• 제목/요약/키워드: Infiltration growth process

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단결정 YBCO 벌크 초전도체 제조에 대한 액상침투법과 고전적 용융공정의 비교연구 (Comparative Study on the Fabrication of Single Grain YBCO Bulk Superconductors using Liquid Infiltration and Conventional Melt Growth Processes)

  • 아시프 마흐무드;전병혁;김찬중
    • Progress in Superconductivity
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    • 제11권1호
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    • pp.42-46
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    • 2009
  • With an aim of comparison, single grain Y-Ba-Cu-O (YBCO) bulk superconductors were fabricated using a liquid infiltration growth (LIG) process and a conventional melt growth (MTG) process with top seeding. The MTG process uses an $YBa_2Cu_3O_{7-x}$(Y123) powder as a precursor, while the LIG process uses $Y_2BaCuO_5(Y211)/Ba_3Cu_5O_8(Y035)$ pre-forms. The growth of a single Y123 domain on the top seed was successful in the both processes. Different feature between the two processes is the interior microstructure regarding the critical current density ($J_c$). The LIG-processed YBCO sample showed a lower porosity, more uniform distribution of Y211 particles and the enhanced Y211 refinement compared to the conventional MTG process. The $J_c$ improvement in the LIG process is attributed to the dispersion of finer Y211 particles as well as lower porosity within the Y123 superconducting matrix.

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반응용융 침투법에 의한 $Al_2O_3/AL$복합재료의 제조 및 기계적 특성 평가 (Fabrication and mechanical properties of $Al_2O_3/AL$ composites by reactive melt infiltration)

  • 윤여범;김송희;태원필
    • 한국결정성장학회지
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    • 제7권4호
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    • pp.610-618
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    • 1997
  • 반응용침법으로 제조된 $Al_2O_3$/Al 복합재료는 900-$1200^{\circ}C$의 온도범위에서 $Al_2O_3$ 분말성형체에 용융Al을 침투시켜 제조하였다. 용융침투는 각 온도에서 잠복기를 거친후 발생하였으며, 복합재료의 성장속도는 시간에 따라 선형적으로 비례하였다. 제조된 복합재료의 주성분은 $Al_2$O$_3$와 Al이었고 소량의 Si이 탐지되었다. 복합재료의 상대밀도는 $Al_2O_3$ 입자크기가 증가함에 따라 증가하였고 용융 침투온도가 높을수록 감소하였다.

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Cu-Cr 계 접점재료의 소결특성에 관한 연구 (A sturdy on the sintering characteristics for Cu-Cr contact material)

  • 연영명;오일성;박홍태;이상엽;서정민
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1643-1645
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    • 2000
  • The effects of pre-sintering and infiltration conditions on the electrical and physical properties of Cu-Cr contact material have been studied. Specimens were prepared by infiltration technique, aiming at the final composition of Cu50w%Cr, with varying pre-sintering and infiltration conditions. It showed that increased pre-sintering temperature had a little influence on the final microstructure of Cu-Cr contact material, but improved the surface morphology of Cr-skeleton resulting in better wettability in the followed infiltration process. It also showed that Cr grain growth and gram shape change became prominent with increasing infiltration temperature and time.

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Processing and properties of $Al_{2}O_{3}/SiC$ nanocomposites by polycarbosilane infiltration

  • Jung-Soo Ha;Chang-Sung Lim;Chang-Sam Kim
    • 한국결정성장학회지
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    • 제12권2호
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    • pp.80-86
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    • 2002
  • $Al_{2}O_{3}/SiC$ nanocomposites were made by infiltrating partially sintered alumina bodies with polycarbosilane (PCS) solutions, which is a SiC polymer precursor, with pressureless sintering. The SiC content, densification, phases, strength, and microstructure were investigated with the processing parameters such as PCS solution concentration and heat treatment condition for PCS pyrolysis and sintering. The results were compared with those for pure alumina and nanocomposite samples made by the existing polymer precursor route (i.e. the PCS addition process). The SiC contents of up to 1.5 vol% were obtained by the PCS infiltration. PCS pyrolysis, followed by air heat treatment, was needed before sintering to avoid a cracking problem and to attain a densification as high as 98 % of theoretical. The nanocomposites exhibited significantly higher strength than pure alumina and those prepared by the PCS addition process despite larger grain size. Besides $\alpha-Al_{2}O_{3}/SiC$ and $\beta-SiC$ phases, mullite was present a little in the nanocomposites, which resulted from the reaction of $SiO_{2}$ in the pyrolysis product of PCS with the $Al_{2}O_{3}$ matrix during sintering. The nanocomposites had intagranular particles believed to be SiC, which is a typical feature of $Al_{2}O_{3}/SiC$ nanocomposites.

밭에서의 유효우량 산정모형 개발 (Modeling Effective Rainfall for Upland Crops)

  • 정하우;김성준
    • 한국농공학회지
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    • 제35권1호
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    • pp.29-39
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    • 1993
  • A model for estimating daily effective rainfall of upland crops was developed. The infiltration process was described by Green-Ampt infiltration model developed by Chu(1978). The model considers delayed surface ponding and surface detention storage under a uniform soil profile. The Green-Ampt parameters, that is, average hydraulic conductivity and average capillary pressure head on a sandy loam soil were determined from field experiment using Air-entry permeameter developed by Bouwer(1966). The model was verified by comparing measured and simulated surface runoff. The ratios of effective rainfall to total rainfall for red pepper, soybean, sesame and Chinese cabbage were evaluated using Borg's root growth model( 1986) respectively. The followings are a summary of this study results; 1.In a sandy loam soil average hydraulic conductivity was 3.28cm/hr and average capillary pressure head was 3.00cm. 2.The root growth of upland crops could be expressed by Borg's root growth model successively. 3.The measured and simulated surface runoff was agreed well with each other. 4.As the rainfall amount was increased, the ratio of effective rainfall to total rainfall was decreased exponentially till a certain growing period.

