• Title/Summary/Keyword: Infrared absorption

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Reagentless Determination of Human Serum Components Using Infrared Absorption Spectroscopy

  • Hahn, Sang-Joon;Yoon, Gil-Won;Kim Gun-Shik;Park Seung-Han
    • Journal of the Optical Society of Korea
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    • v.7 no.4
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    • pp.240-244
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    • 2003
  • Simultaneous determination of concentrations for four major components in human blood serum was investigated using a Fourier-transform mid-infrared spectroscopy. Infrared spectra of human blood serum were measured in 8.404 ∼ 10.25 ${\mu}m$ range where the highest absorption peaks of glucose are located. A partial least square (PLS) algorithm was utilized to establish a calibration model for determining total protein, albumin, globulin and glucose levels which are commonly measured metabolites. The standard error of cross validation obtained from our multivariate calibration model was 0.24 g/dL for total protein, 0.15 g/dL for albumin, 0.17 g/dL for globulin, and 6.68 mg/dL for glucose, which are comparable with or meet the criteria for clinical use. The results indicate that the infrared absorption spectroscopy can be used to predict the concentrations of clinically important metabolites without going through a chemical process with a reagent.

Investigation of a series of near-infrared absorbing heptamethine cyanine dyes

  • Yun, Hye-Su;Park, Su-Yeol;Sin, Seung-Rim;Sin, Jong-Il;An, Gyeong-Ryong;Lee, Sang-O;O, Seong-Geun;Jeon, Geun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.11a
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    • pp.115-116
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    • 2009
  • In this study, near-infrared absorbing dyes, namely, new rigidified heptamethine cyanine dyes were synthesized and investigated their properties. The cyanine dyes have been synthesized by a condensation reaction between a quanternary salt containing as activated methyl group and an unsaturated bisaldehyde or its equivalent. We were investigated the synthesis of new rigidified heptamethine cyanine and related the compounds with near infrared absorption. The full spectroscopic characterization of all cyanine were described. Absorption properties in the near-infrared region may cause these dyes to the potential used in bio-probe, optical recording media materials.

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Molecular Dyamics Simulation and Far Infrared Measurements of $Ba_{0.6}K_{0.4}BiO_3$

  • Lee, C.Y.;Song, Ki.Y.;Sperline, R.P.
    • Korean Journal of Materials Research
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    • v.6 no.6
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    • pp.555-560
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    • 1996
  • The vibrational behavior and the molecular dynamics of the high Tc superconductor Ba0.6K0.4BiO3 have been studied experimentally and by atomistic computer simulation methods. For Ba0.6K0.4BiO3, the vibrational spectrum is dominated by oxygen ion modes from 150cm-1 to 820cm-1 including infrared absorption bands at 330, 480, 640 and 830cm-1including infrared absorption bands at 330, 480, 640 and 830cm-1at room temperature. Band assignments are discussed in relation to those bands predicted by simulations, and the infrared and Raman measurements reported in the literature.

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Infrared Absorption Spectroscopic Studies of ${\alpha},{\omega}$-Diphenylpolyenyl Anions with Odd Numbered Polyene Molecules

  • Kim, Jin Yeol;Kim, Eung Ryeol;Son, Dae Won
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.833-836
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    • 2001
  • Infrared absorption spectra of $\alpha\omega-diphenylpolyenyl$, anions Ph(CH)nPh- (DPn-, n=7, 9, and 13) in the tetrahydrofuran-d6 solutions was measured in the range of 1700 and 1200 cm-1 . The infrared spectra obtained from anions (DPn) showed considerable difference from their neutral species (DPn); their intensities were enhanced at least two orders of magnitude stronger than their neutral species. The in-plane CH bending modes at 1464 and 1375 cm-1 are correspondingly strengthened with the chain length increased, but the C=C stretching at 1541 cm-1 is weakened and frequencies are not changed. We provide an IR evidence for the first time that the bond order or bond alternations of the anions (soliton) are different from those of radical anions (polaron) as well as neutral species.

Analysis of Drugs and Chemicals by Infrared Absorption Spectrophotometry(II) Quantitative Analysis of Sulfamethoxydiazine and Sulfamethoxypyridazine in Pharmaceutical Preparations. (Infrared spectrophotometry에 의한 의약품의 분석연구 (II) 적외선흡수 Spectra에 의한 Sulfamethoxydiazine 및 Sulfamethoxy-pyridazine의 정량분석)

  • 옥치완;권영훈
    • YAKHAK HOEJI
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    • v.13 no.2_3
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    • pp.51-56
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    • 1969
  • In quantitative analysis of sulfonamide drugs by means of infrared Spectrophotometry, the author tried to analyse Sulfamethoxydiazine and Sulfamethoxypyridazine in their Pharmaceutical Preparations. By the survey of infrared absorption spectra of Sulfamethoxydiazine and Sulfamethoxypyridazine. We found quantitative properties at the peaks of wave number 1150 cm$^{-1}$ (Sulfamethoxydiazine) and 1090 cm$^{-1}$ (Sulfamethoxypyridazine) in the spectra. These peaks obey Beer's Law in a range of 50-150 ug for Sulfamethoxydiazine and 70-350 ${\mu}$g for Sulfamethoxypyridazine in 300 mg KBr disc. By this method, Sulfamethoxydiazine and Sulfamethoxypyridazine could be analyzed less than 2% error.

