• Journal of the Korean Ceramic Society
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• v.36 no.9
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• pp.915-922
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• 1999

Microwave dielectric properties and far infrared reflectivity spectra of the (Zr0.8Sn0.2)TiO4 ceramics were inves-tigated with the various cooling rate. Dielectric constant was nearly same value while the unloaded Q value was largely affected by cooling rate. The Q.f of 42,140 at 7 GHz was obtained for the specimens with cooling rate of 1$^{\circ}C$/min. The effect of the cooling rate on the change of the ionic the electronic polarization and the intrinsic microwave loss of the specimens were investigated by the infrared reflectivity spectra from 50 to 4000cm-1 which were calculated by Kramers-Kroning analysis and the classical oscillator model. The relative tendency of microwave dielectric properties of the specimens calculated from the relfectivity data were in good agreement with the results by the post resonant method.

• Journal of the Korean Ceramic Society
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• v.37 no.3
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• pp.240-246
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• 2000

The microwave dielectric properties of the complex perovskite (Pb0.5Ca0.5)(Fe0.5Ta0.5)O3 ceramics were investigated with the porosity and the dielectric mixing rule. Assuming that the specimens were mixtures of real dielectrics and pores, with 3-0 connectivity, the ionic polarizabilities modified by Maxwell's equation were more close to the theoretical values rather than those modified by Wiener's equation in porous specimens. The theoretical dielectirc loss were obtained with the infrared reflectivity spectra from 50 to 4000cm-1, which were calculated by Kramers-Kronig analysis and classical osciallator model. The relative tendency of dielectric loss calculated from the theoretical value and Maxwell's equation in the specimens with different porosities was in good agreement with the one by the post resonant method.

• Progress in Superconductivity
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• v.3 no.1
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• pp.13-16
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• 2001

We have measured the reflectivity of superconducting infinite-layer compounds $Sr_{0.9}$ $Ln_{0.1}$ Cu $O_2$ (Ln=La, Gd, Sm) with $T_{c}$ : 39 K using a Fourier-transform infrared spectrometer. We have identified the optical phonon modes from their infrared reflectivity and conductivity spectra and have proposed possible displacement patterns. The La- and the Gd-doped compounds exhibited only four ($2A_{2u}$ $+2E_{u}$) out of the five ($2A_{2u}$ $3E_{u}$) infrared-active phonons predicted by a group theoretical analysis whereas the Sm-doped compound exhibited all five modes. For the La-doped sample, we investigated the temperature dependence of the optical response functions in a wide temperature range of 7 - 300 K. In FIR region, the reflectivity is apparently enhanced below ~120 $cm^{-1}$ as temperature decreases across $T_{c}$. The value of $2$\Delta$/k_{B}$ $T_{c}$ is about 4.5, which is consistent with maximum gap value of d-wave $high- T_{c}$ cuprates.> c/ cuprates.uprates.s.

• Journal of the Korean Ceramic Society
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• v.37 no.3
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• pp.256-262
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• 2000

The dielectric properties of complex perovskite ($Pb_{1-x}Ca_{x}$)($Fe_{0.5}Ta_{0.5}$)$O_{3}$ with >($0.5{\le}x{\ge}0.65$ were investigated at microwave frequencies. Dilectric constant decreased with increasing Ca content, and was directly proportional to the cube of average ionic ra야 of A-site. For the specimen of x=0.6 sintered at $1250^{\circ}C$ for 3 h in air, dielectric constant (k) of 63, QF of 11000 GHz, and the temperature coefficient of resonant frequency(TCF) of -14ppm/$^{\circ}C$ were obtained. As Ca content increased, TCF of the specimen negatively increased due to the reduction of the tolerance factor(t). Changes in intrinsic loss with varying Ca content was investigated by the infrared reflectivity spectra ranging 50 to 4000 $cm^{-1}$, which were calculated by the Kramers-Kronig analysis and classical oscillator model. The relative tendency of microwave dielectric properties of the ($Pb_{1-x}Ca_{x}$)($Fe_{0.5}Ta_{0.5}$)$O_{3}$ specimens calculated from the reflectivity data were in good agreement with the results by the post resonant method.