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Growth of Al2O3/Al Composite by Directed Metal Oxidation of Al Surface Doped with Sodium Source

  • Park, Hong Sik;Kim, Dong Seok;Kim, Do Kyung
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.439-445
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    • 2013
  • Both an unreinforced $Al_2O_3$/Al matrix and a ${\alpha}-Al_2O_3$ particulate reinforced composite have been produced by the oxidation of an Al surface doped with NaOH in the absence of any other dopant. Fabrication of the matrix was initiated by the formation of $NaAlO_2$, which provides a favorable surface structure for the matrix formation by breaking the protective $Al_2O_3$ layer on Al. During the matrix growth, the external surface of the growth front was covered with a very thin sodium-rich oxide. A cyclic formation process of the sodium-rich oxide on the growth surface was proposed for the sodium-induced directed metal oxidation process. This process involves dissolution of the sodium-rich oxide, motion of Na to the growth front, and re-formation of the oxide on the surface. Near-net-shape composites were fabricated by infiltrating an $Al_2O_3$/Al matrix into a ${\alpha}-Al_2O_3$ particulate preform, without growth barrier materials. The infiltration distance increased almost linearly in the NaOH-doped preform.

용융 Si-C-SiC계에서 $\beta$-SiC 생성기구 ($\beta$-SiC Formation Mechanisms in Si Melt-C-SiC System)

  • 서기식;박상환;송휴섭
    • 한국세라믹학회지
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    • 제36권6호
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    • pp.655-661
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    • 1999
  • ${\beta}$-SiC formation mechanism in Si melt-C-SiC system with varying in size of carbon source was investigated. A continuous reaction sintering process using Si melt infiltration method was adopted to control the reaction sintering time effectively. It was found that ${\beta}$-SiC formation mechanism in Si melt-C-SiC system was directly affected by the size of carbon source. In the Si melt-C-SiC system with large carbon source ${\beta}$-SiC formation mechanism could be divided into two stages depending on the reaction sintering time: in early stage of reaction sintering carbon dissolution in Si melt and precipitation of ${\beta}$-SiC was occurred preferentially and then SIC nucleation and growth was controlled by diffusion of carbon throughy the ${\beta}$-SiC layer formed on graphite particle. Furthmore a dissolution rate of graphite particles in Si melt could be accelerated by the infiltration of Si melt through basal plane of graphite crystalline.

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백서 연조직에 저수준 레이저 요법시 창상 치유기전에 관한 연구 (EFFECT OF LOW LEVEL LASER THERAPY ON HEALING OF OPEN SKIN WOUNDS IN RATS)

  • 유상우;김경욱;이재훈;김창진
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제26권5호
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    • pp.481-489
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    • 2000
  • This research was focused on overall examination of tissue alteration, wound healing promotion. After the hair on the dorsal surface was shaved, $5{\times}5mm$ oval skin defect was formed. Experimental wounds of right side were irradiated on every day for 90 second with Ga-Al-As semi-conductor laser. Left side wounds served as control group. The rats were sacrificed on the 1st, 3rd, 5th, 7th, 14th, 21th day. For light microscopically, parafin section were stained with H&E, MT. The outcomes were as follows : 1. On 1st day, experimental and control group were seen acute inflammatory cell infiltration, edema. 2. On the 3rd days, both groups were seen crust development, collagen, blood vessel proliferation. 3. On the 5th days, experimental group were reduced edema and inflammatory cell infiltration than control group. 4. On the 7th days, both groups were observed edema, inflammatory cell infiltration disappearance and keratinocytes motility from wound defect. 5. On the 14th days, experimental group appeared collagen, blood vessel proliferation and hair follicle than control group. 6. On the 21th days, both groups were seen normal status re-epithelization. According to the above results, The wound-healing stimulated by laser radiation involves an increased rate of epithelial growth. LLLT was confirmed that it has fibroblast, blood vessel proliferation, influence initial wound healing process.

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Al-합금의 단열섬유판 반응침투에 의한 $Al_2O_3$-세라믹스의 형성 (Formation of $Al_2O_3$-Ceramics by Reactive Infiltration of Al-alloy into Insulation Fiber Board)

  • 김일수
    • 한국세라믹학회지
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    • 제34권5호
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    • pp.483-490
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    • 1997
  • Al2O3/metal composites were fabricated by oxidation and reaction of molten Al-alloy into two types of commercial Al2O3-SiO2 fibrous insulation board. The growth rate, composition and microstructure of these materials were described. An AlZnMg(7075) alloy was selected as a parent alloy. Mixed polycrystalline fiber and glass phase fiber were used as a filler. The growth surface of an alloy was covered with and without SiO2. SiO2 powder was employed as a surface dopant to aid initial oxidation of Al-alloy. Al-alloy, SiO2, fiber block and growth inhibitor CaSiO3 were packed sequentially in a alumina crucible and oxidized in air at temperature range 90$0^{\circ}C$ to 120$0^{\circ}C$. The growth rate of composite layer was calculated by measuring the mass increasement(g) per unit surface($\textrm{cm}^2$). XRD and optical microscope were used to investigate the composition and phase of composites. The composite grown at 120$0^{\circ}C$ and with SiO2 dopant showed rapid growth rate. The growth behavior differed a little depending on the types of fiber used. The composites consist of $\alpha$-Al2O3, Al, Si and pore. The composite grown at 100$0^{\circ}C$ exhibited better microstructure compared to that grown at 120$0^{\circ}C$.

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