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Glucose Prediction in the Interstitial Fluid Based on Infrared Absorption Spectroscopy Using Multi-component Analysis

  • Kim, Hye-Jeong;Noh, In-Sup;Yoon, Gil-Won
    • Journal of the Optical Society of Korea
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    • v.13 no.2
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    • pp.279-285
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    • 2009
  • Prediction of glucose concentration in the interstitial fluid (ISF) based on mid-infrared absorption spectroscopy was examined at the glucose fundamental absorption band of 1000 - 1500/cm (10 - 6.67 um) using multi-component analysis. Simulated ISF samples were prepared by including four major ISF components. Sodium lactate had absorption spectra that interfere with those of glucose. The rest NaCl, KCl and $CaCl_2$ did not have any signatures. A preliminary experiment based on Design of Experiment, an optimization method, proved that sodium lactate influenced the prediction accuracy of glucose. For the main experiment, 54 samples were prepared whose glucose and sodium lactate concentration varied independently. A partial least squares regression (PLSR) analysis was used to build calibration models. The prediction accuracy was dependent on spectrum preprocessing methods, and Mean Centering produced the best results. Depending on calibration sample sets whose sodium lactate had different concentration levels, the standard error prediction (SEP) of glucose ranged $17.19{\sim}21.02\;mg/dl$.

High-resolution Near-infrared Spectroscopy of IRAS 16316-1540: Evidence of Accretion Burst

  • Yoon, Sung-Yong;Lee, Jeong-Eun;Park, Sunkyung;Lee, Seokho;Herczeg, Gregory J.;Mace, Gregory;Lee, Jae-Joon
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.42.3-42.3
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    • 2019
  • The high-resolution near-infrared (NIR) spectroscopy can reveal the evidence of the accretion burst (e.g., the broadened absorption features produced by the Keplerian disk motion) although the moment of the outburst was not caught. The embedded protostar IRAS 16316-1540 observed with the Immersion Grating Infrared Spectrograph (IGRINS, $R={\Delta}{\lambda}/{\lambda}{\sim}45000$) shows the broad absorption features in atomic and CO transitions, as seen in FU Orionis objects (FUors), indicative of an outburst event. We examine whether the spectra of IRAS 16316-1540 arise from the rotating inner hot gaseous disk. Using the IGRINS spectral library, we show that the line profiles of IRAS 16316-1540 are more consistent with an M1.5 V template spectrum convolved with a disk rotation profile than the protostellar photosphere absorption features with a high stellar rotation velocity. We also note that the absorption features deviated from the expected line profile of the accretion disk model can be explained by a turbulence motion generated in the disk atmosphere. From previous observations that show the complex environment and the misaligned outflow axes in IRAS 16316-1540, we suggest that an impact of infalling clumpy envelope material against the disk induces the disk precession, causing the accretion burst from the inner disk to the protostar.

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Feeding Effect of Far Infrared Irradiated Rice to Survival Activity against Drowning of Mouse (원적외선 저장쌀의 급여가 흰쥐의 생존력에 미치는 영향)

  • Kwon, O-Jun;Yoo, Byung-Hyuk;Choi, Ung-Kyu;Son, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.35 no.2
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    • pp.302-305
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    • 2003
  • Effect of feeding far infrared-irradiated rice on survival ability of mice against drowning was investigated. Moisture absorption of far infrared-irradiated rice was about 1.3-fold higher than that of normal rice. L-Value was maintained high during cooking and storage. Weight of mice was not influenced by far infrared-irradiated rice content. No significant difference in survival abilities of mice between normal rice and far infrared-irradiated rice was shown until 1 breeding week. Significant differences in survival ability between two groups were found in 2 (9.5%) and 3 breeding weeks (7.2%).

Broadening of absorption spectrum in a p-type InGaAs-InAlAs coupled Quantum well (p형 InGaAs-InAlAs 결합양자우물을 이용한 흡수계수스펙트럼의 broadening)

  • 김경환;김성준
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.3
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    • pp.34-40
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    • 1997
  • Intervalence subband absroption of normally incident infrared radiation in p-type InGaAs-InAlAs coupled quantum well (CQW) is theoretically investigated by the multiband effective mass formalism. By solving a 4*4 luttinger-kohn hamitonian, we calculate valence subband structures, intervalence subband transition matrix elements, and absorption coefficient spectrum in the CQW which consists of a wider well, a thinner well and a barreir between them. Using the flexible design parameters given to the valence band CQW structure, we show that the absorption coefficient profile can be tailored. For a carefully designed CQW, theabsorption coefficient cn be made to maintain a large value over a wider wavelength range of incident infrared radiation compared with that shown in intersubband absorption in usual single quantum well.

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An automated analysis tool for the IR absorption spectra of interstellar ices

  • Kim, Chul-Hwan;Lee, Jeong-Eun;Kim, Jaeyeong;Jeong, Woong-Seob
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.57.1-57.1
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    • 2021
  • The icy mantles of interstellar grains are developed by the freeze-out of interstellar molecules and atoms onto grain surfaces. The ice molecules become more complex by surface chemistry induced directly by high energy photons or by the thermal energy diffused over heated grain surface. Therefore, the ice composition is an important tracer of physical conditions where the ices form. Ices have been studied via their absorption features against continuum sources, such as young stellar objects or evolved background stars, in infrared wavelengths. The Spitzer IRS was the most sensitive spectrometer for the observations of infrared ice absorption features. We has been developing an automated analysis tool for the Spitzer IRS spectra, especially for the 15 ㎛ CO2 bending mode. The 15 ㎛ CO2 absorption feature is very useful for the study of accretion process in star formation since its spectral shape varies with thermal condition of the dust grains. Eventually, this tool will cover the whole range of the Spitzer IRS spectrum (5~20 ㎛).

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