C. Kwon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.11a
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    • pp.10-10
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    • 2001
  • In this paper, initial depositing process of electroless Ni-Cu-P alloy was investigated by means of SEM, TEM and AES. The results show that the initial deposition is inhomogeneous and there exist different transition layers between different coatings and substrates, which are decided by the structures and compositions of the bath. For Ni-P binary alloy, its deposition takes place superiorly at grain boundary and on some grains with beneficial texture, the thickness of transition layer composed of Ni-Fe-P reaches 2000 angstrom. But during initiation of Ni-Cu-P trinary alloy, only at grain boundary is prIor to be deposited electrolessly, transited layer contains Ni-Fe-Cu-P and is decreased to about 500 angstrom. The structures of the films of Ni-P and Ni-Cu-P are crystalline at the initial depositing stage. The mechanisms of the process are put forward in this paper.

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The Preliminary Study on the Quantitative Analysis of Quarts by Fourier Transform Infrared Spectrophotometric Direct on Filter(FTIR-DOF) Method -Effects of filter materials, inhomogeneity of deposition, and humidity- (Fourier Transform Infrared Spectrophotometric Direct on Filter 방법을 이용한 석영 분석의 기초 연구 - 필터재질, 비균일 침착 및 습도의 영향 -)

  • Phee, Young Gyu;Kim, Hyunwook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.15 no.1
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    • pp.1-7
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    • 2005
  • Although the Fourier Transform Infra-Red spectrophotometric Direct on Filter(FTIR-DOF) method is a useful analytical technique for quantifying quartz content in respirable dust samples, a number of analytical problems must be taken into consideration such as, to name only a few, inhomogeneous deposition of particles, level of environmental humidity, uneven surface of the filter, and interfering minerals in the sample. This study was designed to select the most suitable wavelength and proper filter material for the method, and to investigate effects of humidity and inhomogeneous deposition of particles on the filter. Samples of respirable dust, created in a dust chamber containing standard material of quartz, were collected using a cyclone equipped with a 25mm filter as a collection medium. The results were as follows; 1. Among seven (7) commercially available filters tested for the FTIR-DOF method, the DM 800 filter showed the best analytical performance having the lowest background absorbance bands and no overlapping peaks at 799, 779, and $695cm^{-1}$. 2. The variations of absorbance due to humidity ranged from 1.0% to 3.3% for $799cm^{-1}$, 1.0% to 3.3% for $779cm^{-1}$, and 8.9%~20.9% for $695cm^{-1}$ peaks, respectively. The $699cm^{-1}$ peak was proved to be most vulnerble to environmental humidity for quantitative analysis of quartz. 3. As for effects of inhomogeneous deposition of samples, the highest variation of absorbance of 10.9% ($13.5{\mu}g$) was observed when using the 695cm-1. The variations of absorbance from the other two peaks, 799 and $779cm^{-1}$, ranged from 1.2 to 3.2%, and 1.4 to 4.1%, respectively. Therefore, the $799cm^{-1}$ peak was considered to be most reliable for quantitative analysis of quartz. The results of this study suggest that, for quantitative analysis of quartz in the respirable dust samples, use of the $799cm^{-1}$ peak can minimize the influence of environmental humidity and inhomogeneous deposition of particles on the filter. The FTIR-DOF method, if adopted for routine analysis of quartz in the respirable dust samples, could save sample preparation time and efforts substantially and also could increase analytical throughputs. Since use of the $799cm^{-1}$ peak is prone to be affected by interferences in the sample, further research on minimizing the effects is needed.

Microstructure and Wear Resistance Properties of Cu-W Sintered Materials Fabricated by Hot Pressing (Hot pressing으로 제조된 Cu-W계 소결재의 미세조직 및 내마모특성)

  • Park, Ji-Hwan;Kim, Su-Bang;Park, Yun-U
    • Korean Journal of Materials Research
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    • v.10 no.3
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    • pp.227-232
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    • 2000
  • Cu-W composites containing 20wt.% W were fabricated by hot pressing. Hot pressing was carried out at temperatures ranging from 800 to $1000^{\circ}C$ under pressures of 15MPa for 30MPa for 30min and 60min. This process gave composites of higher density, higher hardness and higher wear resistance than the conventional sintering processes. However, the microstructure of Cu-W composites under pressure of 15MPa revealed there was an inhomogeneous distribution of W, segregation of W on some area. These undesirable results are attributed to the immiscibility of W in Cu and the pressure effect on sintering.

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PWSCC growth rate model of alloy 690 for head penetration nozzles of Korean PWRs

  • Kim, Sung-Woo;Eom, Ki-Hyun;Lim, Yun-Soo;Kim, Dong-Jin
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1060-1068
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    • 2019
  • This work aims to establish a model of a primary water stress corrosion crack growth rate of Alloy 690 material for the head penetration nozzles of Korean pressurized water reactors. The test material had an inhomogeneous microstructure with bands of fine-grains and intragranular carbides in the matrix of coarse-grains, which was similar to the archive materials of the head penetration nozzles. The crack growth rate was measured from the strain-hardened materials as a function of the stress intensity factor in simulated primary water at various temperatures and dissolved hydrogen contents. The effects of strain-hardening, temperature, and dissolved hydrogen on the crack growth rate were analyzed independently, and were then introduced as normalizing factors in the crack growth rate model. The crack growth rate model proposed in this work provides a key element of the tools needed to assess the progress of a stress corrosion crack when detected in thick-wall Alloy 690 components in Korean reactors.