• Title/Summary/Keyword: Infrared absorption

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IR Absorption Property in NaNo-thick Nickel Cobalt Composite Silicides (나노급 두께의 Ni50Co50 복합 실리사이드의 적외선 흡수 특성 연구)

  • Song, Oh Sung;Kim, Jong Ryul;Choi, Young Youn
    • Korean Journal of Metals and Materials
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    • v.46 no.2
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    • pp.88-96
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    • 2008
  • Thermal evaporated 10 nm-$Ni_{50}Co_{50}$/(70 nm-poly)Si films were deposited to examine the energy saving properties of silicides formed by rapid thermal annealing at temperature ranging from 500 to $1,100^{\circ}C$ for 40 seconds. Thermal evaporated 10 nm-Ni/(70 nm-poly)Si films were also deposited as a reference using the same method for depositing the 10 nm-$Ni_{50}Co_{50}$/(70 nm-poly)Si films. A four-point probe was used to examine the sheet resistance. Transmission electron microscopy (TEM) and X-ray diffraction XRD were used to determine cross sectional microstructure and phase changes, respectively. UV-VIS-NIR and FT-IR (Fourier transform infrared spectroscopy) were used to examine the near-infrared (NIR) and middle-infrared (MIR) absorbance. TEM analysis confirmed that the uniform nickel-cobalt composite silicide layers approximately 21 to 55 nm in thickness had formed on the single and polycrystalline silicon substrates as well as on the 25 to 100 nm thick nickel silicide layers. In particular, nickel-cobalt composite silicides showed a low sheet resistance, even after rapid annealing at $1,100^{\circ}C$. Nickel-cobalt composite silicide and nickel silicide films on the single silicon substrates showed similar absorbance in the near-IR region, while those on the polycrystalline silicon substrates showed excellent absorbance until the 1,750 nm region. Silicides on polycrystalline substrates showed high absorbance in the middle IR region. Nickel-cobalt composite silicides on the poly-Si substrates annealed at $1,000^{\circ}C$ superior IR absorption on both NIR and MIR region. These results suggest that the newly proposed $Ni_{50}Co_{50}$ composite silicides may be suitable for applications of IR absorption coatings.

Tunable Diode Laser Absorption Spectroscopy for Environmental Monitoring (파장가변 다이오드 레이저 흡수 분광학을 사용한 대기환경분석)

  • Ju Sang-U;Kim Seong-Geun
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.247-248
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    • 2003
  • Tunable diode laser absorption spectroscopy (TDLAS) has been widely used in environmental monitoring of gaseous species in the past decade. TDLAS is a direct measurement technique for pollutants such as NOx without any interference from other species. Because of its superior spectral purity (~0.001 ­$cm^{-1}$), absorption linewidths with resolvable rotational structure can be studied in the mid infrared region where strong fundamental vibrational transitions of molecules appear. (omitted)

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Spectral Characteristics Visible and Near-infrared of Metamorphic Rocks (변성암의 분광특성)

  • 조민조;강필종;이봉주
    • Korean Journal of Remote Sensing
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    • v.8 no.1
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    • pp.1-13
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    • 1992
  • The study is to analize the spectral characteristics of metamorphic rocks by their spectral reflectance curves obtained from CARY 17-D Spectrophotometer. Coarse grained rocks generally show strong absorption at 1.4 and 1.9 $\mu\textrm{m}$ due to preserved water inclusion in quartz of feldspar. The basic rocks show a broad absorption due to Fe$^{++}$ ion rich in mafic minerals. Strong absorption near 2.0$^+\mu\textrm{m}$ suggests existence of carbonate or clay minerals.

INFRARED - X-RAY CONNECTION IN NEARBY ACTIVE GALACTIC NUCLEI; AKARI AND MAXI RESULTS

  • Isobe, Naoki;Nakagawa, Takao;Yano, Kenichi;Baba, Shunsuke;Oyabu, Shinki;Toba, Yoshiki;Ueda, Yoshihiro;Kawamuro, Taiki
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.185-187
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    • 2017
  • Combining the AKARI Point Source Catalog and the 37-month Monitor of All-sky X-ray Image (MAXI) catalog, the infrared and X-ray properties of nearby active galactic nuclei were investigated. The 37-month MAXI catalog tabulates 100 nearby Seyfert galaxies, 73 of which are categorized into Seyfert I galaxies. Among these Seyfert galaxies, 69 ones were found to have an AKARI infrared counterpart. For the Seyfert I galaxies in this sample, a well-known correlation was found between the infrared and X-ray luminosities. However, the observed X-ray luminosity of the Seyfert II galaxies tends to be lower for the infrared luminosity than the Seyfert I galaxies. This suggests that the X-ray absorption is significant in the Seyfert II galaxies. The Seyfert II galaxies seem to have a bimodal distribution of the IR color between $18{\mu}m$ and $90{\mu}m$. Especially, a large fraction of the Seyfert II galaxies exhibits a redder IR color than the Seyfert I galaxies. A possible origin of the redder IR color is briefly discussed, in relation to the star formation activity in the host galaxy, and to the X-ray absorption.

A Study on the Infrared Radiation Properties of Anodized Aluminum (양극산화된 알루미늄의 적외선 복사특성 연구)

  • 강병철;최정진;김기호
    • Journal of the Korean institute of surface engineering
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    • v.35 no.3
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    • pp.149-157
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    • 2002
  • Spectral emissivity depends on the surface conditions of the materials. The mechanisms that affect the spectral emissivity in anodic oxide films on aluminum were investigated. The aluminum specimens were anodized in a sulfuric acid solution and the thickness of the resulting oxide film formed changed with the anodizing time. FT-IR spectrum analysis identified the anodic oxide film as boehmite ($Al_2$$O_3$.$H_2$O). Both the infrared emisivity and reflectivity of the anodized aluminum were affected by the structure of the anodic oxide film because Al-OH and Al-O-Al have a pronounced absorption band in the infrared region of the spectrum. The presence of an anodic oxide film on aluminum caused a rapid drop in the infrared reflectivity. An aluminum surface in the clean state had an emissivity of approximately 0.2. However, the infrared emissivity rapidly increased to 0.91 as the thickness of the anodic oxide film increased.

A PRELIMINARY STUDY ON THE CHARACTERIZATION OF HONEY BY NEAR INFRARED SPECTROSCOPY

  • Davies, Anthony M.C.;Radovic, Branka;Fearn, Tom;Anklam, Elke
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1052-1052
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    • 2001
  • Hear infrared (NIR) spectra were measured, at five temperatures, for forty-eight samples of honey, from a variety of geographical and botanical sources, and the data has been used to explore the possibility of using NIR spectroscopy for testing label claims concerning the geographical and botanical source of honey being offered for sale to the public. These results demonstrate that the successful characterization of the botanical source of a honey may be obtained by NIR spectroscopy. Further work with large numbers of samples and groups will be required to realized this potential. Additional analysis of these data suggest that research into new ways of obtaining information on the change of absorption with temperature might be beneficial for a range of technologies.

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Low Resolution Near-Infrared Stellar Spectra Observed by CIBER

  • Kim, MinGyu;Lee, Hyung Mok
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.76.2-76.2
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    • 2016
  • We present near-infrared (0.8 - 1.8 microns) spectra of 63 bright (J_mag < 10) stars observed with Low Resolution Spectrometer (LRS) onboard the rocket-borne Cosmic Infrared Background Experiment (CIBER). Two Micron All Sky Survey (2MASS) photometry information is used to find cross-matched stars after reduction and extraction of the spectra. We identify the spectral types of observed stars by comparing with spectral templates from the Infrared Telescope Facility (IRTF) library. All the observed spectra are consistent with late F to M stellar spectral types, and we identify various infrared absorption lines. As our observations are performed above the Earth's atmosphere, our spectra are free from telluric contamination. Including HST/NICMOS and Cassini/VIMS, the spectral coverage has rarely been achieved in space, and the methods developed here can inform statistical studies with future low-resolution spectral measurements such as GAIA photometric and radial velocity spectrometer.

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Analysis of biomarkers with tunable infrared gas sensors (가변 파장형 적외선 가스 센서에 의한 생체표지자 분석)

  • Yi, Seung Hwan
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.314-319
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    • 2021
  • In this study, biomarkers were analyzed and segmented using tunable infrared gas sensors after performing the principal component analysis. The free spectral range of the device under test (DUT) was around 30 nm and DUT-5580 yielded the highest output voltage property among the others. The biomarkers (isoprophyl alcohol, ethanol, methanol, and acetone solutions) were sequentially mixed with deionized water and their mists were carried into the gas chamber using high-purity nitrogen gas. A total of 17 different mixed gases were tested with three tunable infrared gas sensors, namely DUT-3144, DUT-5580, and DUT-8010. DUT-8010 resolved the infrared absorption spectra of whole mixed gases. Based on the principal component analysis with each DUT and their combinations, each mixed gas and the trends in increasing gas concentration could be well analyzed when the contributions of the eigenvalues of the first and second were higher than 70% and 10%, respectively, and their sum was greater than 90%.

$CO_2$ Laser Absorption Measurement of $CH_3CH_2Br$ using Photoacoustic Method

  • Jang Soo Shin;Kyung Hoon Jung;Cheol Jung Kim
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.553-556
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    • 1992
  • The ${CO}_2$ laser absorption measurement of ${CH}_3{CH}_2Br$ utilizing photoacoustic (PA) technique was performed using a cw and a pulsed ${CO}_2$ lasers. The absorption profile in the ${CO}_2$ laser wavelength region (9-10 ${\mu}$m) and the macroscopic small signal absorption cross section at 10P(20) (10.59 ${\mu}$m, 944 $cm^{-1}$) laser line were measured using a cw ${CO}_2$ laser. The laser fluence dependence on infrared multiphoton absorption (IRMPA) was also studied with a pulsed TEA ${CO}_2$ laser at 10P(20) laser line. In view of monotonic increase of PA signal with the rise of laser fluence, it was suggested that the anharmonicity in pumped vibration mode did not restrict ir multiphoton absorption in ${CH}_3{CH}_2Br$ system as found in large molecular system.

SYSTEMATIC STUDY OF INTERSTELLAR ICES IN NEARBY GALAXIES

  • Yamagishi, M.;Kaneda, H.;Oyabu, S.;Ishihara, D.;Onaka, T.;Shimonishi, T.;Suzuki, T.
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.249-252
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    • 2012
  • The absorption features due to interstellar ices, especially $H_2O$ and $CO_2$ ices, provide us with crucial information on present and past interstellar environments, and thus the evolutionary histories of galaxies. Before AKARI, however, few detections of ices were reported for nearby galaxies. The AKARI's unique capability of near-infrared spectroscopy with high sensitivity enables us to systematically study ices in nearby galaxies. Thus we have explored many near-infrared spectra ($2.5-5{\mu}m$) of the 211 pointed observations, searching for the absorption features of ices. As a result, out of 122 nearby galaxies, we have significantly detected $H_2O$ ice from 36 galaxies and $CO_2$ ice from 9 galaxies. It is notable that the ices are detected not only in late-type galaxies but also in early-type galaxies. We find that $CO_2$ ice is more compactly distributed near the galactic center than $H_2O$ ice. Finally, we suggest that the gas density of a molecular cloud and UV radiation may be important factors to determine the abundance of ices.